Reactivity of Metals and Reaction Rates

Displacement Reactions

  • Displacement observations: Magnesium forms a brown coating when reacting with copper solutions (identifying the coating as Copper metal) but shows no change in magnesium sulfate solution.

  • Reactivity series determination: Magnesium > Aluminium > Metal X > Copper.

  • Identity of Metal X: Zinc.

Investigation: Reaction with Hydrochloric Acid

  • Research Question: Determining how the type of metal (MgMg, AlAl, ZnZn, FeFe, CuCu ) affects the rate of reaction (cm3/s\text{cm}^3/\text{s}) when 1.0g1.0\,\text{g} of metal reacts with dilute hydrochloric acid.

  • Hypothesis: Magnesium > Aluminium > Metal X > Copper because metals higher in the reactivity series lose electrons more readily to form positive ions.

  • Variables:

    • Independent: Type of metal used (MagnesiumMagnesium, AluminiumAluminium, MetalXMetal X, CopperCopper).

    • Dependent: Rate of hydrogen (H2H_2) production per unit time (cm3/s\text{cm}^3/\text{s}).

    • Controlled: Concentration of hydrochloric acid, temperature of reactants, surface area of metal, mass of metal used (1.0g1.0\,\text{g}), and volume of hydrochloric acid (25cm325\,\text{cm}^3).

Experimental Procedure and Data

  • Methodology: 1.0g1.0\,\text{g} of metal is added to 25cm325\,\text{cm}^3 of acid in a conical flask; hydrogen gas volume is recorded via gas syringe every 20s20\,\text{s} for a total of 120s120\,\text{s}.

  • Results and Evidence:

    • Magnesium: Reacted most vigorously, producing 74cm374\,\text{cm}^3 of hydrogen gas after 120s120\,\text{s}.

    • Copper: Produced 0cm30\,\text{cm}^3 of hydrogen gas, showing no visible reaction.

    • Conclusion: The acid experiment results support the displacement series order.

Method Evaluation and Improvements

  • Aluminium's Oxide Layer: The presence of an oxide layer caused AluminiumAluminium to produce only 35cm335\,\text{cm}^3 of gas compared to MetalXMetal X (Zinc) producing 37cm337\,\text{cm}^3, contradicting the expected order. Improvement: Sand the aluminium surface before testing.

  • Limited Trials: Only one trial per metal was performed, making it difficult to distinguish real differences from random error. Improvement: Conduct at least three trials and calculate a mean.

  • Gas Loss: Potential hydrogen escape from the apparatus could lead to lower-than-expected volumes. Improvement: Ensure all bungs and gas syringe connections are airtight.