Reaction Rates and Collision Theory Notes

Chemical Reaction

Definition = A process where one set of chemical substances is transformed to another set of chemical substances

• The transformation happens through the rearrangement of atoms

• A reaction is accompanied by an energy change

(THE LAW OF) CONSERVATION OF MASS

In a chemical reaction, matter is neither created nor destroyed

• For example, if we start out with four oxygen atoms, we need to end up with four oxygen atoms

• We say that matter is conserved

•The mass of matter is always the same before and after a chemical reaction.

(THE LAW OF) CONSERVATION OF ENERGY

•Energy is also conserved in a chemical reaction

• There is always energy stored within

chemical bonds

• It is called chemical potential energy

•Chemical energy is observed only when a chemical reaction occurs

• During a chemical reaction, energy is either absorbed or released

•A reaction that releases energy (usually in the form of heat) is called exothermic

•A reaction that absorbs energy (usually in the form of heat) is called endothermic

Reaction Rate

  • The speed at which reactants are used or products are formed (change in concentration).

  • Example: Formation of rust

Collision Theory

  • Chemical reaction involves breaking bonds in reactants, rearranging atoms into products, and forming new bonds.

  • Particles must collide to react (not all collisions lead to a reaction).

  • Particles must have proper orientation.

  • Collision energy must be high enough to break old bonds (activation energy, EaE_a).

Successful Reaction Conditions

  1. Reactants must collide.

  2. Reactants must have proper orientation.

  3. Reactants must collide with sufficient energy to break old bonds.

Factors Impacting Reaction Rates

  • Temperature ( increased temperature = increased kinetic energy = molecules move faster = collision occurs more frequently )

  • Concentration ( higher concentration = more chances of collision )

  • Surface area.

  • Catalyst ( something that speeds up a chemical reaction )

Key Terms

  • Reactants

  • Products

  • Reaction rate

  • Collision theory

  • Activation energy

  • Catalyst

  • Endothermic reaction

  • Exothermic reaction

  • Spontaneous reaction

  • Non-spontaneous reaction

  • Direction of reaction

  • Reversible reaction