1.4 Thiols

  • General formula: R-SH
  • Name of functional group: sulfhydryl
Properties of Thiols
  • “Stinky” molecules such as skunk, garlic
  • Inorganic H2S is the smell of rotten eggs. Thiols are added to natural gas so we can detect leaks.
  • Thiols can be neutralized with hydrogen peroxide.
  • Due to lack of H bonding, solubility/BP is lower than alcohols.
Naming Thiols
  • Suffix “thiol” is added to the name.

 ![2-methylbutanethiol

](https://knowt-user-attachments.s3.amazonaws.com/7fe854ff604846418511f5dc1aba6312.jpeg)