Valence Electrons and Chemical Behavior

Valence Electrons

  • Valence electrons are those found in the outermost shell (valence shell).
  • The chemical behavior of an atom is mostly determined by its valence electrons, not the electrons in the inner shells.

Elements with One Valence Electron

  • Hydrogen (H), Lithium (Li), and Sodium (Na) each have only one electron in their valence shell.
  • Hydrogen has 1 electron in its first shell, which is its valence shell.
  • Lithium has 3 electrons: 2 in the first shell and 1 in the second (valence) shell.
  • Sodium has 11 electrons: 2 in the first shell, 8 in the second shell, and 1 in the third (valence) shell.
  • These elements behave similarly chemically due to the single electron in their outermost shell.

Filled Outermost Shells and Noble Gases

  • Helium (He) has a filled outermost shell with 2 electrons.
  • Neon (Ne) has a filled outermost shell (second shell) with 8 electrons and a total of 10 electrons (2 in the first shell).
  • Elements with a full valence shell are chemically inert and do not readily participate in chemical reactions; these are called noble gases (Helium, Neon, Argon).
  • Noble gases are very stable and have no tendency to gain, lose, or share electrons.

Grouping of Atoms

  • Atoms are grouped based on the number of electrons in their outermost shell, not the number of protons.
  • Beryllium (Be) and Magnesium (Mg) behave similarly because they both have two electrons in their outermost shell.
  • Magnesium has 12 electrons: 2 in the first shell, 8 in the second shell, and 2 in the third (valence) shell.
  • Beryllium has 4 electrons: 2 in the first shell and 2 in the second (valence) shell.

Electron Orbitals

  • An orbital is the three-dimensional space where an electron is found 90% of the time.
  • This is more specific than describing electrons as orbiting in concentric circles around the nucleus.
  • Each electron shell contains electrons at a particular energy level.
  • Within a particular shell, electrons are distributed among a specific number of orbitals, which have distinctive shapes and orientations.

Orbitals in Neon

  • The first shell has one orbital, called the 1s orbital, which is spherical.
  • The second shell has one 2s orbital (spherical) and three 2p orbitals (dumbbell-shaped).
  • The 2p orbitals are at right angles to one another (along the x, y, and z axes).
  • Each orbital can hold no more than two electrons.
  • The second shell can hold a total of eight electrons: two in the 2s orbital and two in each of the three 2p orbitals.
  • If all orbitals are superimposed, it shows the space where electrons are likely to be found.
  • Electrons do not orbit the nucleus in a predictable pattern but move unpredictably within their orbitals.

Subatomic Particles

  • Atoms are made of subatomic particles: protons (positively charged, in the nucleus), neutrons (neutral, in the nucleus), and electrons (negatively charged, forming a negative cloud around the nucleus).
  • Electrons determine chemical behavior.
  • Helium, with a filled valence shell, does not participate in chemical bonding because it's stable.

Video Explanation

  • Electrons have different energy levels, called shells, which can only fit a certain amount of electrons.
  • Electrons don't orbit the nucleus in a fixed path but are unpredictable.
  • It is impossible to know both where an electron is and where it's going at any given time.
  • Orbitals are specific shapes where electrons live.

Incomplete Valence Shells and Chemical Bonds

  • Atoms with incomplete valence shells can share or transfer electrons with other atoms to complete their outermost shell.
  • Atoms can transfer electrons (give off or accept) or share electrons.
  • Sharing electrons results in chemical bonds that hold atoms together.
  • Sharing of electrons is called covalent bonds, which results in the formation of molecules.

Covalent Bonds

  • A covalent bond results when atoms share a pair of valence electrons.
  • Hydrogen (H) has one proton and one electron, which whizzes around in the 1s orbital.
  • In a covalent bond, shared electrons count as part of each atom's valence shell.
  • Each electron is attracted to the other atom's nucleus.
  • When atoms get close enough, each electron is attracted to the other atom's nucleus.
  • When two hydrogen atoms share electrons, they form a hydrogen molecule held together by a covalent bond.
  • Each hydrogen atom has the benefit of the other one's electron, effectively filling its valence shell.
  • The electron cloud holds the two nuclei together.
  • The sharing of valence electrons completes the outermost shell of each participating atom.