Chemical Bonds & Intermolecular Forces

Chemical Bonds

  • Three types of strong chemical bonds:
    • Ionic
    • Covalent
    • Metallic

Ionic Bonding

  • Occurs between metals and non-metals.
  • Involves the transfer of electrons in outer shells.
  • Metals lose electrons to form positive ions; non-metals gain electrons to form negative ions.
  • Electrostatic attraction between oppositely charged ions is ionic bonding.
  • Ions formed by Group 1 and 2 metals, and Group 6 and 7 non-metals relate to their group number.
    • Group 1 forms 1+ ions, Group 2 forms 2+ ions, Group 6 forms 2- ions, Group 7 forms 1- ions.
  • Ionic compounds have giant structures held together by strong electrostatic forces in all directions.
  • Empirical formula: Simplest ratio of ions in the giant structure (e.g., NaCl).

Covalent Bonding

  • Atoms share pairs of electrons to form strong covalent bonds.
  • Covalently bonded substances can be small molecules, large molecules (polymers), or giant covalent structures.
  • Limitations of dot and cross diagrams:
    • Electrons shown differently, but they are the same.
    • Doesn't accurately show bond angles or molecular shape.

Metallic Bonding

  • Electrons in outer shells of metal atoms are delocalized and free to move.
  • Sharing of delocalized electrons creates strong metallic bonds.
  • Metals have a giant structure with atoms in regular patterns.
  • Atoms are arranged neatly in rows surrounded by a "sea" of delocalized electrons.
  • Metal atoms lose outer shell electrons, resulting in more protons than electrons, thus becoming positively charged.