Anti-Diabetes Drug Mechanisms and Classifications
Anti-Diabetes Drugs
Presenter: Dr. Bipin
References: Lipponcort, Tripathi, and Internet
Diabetes Mellitus Overview
Definition: Diabetes mellitus (DM) is a metabolic disorder characterized by:
Hyperglycemia:
Fasting plasma glucose ≥ 126 mg/dl
2 hours after 75 g oral glucose ≥ 200 mg/dl
Additional Features:
Glycosuria (glucose in urine)
Hyperlipidemia (elevated lipids in the blood)
Negative nitrogen balance (improper balance between nitrogen intake and output)
Sometimes ketonemia (presence of ketones in the blood)
Pathological Changes:
Thickening of capillary basement membrane.
Increased vessel wall matrix and cellular proliferation leading to:
Vascular complications such as lumen narrowing
Early atherosclerosis
Sclerosis of glomerular capillaries
Retinopathy (damage to retina)
Neuropathy (nerve damage)
Peripheral vascular insufficiency
Blood Glucose Level Chart
Over 3 Months:
Category
HbA1c (%)
Fasting Mg/DL
Fasting mmo/L
After Meal Mg/DL
After Meal mmo/L
2-3 hrs after meal Mg/DL
2-3 hrs after meal mmo/L
Normal
4-5.6%
80-100
4.4-5.5
170-200
9.4-11.1
120-140
6.7-7.8
Elevated
5.7-6.4%
101-125
5.6-6.9
190-230
10.6-12.8
140-160
7.8-8.9
High
> 6.5%
> 126
> 7.0
220-300
12.2-16.7
> 200
> 11.1
Units:
(US) mg/dL: milligrams per deciliter
(UK) mmo/L: millimoles per liter
Types of Diabetes Mellitus
1. Type I Diabetes Mellitus (IDDM)/Juvenile Onset:
Characterized by:
Destruction of β cells in the pancreatic islets
Majority of cases are autoimmune (Type 1A) where antibodies against β cells are detectable; some are idiopathic (Type 1B) with no antibodies found
Low or very low circulating insulin levels
Higher propensity for ketosis
Less common with low genetic predisposition
2. Type II Diabetes Mellitus (NIDDM)/Maturity Onset:
Generally involves:
No loss or only moderate reduction in β cell mass
Insulin levels may be low, normal or even high
No demonstrable anti-β-cell antibodies
High genetic predisposition
Generally late onset (past middle age)
More than 90% of diabetes cases are Type 2 DM
Approaches to Drug Therapy in Type II DM
Goals include:
Improving insulin availability
Overcoming insulin resistance
Medication Classes:
Exogenous insulin
Sulfonylureas
Meglitinide/Phenylalanine analogues
Biguanides (Metformin)
Thiazolidinediones (Pioglitazone)
Alpha-glucosidase inhibitors
Dipeptidyl peptidase-4 inhibitors (DPP-4 inhibitors)
GLP-1 receptor agonists
Limitations/Challenges:
Multiple daily injections (insulins)
Hypoglycemic episodes
Weight gain
Concerns about premature atherosclerosis due to hyperinsulinemia
Inability to achieve normoglycemia by themselves in many patients, especially in moderate-to-severe cases
Insulin Overview
Discovery:
Discovered in 1921 by Banting and Best; demonstrated its hypoglycemic action
First obtained in pure crystalline form in 1926; structure worked out in 1956 by Sanger
Structure:
A two-chain polypeptide consisting of 51 amino acids with molecular weight ~6000.
A-chain: 21 amino acids
B-chain: 30 amino acids
Differences: Between human, pork, and beef insulins exist
Regulation of Insulin Secretion
**Secretion Rate:
Basal condition:** ~1U insulin is secreted per hour by the human pancreas.
After meals, a much larger quantity is secreted.
Regulatory Mechanisms:
Chemical Mechanisms:
Pancreatic β cells have a glucose sensing mechanism based on glucose entry (via glucose transporter GLUT1) and phosphorylation by glucokinase.
Activation of glucosensor leads to increased ATP, which inhibits ATP-sensitive K+ channels (K+ATP) and partially depolarizes β cells.
Increases intracellular Ca²+ availability leading to insulin exocytosis.
Other nutrients (amino acids, fatty acids, ketone bodies) also elicit insulin release, but glucose is the principal regulator.
Glucose induces a quick initial output of insulin within 2 minutes (first phase) followed by a sustained second-phase release.
Hormonal Regulation
Hormonal Influences:
Hormones such as growth hormone, corticosteroids, and thyroxine modify insulin release in response to glucose.
Intra-islet paracrine interactions are significant.
Different islet cell types (α cells, β cells, and δ cells) interact to provide precise control of insulin release.
Neural Regulation
The islets are richly supplied by sympathetic and vagal nerves.
Adrenergic α2 receptor activation: Decreases insulin release by inhibiting β cell adenylyl cyclase.
Adrenergic β2 stimulation: Increases insulin release by stimulating β cell adenylyl cyclase.
Cholinergic Activation: Insulin secretion via IP3/DAG pathway increasing intracellular Ca²+ in β cells.
Actions of Insulin
Overall Effects:
Insulin is a major anabolic hormone that promotes the synthesis of glycogen, lipids, and protein and facilitates glucose transport across cell membranes.
Detailed Actions:
Facilitates glucose transport across cell membrane:
Skeletal muscle and adipose tissue are sensitive to insulin.
Glucose entry in certain cells is largely independent of insulin (e.g., liver, brain).
Muscular activity stimulates glucose entry into muscle.
Glucose transporter glycoproteins (GLUT4) are regulated by insulin for translocation.
Long-term, insulin upregulates GLUT4 synthesis.
Intracellular utilization:
Glucose is phosphorylated to glucose-6-phosphate, enhanced by insulin's action on glucokinase.
Stimulates glycogen synthesis and inhibits glycogenolysis in liver and muscle.
Inhibits gluconeogenesis:
Reduces glucose production from proteins and fats in the liver.
In insulin deficiency, proteins are routed to form glucose, worsening hyperglycemia.
Inhibits lipolysis:
Reduces fatty acid and glycerol breakdown, favoring triglyceride synthesis.
Excess lipid breakdown in diabetes leads to ketone body production.
Enhances transcription of lipoprotein lipase:
Acceleration of the clearance of VLDL and chylomicrons.
Facilitates amino acid uptake:
Promotes protein synthesis and inhibits protein breakdown.
Insulin deficiency leads to protein breakdown and negative nitrogen balance.
Summary of Insulin Effects on Body Systems
Liver:
Increases glucose uptake and glycogen synthesis
Inhibits glycogenolysis and gluconeogenesis
Muscle:
Increases glucose uptake
Inhibits protein breakdown
Adipose Tissue:
Increases glucose uptake and triglyceride storage
Inhibits lipolysis
Diabetic State Actions
In the diabetic state, catabolism outweighs anabolism. Rapid actions of insulin generally occur within seconds/minutes, while others involving DNA-mediated synthesis take hours (intermediate actions). Long-term effects of insulin involve cell differentiation and multiplication.
Fate of Insulin
Insulin is distributed extracellularly; it is peptide in nature and is degraded in the gastrointestinal system if given orally.
Insulin metabolism occurs primarily in the liver, with a t1/2 of 5-9 minutes. Nearly half of the insulin in the portal vein is inactivated in the liver.
Types of Insulin Preparations
Rapid-Acting Insulin:
Examples: Insulin lispro, Insulin aspart, Insulin glulisine.
Onset: 0.2-0.4 hours, Duration: 3-5 hours.
Short-Acting Insulin:
Example: Regular insulin.
Onset: 0.5-1 hour, Duration: 6-8 hours.
Intermediate-Acting Insulin:
Example: NPH insulin.
Onset: 1-2 hours, Duration: 12-20 hours.
Long-Acting Insulin:
Examples: Insulin glargine, Insulin detemir.
Onset: 1-4 hours, Duration: ~24 hours.
Ultra-Long Acting:
Insulin degludec (lasts over 42 hours).
Pre-Mixed Insulin:
Humulin M3, NovoMix 30, etc.
Onset: Biphasic 30-60 min, Duration: Up to 24 hours.
Mechanism of Action of Insulin
Receptor Binding: Insulin binds to a specific tyrosine kinase receptor on target cells, which leads to:
Autophosphorylation of the β-subunits of the receptor.
Signal Transduction: Phosphorylation cascade that translocates GLUT-4 vesicles to the cell membrane, facilitating glucose uptake.
Metabolic Effects:
In liver: Stimulates glycogenesis, inhibits gluconeogenesis and glycogenolysis
In adipose: Stimulates lipogenesis and inhibits lipolysis
In muscle: Enhances amino acid uptake and protein synthesis
Electrolyte Effect: Drives potassium (K+) into cells via Na+/K+-ATPase pump.
Primary Indications for Insulin Use
Type 1 Diabetes Mellitus (T1DM): Essential and life-saving therapy.
Type 2 Diabetes Mellitus (T2DM): Used when glycemic targets are not met with lifestyle changes and other agents.
Gestational Diabetes Mellitus: Used when medical nutritional therapy fails.
Stressful Conditions Requiring Insulin
Diabetic Ketoacidosis (DKA) and Hyperosmolar Hyperglycemic State (HHS): Cornerstone of management, typically with IV regular insulin.
Acute Hyperkalemia: Administer insulin to shift potassium intracellularly.
Diabetes Secondary to Other Conditions: E.g., pancreatitis, pancreatectomy, cystic fibrosis.
Stress-Induced Hyperglycemia: In hospitalized patients, e.g., during critical illness.
Dosing and Administration
General Principles: Insulin dosing is personalized based on glycemic targets, age, weight, renal function, diet, and activity. Frequent monitoring is crucial for titration.
Dosing for Type 1 Diabetes: 0.4 - 1.0 units/kg/day; typical regimen is basal-bolus.
Dosing for Type 2 Diabetes: Starting doses often lower; common starting point for basal insulin is 10 units/day or 0.1-0.2 units/kg.
Switching and Titration of Insulin
Adjust doses based on fasting and postprandial glucose.
A common rule: increase dosage by 2 units or 10-15% twice weekly until targets are met.
Adverse Effects of Insulin
Hypoglycemia: Most common and dangerous effect.
Weight Gain: Due to anabolic effects of insulin.
Injection Site Reactions: Lipohypertrophy, lipoatrophy, and allergic reactions.
Systemic Allergy: Rare but can result in anaphylaxis.
Insulin Resistance: High doses may be needed due to various factors; transient edema and blurred vision can occur.
Contraindications and Precautions
Absolute Contraindication: Hypoglycemia.
Relative Precaution: Hypersensitivity to insulin or its excipients.
Conditions Requiring Dose Adjustment: Various conditions can alter insulin needs.
Drug Interactions
Drugs that Decrease Insulin Requirements: Oral antidiabetics, ACE inhibitors, Alcohol, etc.
Drugs that Increase Insulin Requirements: Corticosteroids, Thiazide diuretics, etc.
Drugs that Mask Hypoglycemia Symptoms: Non-selective beta-blockers.
Overview of Major Classes of Antidiabetic Drugs
## Biguanides (Metformin)
Mechanism: Activates AMP-kinase, reduces hepatic gluconeogenesis and increases peripheral insulin sensitivity.
Indications: First-line for T2DM, prediabetes, gestational diabetes, PCOS.
Side Effects: GI symptoms, B12 deficiency, lactic acidosis risk.
Sulfonylureas
Mechanism: Acts on pancreatic beta cells to stimulate insulin release.
Indications: T2DM when Metformin is not effective.
Important: Can cause hypoglycemia and weight gain.
Meglitinides (Glinides)
Mechanism: Similar to sulfonylureas with a rapid onset and short duration.
Indications: Post-prandial hyperglycemia management.
Thiazolidinediones (TZDs)
Mechanism: Agonists of PPAR-γ increasing insulin sensitivity.
Indications: T2DM often in combination therapy.
Caution: Risk of heart failure.
DPP-4 Inhibitors (Gliptins)
Mechanism: Inhibit DPP-4 to prolong action of incretin hormones.
Indications: Add-on for T2DM patients.
SGLT2 Inhibitors (Gliflozins)
Mechanism: Inhibit SGLT2 in kidneys, causing glucosuria.
Indications: T2DM, heart failure, chronic kidney disease.
Alpha-Glucosidase Inhibitors
Mechanism: Inhibit enzymes that digest carbohydrates, reducing post-prandial glucose spikes.
Oral GLP-1 Receptor Agonists
Mechanism: Modulate glucose-dependent insulin secretion and slow gastric emptying.
Conclusion
Primary Drug of Choice: Always start with Metformin unless contraindicated.
Considerations in Therapy: Always remember individual patient needs and emerging clinical guidelines to effectively manage diabetes.