Concentration of Ions

Understanding Resting Membrane Potential and Action Potentials

Importance of Ion Flow in Membrane Potentials

  • Resting membrane potential and action potentials are closely related to the flow of ions through channels when opened.
  • It is necessary to comprehend the ion concentrations across the cell membrane, specifically:
    • Intracellular fluid
    • Extracellular fluid

Ion Concentrations Across the Cell Membrane

  • Students are typically asked to accept specified ion concentrations without question.
  • Personal acknowledgment: The author found it challenging to simply memorize these concentrations without comprehension.
  • Aim: To provide a narrative or framework for understanding how ion concentrations arise between the inside and outside of the cell.

The Concept of Neutrality in Cells

  • Within the cell:
    • The environment is said to be electrically neutral.
  • Author's prior explanation:
    • The universe, in its entirety, tends to be electrically neutral as well.
    • Example: Atoms within a defined volume, like those in a pen, represent molar concentrations.
Molar Concentrations and Avogadro's Number
  • Avogadro's number: Approximately 6.022×10236.022 \times 10^{23} atoms/moles.
  • Discussion of how large quantities lead to a net neutrality, both in the universe and within organelles such as cells.
Concept of Average in Classes of Students (Analogy)
  • Analogy used: Average age of a selection of students can reflect the average age of an entire class (
    • In a class of 30 or 40 students, taking the average of just a few students still approximates the class's overall average closely.
  • This concept is applied to how we think about charges and ions within a cell.

Charge Separation Across Membranes

  • Neutrality within the entire system does not mean charges are uniformly distributed.
  • Charge separation occurs:
    • Negative charges align on the inside of the membrane.
    • Positive charges align on the outside near the membrane oxygenation.
  • Concept led to the development of voltage across the membrane due to this charge separation.

Ion Concentrations Across Membranes

Potassium (K⁺)
  • Concentration inside the cell: approximately 140 millimolar (mM).
  • Concentration outside the cell: approximately 5 mM.
  • Two measurement methods:
    • Milliequivalents per liter (meq/L)
    • Millimoles per liter (mM)
  • Inside the cell potassium is approximately 150 meq/L and outside is about 4 meq/L.
  • Importance of potassium in cell function:
    • Higher concentration inside may be due to early biological processes and evolution.
    • Potassium channels allow K⁺ to move based on concentration gradients.
Sodium (Na⁺)
  • Concentration outside the cell: approximately 140 mM or 145 meq/L.
  • Concentration inside the cell: approximately 15 mM or 12 meq/L.
  • Sodium concentrations inform directional flow into the cell when channels open.
Chloride (Cl⁻)
  • Concentration outside the cell: approximately 110 mM.
  • Concentration inside the cell: approximately 4-30 mM.
  • Cl⁻ remains a negatively charged ion and its distributions are important for understanding cellular resting potentials.
Calcium (Ca²⁺)
  • Concentration outside the cell: approximately 1-2 mM.
  • Concentration inside the cell: approximately 0.0001 mM.
  • Calcium is significant as it carries a double positive charge, influencing charge dynamics across membranes.

Summary of Ion Movement and Concentrations

  • Overall presentation of charges:
    • Outside the cell: roughly 145 positive charges, balanced by 110 negative charges.
    • Inside the cell: approximately 140-155 positive charges balanced by negatively charged proteins.
    • Potassium exits the cell, creating a surplus of positive charges outside.
    • Sodium, chloride, and calcium concentrations also contribute dynamically to charge states.

Final Notes on Concentrations and Ion Movement

  • Knowledge of these concentrations seems crucial for understanding ion movements:
    • K⁺ moves out of the cell.
    • Na⁺, Cl⁻, and Ca²⁺ move into the cell.
  • Awareness of these concepts will support deeper comprehension of membrane potentials and cellular behavior when channels open.