Ch2

2.1 Atoms and Atomic Bonds

  • Matter

    • Refers to anything that takes up space and has mass.

    • Can exist in three states: solid, liquid, or gas.

    • Composed of elements.

  • Element

    • A substance that cannot be broken down into another substance by ordinary chemical means.

    • There are 92 naturally occurring elements.

    • Four elements that make up about 96% of the body weight of most living organisms:

    • Carbon (C)

    • Hydrogen (H)

    • Oxygen (O)

    • Nitrogen (N)

Where Do Elements Come from?

  • Normal chemical reactions do not produce elements.

  • Heavier elements, such as iron, are produced during supernova explosions.

  • Supernovas scatter heavier elements into space, where they eventually become part of planets.

  • Notably, the iron found in blood originates from these stellar explosions.

  • Quote by Neil deGrasse Tyson: "After all, what nobler thought can one cherish than that the universe lives within us all?"

Atomic Structure

  • Atomic Theory: States that elements consist of atoms.

  • Atomic Symbol: Represents the name of the atom or element (e.g., H for hydrogen, Na for sodium).

  • Subatomic Elements:

    • Neutrons: No electrical charge, located in the atomic nucleus.

    • Protons: Positive charge, also in the nucleus.

    • Electrons: Negative charge, found outside of the nucleus, moving in orbitals.

  • Mass Number: The sum of protons and neutrons (electrons are negligible in mass).

  • Atomic Weight: This varies with gravitational pull.

Atomic Number

  • Atomic Number: All atoms of an element have the same number of protons.

  • This also indicates the number of electrons if the atom is electrically neutral.

  • Periodic Table:

    • Elements are organized such that their chemical and physical characteristics recur in a predictable manner.

    • Atoms are arranged into periods (rows) and groups (columns).

Isotopes

  • Isotopes: Atoms of the same element that differ in the number of neutrons.

  • Isotopes have the same number of protons but a different number of neutrons which results in different mass numbers.

  • Characteristics:

    • Some isotopes are unstable and may decay, emitting radiation.

    • They can be used for medical imaging (e.g., PET scans).

    • Can cause cellular damage leading to cancer.

    • Useful for sterilizing medical equipment.

Arrangement of Electrons in an Atom

  • Electron Configuration: Electrons are in constant motion, and can be modeled with energy levels or electron shells.

  • The first shell can hold up to two electrons.

  • Each subsequent shell can hold up to eight electrons.

  • Octet Rule:

    • Valence shell is the outermost shell.

    • Stability occurs when the outer shell has eight electrons.

    • Atoms can give up, accept, or share electrons to achieve a stable configuration.

    • Chemical properties of atoms are primarily determined by the arrangement of their electrons.

Types of Chemical Bonds

  • Molecule: A group of atoms bonded together (e.g., O2 for oxygen gas, H2O for water).

  • Compound: A molecule containing atoms of at least two different elements (e.g., NaCl or H_2O).

  • Ionic Bonds:

    • Formed when electrons are transferred between atoms, creating ions.

    • Ion: An atom or molecule with an electrical charge due to the loss or gain of electrons.

    • Cation: A positively charged ion (loses electrons).

    • Anion: A negatively charged ion (gains electrons).

    • Occur typically between a metal and a nonmetal.

    • The attraction between oppositely charged ions forms the bond (e.g., Na^+ and Cl^- form NaCl).

  • Covalent Bonds:

    • Formed when atoms share electrons to achieve a stable outer shell.

    • Can occur between two nonmetal atoms.

    • Nonpolar Covalent Bonds: Electrons are shared equally between the atoms (e.g., O2, H2).

    • Polar Covalent Bonds: Electrons are shared unequally, resulting in partial positive and partial negative charges on different parts of the molecule (e.g., H_2O). Oxygen is more electronegative than hydrogen, pulling electrons closer to itself.