Definition of Temperature: A measure of the hotness of a body.
S.I. Unit: The Kelvin (K).
Celsius Scale:
Developed by Anders Celsius in 1742.
Based on two reference points: the freezing point of water at 0∘C and the boiling point of water at 100∘C.
Common uses: Air temperature, body temperature, oven temperature.
Kelvin Scale:
Developed by Lord Kelvin in 1848.
Removes the need for negative temperatures because its lowest value is zero (0K).
Absolute Zero: This point is where internal energy is at a theoretical minimum value.
Temperature Conversion Formulas:
Temperature in Celsius = Temperature in Kelvin −273.15
T(∘C)=T(K)−273.15
Example 1(i): To convert 325K to Celsius: t=325−273.15=51.85∘C.
Example 1(ii): To convert 26∘C to Kelvin: 26=T−273.15⇒T=299.15K.
Thermometric Properties: Any physical property that changes measurably with a change in temperature.
Length of a column of liquid: Liquids expand when heated (e.g., Mercury-in-glass thermometer). Liquid rises in a narrow column as it expands.
Electrical Resistance:
In metals, resistance increases with temperature because particles vibrate more, hindering current flow.
In thermistors (semiconductors), resistance decreases as temperature increases.
E.m.f. of a thermocouple: If two different metals are joined in a circuit and junctions are kept at different temperatures, an electromotive force (voltage) is induced. Greater temperature difference results in greater e.m.f.
Volume of a gas at constant pressure: Volume increases when heated (pV is constant).
Pressure of a gas at constant volume: Pressure increases when heated.
Colour: Certain crystals change colour with temperature, used in plastic strip body thermometers.
Practical Thermometers:
Clinical thermometer: Small scale (36∘C−37∘C); uses alcohol instead of poisonous mercury; features a constriction to prevent liquid backflow until shaken.
Oven thermometer.
Temperature gauge in a car.
Section B: Heat, Internal Energy, and Transfers
Heat: A form of energy that causes temperature rise when added and temperature fall when removed.
Internal Energy: The sum of the potential and kinetic energies of the molecules in a body.
States of Matter: Generally three states: solid, liquid, and gas. Adding heat causes transitions from solid to liquid to gas.
Thermal Equilibrium: Heat moves from hot to cold until temperatures are identical, at which point flow stops.
Conductors and Insulators:
Conductor: Substance allowing easy heat flow (e.g., metal spoon).
Conduction: Transfer of heat through a solid without net movement of the particles. Energy passes via particle vibrations.
Demonstration: Conductivity ring with wax and ball bearings on strips of different metals. Copper allows the bearing to fall first, proving it is the best conductor.
Convection: Transfer of heat through a fluid (liquid or gas) due to particle movement. Heated particles become less dense and rise, creating a convection current.
Example: In a hot water immersion tank, the "sink" setting heats the top element (small quantity), while the "bath" setting heats the bottom element (entire tank).
Radiation: Transfer of heat as electromagnetic (usually infrared) radiation without needing matter. Heat from the sun travels through the vacuum of space this way.
Applications: Night-vision goggles, security camera motion sensors.
Greenhouse Effect: Greenhouse gases trap escaping thermal energy reflected from the Earth's surface, acting like a blanket. Pollution increases these gases, causing global warming.
Solar Constant: The amount of energy falling normally on $1\,\text{m}^{2}$ of the earth's atmosphere per second at mean distance from the sun.
Value: ≈1360Wm−2.
Efficiency and U-values:
U-value: Amount of heat energy conducted per second through 1m2 of a substance when a temperature difference of 1∘C (1K) is maintained. Unit: Wm−2K−1. Lower U-values mean better insulation.
Percentage Efficiency Formula:
Percentage efficiency=EnergyinEnergyout×100
Percentage efficiency=PowerinPowerout×100
Example calculation: A kettle with 2.5kJ input and 1800J useful output has an efficiency of 25001800×100=72%.
Section C: Heat Transfers and Latent Heat
Heat Capacity: Heat energy needed to change a substance's temperature by 1K.
Formula: ΔE=Heat Capacity×Δθ
Specific Heat Capacity (SHC): Amount of energy needed to change the temperature of 1kg of a substance by 1K. Unit: J kg−1K−1.
Formula: ΔE=mcΔθ
Common SHC Values:
Water: 4180
Aluminium: 897
Steel: 466
Copper: 385
Applications of SHC:
Storage Heaters: High SHC bricks heat up at night and release heat during the day.
Car Coolants: Water's high SHC allows it to absorb significant engine heat without boiling quickly.
Cookware: Low SHC metals (copper/aluminium) heat up fast.
Conservation of Energy in Heat: Energy lost by one body = Energy gained by the other body.
Latent Heat: Heat taken in or released during a change of state without a change in temperature.
Specific Latent Heat (SLH): Energy needed to change the state of 1kg of a substance. Unit: J kg−1.
Formula: ΔE=ml
Specific Latent Heat of Fusion: Change from solid to liquid.
Specific Latent Heat of Vaporisation: Change from liquid to gas.
Example: Energy to condense 500g of steam (100∘C) and cool to 50∘C.
Total Energy=(ml)+(mcΔθ)=(0.5×2.26×106)+(0.5×4180×50)=1,234,500J.
The Heat Pump: Transfers energy from a cold body to a warm body using a refrigerant with high SLH and a low boiling point.
Evaporation Phase: Pressure is reduced, liquid vaporises and absorbs latent heat (cooling the surroundings).
Compression Phase: Vapour is compressed into a liquid, releasing latent heat (heating the surroundings).
Section D: Optics – Reflection & Refraction
Reflection: The bouncing of light off a surface.
Laws of Reflection:
Angle of incidence (i) = Angle of reflection (r).
The incident ray, normal, and reflected ray lie in the same plane.
Types: Regular reflection (smooth surfaces) vs. Diffuse reflection (rough surfaces).
Virtual Image: Formed by the apparent intersection of light rays; same size, upright, and located behind the mirror.
Refraction: Bending of light as it passes between media of different densities due to speed changes.
Speed comparison: Light travels faster in air/vacuum and slower in glass/water.
Rules of Bending:
Rare to Denser: Bends towards the normal (i>r).
Denser to Rare: Bends away from the normal (i<r).
Snell’s Law: sin(r)sin(i)=n (where n is the refractive index).
Refractive Index (n): Ratio of the sine of i to the sine of r when traveling from a vacuum into a medium.
n=c2c1 (ratio of speeds).
n=Apparent depthReal depth.
Total Internal Reflection (TIR): Occurs when light travels from a denser to a rarer medium at an angle of incidence greater than the critical angle (c).
Critical Angle Formula: n=sin(c)1.
Applications of TIR:
Prism reflectors: Used in bicycles and road signs.
Mirages: Caused by light refracting through air layers of different temperatures near the ground.
Snell’s Window: The circle of light visible to an underwater observer.
Optical Fibres: Thin glass rods where light is trapped via TIR. Used in telecommunications and medical endoscopes.
Section E: Optics – Lenses
Converging (Convex) Lens: Focuses parallel rays at a focal point (F).
Images: Can be real or virtual depending on object position (u).
Magnifying glass: Object placed between F and the pole produces a virtual, enlarged, upright image.
Diverging (Concave) Lens: Spreads out parallel rays. Always produces a virtual, upright, diminished image.
Lens Formula: f1=u1+v1
Real is positive rule (f and v are negative for diverging/virtual setups).
The Human Eye:
Long-sightedness (Hypermetropia): Image focuses behind the retina. Corrected with a converging lens.
Short-sightedness (Myopia): Image focuses in front of the retina. Corrected with a diverging lens.
Section F: Waves and Wave Motion
Definition of a Wave: A means of transferring energy through a medium without net movement of the medium itself.
Types of Waves:
Transverse: Vibration is perpendicular to the direction of travel (e.g., light, water waves, rope waves).
Longitudinal: Vibration is parallel to the direction of travel (e.g., sound, ultrasound, compression on a spring).
Wave Terminology:
Wavelength (λ): Distance between corresponding points on consecutive cycles.
Amplitude (A): Maximum displacement from rest. Energy ∝A2.
Frequency (f): Cycles per second (Hz).
Period (T): Time for one complete oscillation. T=f1.
Wave Speed Formula: v=fλ.
Wave Phenomena:
Reflection: Bouncing off obstacles.
Refraction: Speed and wavelength change when entering a new medium, but frequency remains constant.
Diffraction: Spreading of waves through gaps. More pronounced when wavelength is similar to the gap width. Sound diffracts more than light around doors because its wavelength is longer.
Interference: Combining amplitudes of overlapping waves.
Constructive: Amplitudes add up.
Destructive: Amplitudes cancel. Total destructive interference occurs if waves are 180∘ out of phase.
Polarisation: Only applies to transverse waves. Restricts vibration to one plane.
Applications: Polaroid sunglasses (reduce glare); stress testing in engineering (photoelasticity).
Doppler Effect: Apparent shift in frequency due to the relative motion between source and observer.
Moving Towards: f′=c−ufc (Higher frequency).
Moving Away: f′=c+ufc (Lower frequency).
Applications: Red shift of stars (determining galactic speeds), radar guns for speed traps.
Section G: Sound
Nature of Sound: Longitudinal wave produced by vibrations; requires a medium.
Speed of Sound: Varies with density and elasticity. Air (0∘C) is 331m/s; Steel is 4800m/s.
Limits of Audibility: 20Hz to 20kHz.
Ultrasonics: Frequencies >20kHz. Used in medicine (scans), industrial cleaning (NDT), and navigation (SONAR).
Stationary (Standing) Waves: Formed when two identical waves travel in opposite directions and meet.
Nodes: Zero movement points.
Antinodes: Maximum movement points.
Distance between two nodes = 2λ.
Resonance: Transfer of energy between bodies with the same natural frequency.