Chemical Bonds & Intermolecular Forces
Chemical Bonds
- Three types of strong chemical bonds:
Ionic Bonding
- Occurs between metals and non-metals.
- Involves the transfer of electrons in outer shells.
- Metals lose electrons to form positive ions; non-metals gain electrons to form negative ions.
- Electrostatic attraction between oppositely charged ions is ionic bonding.
- Ions formed by Group 1 and 2 metals, and Group 6 and 7 non-metals relate to their group number.
- Group 1 forms 1+ ions, Group 2 forms 2+ ions, Group 6 forms 2- ions, Group 7 forms 1- ions.
- Ionic compounds have giant structures held together by strong electrostatic forces in all directions.
- Empirical formula: Simplest ratio of ions in the giant structure (e.g., NaCl).
Covalent Bonding
- Atoms share pairs of electrons to form strong covalent bonds.
- Covalently bonded substances can be small molecules, large molecules (polymers), or giant covalent structures.
- Limitations of dot and cross diagrams:
- Electrons shown differently, but they are the same.
- Doesn't accurately show bond angles or molecular shape.
- Electrons in outer shells of metal atoms are delocalized and free to move.
- Sharing of delocalized electrons creates strong metallic bonds.
- Metals have a giant structure with atoms in regular patterns.
- Atoms are arranged neatly in rows surrounded by a "sea" of delocalized electrons.
- Metal atoms lose outer shell electrons, resulting in more protons than electrons, thus becoming positively charged.