Basic physical properties:
3. How do these forces affect boiling point?
Boiling point (BP) is the temperature at which a liquid boils and becomes a gas.
The basic rule: stronger intermolecular attractions generally mean a higher boiling point.
Why? Because more energy is needed to separate the molecules.
For compounds of similar size, a useful starting point is:
LDF only < Dipole–dipole < Hydrogen bonding
This is a simplified guide, not an absolute ranking for every molecule. Molecular size matters, too.
For example, a longer alkane can have a higher boiling point than a much smaller polar molecule because its LDF may be much stronger.