chemistry

Matter and its properties

What is matter?

matter is anything that has a mass and takes up space(volume)

all matter has two things in common: mass and volume.

mass: the amount of matter in an object or sample

  • units: kilogram(k), gram(g), miligram(mg)

volume: the amount of space that a material takes up

  • units: solid - cubic metres(m³), cubic centimetres(cm³)

  • gas or liquid - litres(L), mililitres(mL)

What are some ways to describe matter?(properties of matter)

matter can be described based on its physical properties and chemical properties

physical properties: characteristics of matter that can be observed or measured without changing its chemical identity

some examples include:

  • melting point: the temperature at which a substance changes from solid to liquid state

  • boiling point: the temperature at which a substance changes from liquid to gaseous state

  • malleability: describes how easily a substance can be hammered or bent into different shapes

  • hardness: describes the resistance of a solid to being scratched or dented

  • solubility: describes the ability of a substance to dissolve in a solvent

  • viscosity: describes how quickly a substance flows in liquid form

  • density: quantity of mass in a certain volume of material

chemical properties: ability of matter to react with another substance to form one or more new substances

can only be observed when a substance chemically interacts or reacts with another substance

some examples include:

  • reactivity with acids: some substances react vigorously with acids and others do not. Ex. baking soda and vinegar produce a gas

  • reactivity with oxygen: substances in some objects react with oxygen when exposed to air. Ex. avocadoes turning brown, rusting nails

  • combustibility: ability of material to catch fire and burn in the air. Ex. burning wood

  • lack of reactivity: substances that do not react with other substances are “inert”. Ex. helium in balloons

Matter also undergoes changes: physical change vs. chemical change

physical change: change of matter that does not change its chemical identity or composition

some examples include:

  • freezing of water(liquid) to form ice(solid)

    • Liquid water(h2o) → solid water(h2o)

  • cutting a paper into pieces

chemical change: change of matter that produces one or more products. When a new chemical substance is created, it is a chemical change

some examples include:

  • 2h + o → h2o (formation of water)

  • toasting bread(evidence of new substances forming: colour, smell of bread change when you toast it)

how do we know a new chemical has formed?

Here are some clues:

  • a new substance or material appears

  • emission, sound or light are given off

  • bubbles of gas are formed(not boiling water)

  • a solid material appears when two liquids are mixed(a precipitate)

Two different types of matter data: qualitative vs. quantitative data

qualitative data: can be observed and compared using words(subjective)

some examples include:

  • sight

  • odour

  • texture

  • state

  • etc.

quantitative data: can be measured and recorded by using numbers(objective)

some examples include:

  • there are 8 dolphins in this pod

  • the boiling point of water is 108C

  • the dolphin is 1.45m in length

Classifications of matter

matter can be classified as:

  • mixture: can be separated into parts by physical changes

    • eg. trail mix, salt water

  • pure substances:

    • elements: cannot be separated or broken down by physical or by chemical changes

    • compounds: can be broken down into 2 or more elements by chemical changes but not by physical changes

      • eg. h2o → 2h + o

Measuring volume and density

volume: the amount of space taken up by a substance or object

volume of solid measured in cubic centimetre(cm³) or cubic metre(m³)

volume of liquid + gases measured in litres(L) or millilitres(mL)

volume is determined by:

  • viewing the measurement of a liquid in a container(mL)

  • volume of a rectangular prism(cm³) = length(cm) * width(cm) * height(cm)

  • using a displacement method in a container to measure and irregular shaped object(mL)

    • volume of solid + (volume of water + solid) - (volume of water)

measuring volume:

we use volumetric/graduated flasks to measure volume precisely

when we read the reading, we look at the lowest point of the meniscus

metric system:

an international system of measuring(based on multiples of 10):

  • m,mm,km for length

  • grams for mass

  • secs for time

  • mL, cm³ for volume

  • g/mL, g/cm³ for density

  • celsius for temperature

fluids and density

a fluid is any form of matter that can flow

liquids and gases are fluids since they do not have a fixed shape or volume

solids are not fluids as they have a fixed shape

density of matter(solids, liquids, and gases)

density is the amount of material(mass) for each unit of space it occupies(volume)

density and layers of fluids

fluids that do not mix separate themselves according to their density

less dense fluids settle on top of more dense fluids

density of water is 1g/mL

units for measuring density:

fluids: g/mL

solids: g/cm³

calculating density

density = mass/volume

practice question:

Q. What is the density of a 4cm³ rock that has a mass of 24g?

A. D = (mass/volume) = 24g/4cm³ = 6g/cm³

Q. a 5mL sample of motor oil has a mass of 4.5 g. What is the density of the motor oil?

A. D = mass/volume = 4.5g/mL = 0.9g/mL

Buoyancy

buoyancy is a physical property that is directly proportional to the density of the fluid in which an object immersed(in a fluid)

it is the tendency to rise or float in a fluid

you can think of it as the “upward thrust” or “upward force”

Viscosity

viscosity is a physical property that can be used to describe liquids

it is the measure of resistance to deformation at a given rate

you can think of it as the “thickness” of a liquid

states of matter

matter is made up of tiny particles in atoms and molecules

matter can be found in 4 states: solids, liquids, gas, and plasma

solid

liquid

gas

plasma

example

  • wood

  • silver

  • stone

  • plastic

  • oil

  • juice

  • antifreeze

  • gasoline

  • air

  • helium

  • gasoline

  • stars/the sun

  • lightning bolt

  • neon signs

properties

  • holds its own shape

  • has a constant volume

  • takes the shape of its container

  • has a constant volume

  • takes the shape and volume of its container

  • can be compressed

  • does not have a fixed shape and volume(similar to gas)

  • has different electrical properties than gases

Kinetic molecular theory

a model is a verbal, mathematical or visual representation of a scientific structure or process

theory is a scientific explanation that has been supported by consistent repeated experimental results and is therefore accepted by most scientists

the scientific explanation of the behavior of matter based on all matter being made of particles that possess kinetic energy is called Kinetic Molecular Theory of Matter(KMT)

kinetic energy is the energy of motion

even though we cannot see with out naked eyes, all particles are always moving and therefore possess kinetic energy

energy makes particles move. the more energy the particles have, the faster they can move and the further apart they can get

particles stop moving at zero Kelvin(K), which is -273C

states of matter

KMT states…

particles in solid

particles are very close together

particles vibrate but cannot move around

particles attract one another strongly in a rigid structure

particles in liquid

particles are also very close together but can move around

particles slip and slide past and revolve around each other but stay close together

they attract one another less strongly than in solids

particles in gas

particles are very far apart compared to their size

move around randomly and quickly in straight lines

attraction to one another is effectively zero

particles are constantly moving

energy makes particles move

the more kinetic energy the particles have, the faster they move and the farther apart they get

more energy → faster movement → particles move farther apart

gas > liquid > solid

more kinetic energy → less kinetic energy

The effect of temperature on matter

Lesson Explainer: Changes of State | Nagwa

changes of state occur when matter transforms from one state to another

example: liquid(water) to solid(ice)

when temperature increases, particles gain energy and move faster and further apart

liquid to gas - evaporation/vaporization

gas to liquid - condensation

liquid to solid - freezing

solid to liquid - melting

gas to solid - deposition

solid to gas - sublimation

changes of state and temperature

temperature is the measure of the average kinetic energy of particles in a substance

increasing the temperature of matter means the particles of the matter are gaining energy

once the matter reaches a certain temperature, the particles have gained enough energy to change state

the temperature at which a substance melts is called its melting point(solid to liquid)

the temperature at which a substance boils is called its boiling point(liquid to gas)

Phase Change Diagrams — Overview & Examples - Expii

KMT explains diffusion and thermal expansion/contraction

diffusion is the movement of particles from an area of high concentration to low concentration

solids liquids and gases expand when heated and contract when cooled

thermal expansion is the increase in volume of a substance when its temperature is increased

  • heating increases kinetic energy of particles

thermal contraction is the decrease in volume of a substance when its temperature is lowered

  • cooling decreases kinetic energy of particles

The atom

the smallest particle of an element is an atom

the atom is made up of

  • the nucleus which is made up of protons and neutrons

  • electrons

The atomic theory: all matter is made up of particles called atoms

what is a nucleus?

the center region of an atom is the nucleus

the nucleus of most hydrogen atoms contain only 1 proton

the nucleus of all other atoms contain both protons and neutrons

what is the mass number?

the atomic mass is the total number of protons and neutrons

what is a proton and an electron?

a proton is a positively charged subatomic particle while an electron is a negatively charged subatomic particle

the number of protons in a nucleus determine the atomic number of the nucleus and the identity of an atom

protons are also called “elementary particles”

the region that electrons occupy is called energy shells, which surround the nucleus

an electron is like a spread out cloud of high energy that exists in the whole region. it is also called an electron cloud

electrons do not have a mass → not matter

protons, electrons and neutrons are classified as subatomic particles

for a neutral(not charged) atom, the number of protons is equal to the number of electrons.

in this case, the number of electrons in a neutral atom is 6

what is a neutron?

a neutral subatomic particle found in the nucleus

summary:

name

symbol

electric charge

location in the atom

proton

p+

positive(+)

nucleus

neutron

n0

neutral/none

nucleus

electron

e-

negative(-)

energy shells around the nucleus

atomic number = no. of protons

atomic mass = no. of protons + no. of neutrons

neutral atom = no. of protons = no. of electrons

periodic table

as chemists discovered more elements, they saw the need of organizing all the elements in a consistent way, hence the periodic table

development of the periodic table

by arranging elements in order of increasing atomic mass into columns, Dmitri Mendeleev created the first periodic table

as more and better technology became available, chemists made a significant change to Mendeleev’s method of organizing the elements. the modern periodic table is organized according to the atomic number rather than the atomic mass

why is the periodic table important?

the table acknowledges the existence and properties of all elements

what are elements, compounds and mixtures?

elements are composed of:

  • only one type of atom

  • atoms can exist individually or in compounds(molecules)

  • cannot be separated or broken down by physical or chemical changes

compounds: can be broken down into two or more elements by chemical changes but not physical changes

mixtures: can be separated into parts by physical changes

the major divisions within the periodic table

the set of all elements in a given row going across the table is called a period

the row shows the number of energy shells the element has

the set of all the elements in a given column going down the table is called a group/family

they have the same number of electrons on the outermost shell, hence they have similar chemical properties

group 1: alkali metals

group 2: alkaline earth metals

group 17: halogen

group 18: noble gas - they are the most stable because they have full energy shells

elements on the periodic table are divided into three kinds

example of metals: group 1(sodium), group 2(calcium) and transition metal

example of non-metals: noble gases, halogens and oxygen

example of metalloids: baron, arsenic and silicon(which means they have properties that are a mix between those of metals and solid non-metals)

Periodic Table Metals and Non-Metals | ChemTalk