Nuclear Chemistry 1.1
Radioactive Emissions
Alpha Emission- nucleus emits an alpha particle which consists of 2 protons and 2 neutrons, positively charged with a mass number of 4
- After alpha emission, the atom will have two fewer protons and two fewer neutrons CHANGE ELEMENTS
- Relatively large, slow-moving particle, blocked by a sheet of paper
Beta Emission- The nucleus emits a beta particle which is a high-speed electron, negatively charged with a mass number of 0
- Beta particles form when a neutron is converted into a proton and an electron, (the electron gets ejected from the nucleus)
- After beta emission, the atom will have one less neutron but one more proton
- Massless, fast-moving particle, blocked by 100 sheets of paper
Gamma Emission- The nucleus emits a photon of pure energy, no charge, and no mass
- High energy, very penetrating, not completely blocked by lead, present with almost every other radioactive emission
no change to the atom
Positron Emission- The nucleus emits a beta plus particle which is called a “positron”
- positively charged with a mass number of 0
- Formed in the nucleus when a proton is converted into a neutron and a positron is ejected
- massless, positively charged particle
- doesn’t penetrate matter because it quickly collides with electrons after leaving the nucleus and produces gamma radiation
Electron Capture- The nucleus absorbs an electron
- An inner shell electron is pulled into the nucleus where it combines with a proton to form a neutron.
- During electron capture, the atom loses an electron and a proton but gains a neutron
Results in the emission of an X-ray as a higher energy electron moves to a lower energy level to fill the vacancy left by the captured electron
Radioactive Atoms
- All atoms with more than 83 protons are radioactive
- No number of neutrons can exert enough force to overcome that much repulsion
- Any atom that does not have the optimum proton-to-neutron ratio is defined by the “belt of stability” graph.
Half-Life
Half life- The amount of time it takes for half of a sample to react or decay.
- The half-life of specific radioisotopes is constant but varies for each type of @@element@@
- Radioactive decay processes follow a “1st order” rate law which means that the time it takes for half of a sample to decay is @@independent@@ of the size of the sample.
The half life of a radioactive decay process does not change based on how large or how small the sample is.
amount remaining=initial amount * (1/2)^n
Nuclear Fission and Fusion
Nuclear Fusion
Bombardment- Small high-speed particles are fired at the nuclei of atoms causing a change inside the nucleus, going INTO the nucleus
- This change can result in huge releases of energy
- If two or more atoms slam into each other with enough energy and speed, their nuclei might fuse or join together to become one new, larger nucleus.
- Requires high temps, used in hydrogen bombs
Nuclear Fission
The splitting of a heavy nucleus into smaller fragments by hitting it with a high-speed particle (often a neutron)
- Used at nuclear power plants to produce electricity and used to make nuclear bombs.