Chemistry Test Review 11/11
Bond Types and Properties
Types of Bonds
Ionic: Electron transfer; Non-metal + Metal; smallest particle=Formula unit.
Covalent: Electron sharing; Non-metals + non-metals/metaloids. smallest unit=molecule
polar = unpaired sharing
nonpolar = equal sharing
Metallic: Delocalized electrons; Metals + Metal.
Properties
Ionic: Very soluble, High melting point, Strong conductor in solution. (BIG)
Polar Covalent: Soluble, Moderate melting point, Poor conductor. (MEH)
Nonpolar Covalent: Insoluble, Low melting point, Insulator. (SMALL)
Metallic: Insoluble, High melting point, Very good conductor.
Substance Classification
A: Polar; B: Nonpolar; C: Ionic; D: Metallic.
Electronegativity and Compounds
Bond Types Based on Electronegativity
Nonpolar: 0.0 - 0.50
Polar: 0.5 - 1.70
Ionic: 1.70 and greater.
Compounds Classification are based on Electronegativity values.
Nomenclature and Formulas
Prefixes
1 - mono
2 - di
3 - tri
4 - tetra
5 - penta
6 - hexa
7 - hepta
8 - octa
9 - nona
10 - deca
Compound Formulas: Covalent and Ionic classifications with specific examples.
tricarbon octahydride - C3H8
sodium nitrate - NaNO3
lead (II) chlorate - Pb(ClO3)2
silicon dioxide - SiO2
Li2CO3 - lithium chlorate
Cl2O7 - dichlorine heptoxide
N2O4 dinitrogen tetroxide
Cr(NO3)2 - chromium nitrate
***do not reduce number for covalent molecules, ONLY ionic***
Lewis Structures
RULES
total valence elctrons (even number)
place central atom (least electronegative)
subtract the number of electrons used in bonds
assign remaining to lone pairs until octet on terminal atoms
leftover electrons go to the central atom
if the central atom does not have an octet after all other steps, create double and triple bonds (boron and beryllium don’t always need octet)
***Identify Elements in Lewis Structures based on the true octet rule.
FORMAL CHARGE
formal charge = [# of valence electrons on atom] - [non-bonded electrons + # of bonds]
VSEPR Theory
find steric number
determine amount of lone pairs
determine molecular geometry