Ch6
Helicase: Unwinds DNA to begin replication.
Gyrase: Relieves tension during unwinding.
Primase: Adds RNA primers at the start of the new strand (5’ end).
Pol III Adds remaining nucleotides to the unwinding double helix.
Strands:
Leading Strand: Moves towards the replication fork; DNA synthesis is continuous.
Lagging Strand: Moves away from the replication fork; DNA synthesis is fragmented (discontinuous).
Processing:
RNA primers removed by DNA Polymerase I, leaving little fragments on the lagging strand called Okazaki fragments.
DNA Ligase fills in the gaps to link the fragments together.
Both DNA Poly I and III proofread.


Strand Synthesis
Leading strand is continuous
Lagging strand is discontinuous, forming Okazaki fragments.
Processing of Replicated DNA
RNA primers on the lagging strand are removed by Pol I.
DNA Ligase joins Okazaki fragments.
DNA Polymerase I and III proofread for accuracy.
Nucleotide Composition and Structure
Nucleotide consists of phosphate group, five-carbon sugar, and nitrogen-containing base.
Phosphate group binds to sugar of the next nucleotide.
5’ end contains a free phosphate, while 3’ end contains a free sugar.
Historical Perspectives on DNA
Initially, proteins were believed to contain the genetic blueprint.
Watson and Crick’s discovery elucidated DNA’s double helix structure.
Base Pairing and Chromosomal Composition
Purines (two rings) pair with pyrimidines (one ring).
Chargaff's rule states A=T, C=G.
Chromosomes consist of proteins and DNA.
Semiconservative Replication
Meselson experiment confirmed one old strand remains.
Conservative (separate), Dispersive (mixed), Semi-Conservative (alt)
Key Enzymes in DNA Replication
Helicase unwinds and unzips the parent strand.
Single-strand binding proteins (SSBP) prevent strand reunion.
Primase lays down RNA primers.
DNA Polymerase III makes new DNA.
DNA Ligase joins okazaki fragments.
Polymerase I and III proofread and correct errors.
Milestones in DNA Discovery
Griffith: Bacterial transformation.
Hershey and Chase: Confirmed DNA as hereditary material.
Franklin: Discovered DNA’s helical shape.
Watson and Crick: Revealed DNA’s double helix structure.
Additional Insights
Gyrase relieves tension during unwinding.
Okazaki fragments are formed on the lagging strand.
Hydrogen bonds stabilize the DNA helix.