Tests for Cations
Tests for Cations
- Metal cations in aqueous solution can be identified by the colour of the precipitate they form on addition of sodium hydroxide and ammonia
- If only a small amount of NaOH is used then normally the metal hydroxide precipitates
Analysing results
The table below contains the results for each of the cations included in the syllabus
If a precipitate is formed from NaOH then the hydroxide is insoluble in water

Method:
Add a few drops of dilute sodium hydroxide (NaOH()aq) into an unknown solution and observe any changes.
- We can test further by adding excess NaOH()aq and recording any changes.
Add a few drops of dilute ammonium hydroxide (NHOH()4aq) into an unknown solution and observe any changes.
- We can test further by adding excess NHOH()4aq and recording any changes.
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