BIO 201 : lecture 3

Isotopes
  • Isotopes are atoms of the same element that have the same number of protons but different numbers of neutrons.

  • Since they are the same element, they have the same atomic number but different mass numbers.

  • Example: Hydrogen has three common isotopes:

    1. Protium (\text{^1H}): 1 proton, 0 neutrons (most common).

    2. Deuterium (\text{^2H}): 1 proton, 1 neutron.

    3. Tritium (\text{^3H}): 1 proton, 2 neutrons (radioactive).

  • The chemical properties of isotopes are generally very similar because they depend primarily on the number of electrons (which is equal to the number of protons in a neutral atom), while physical properties like density can differ.

Chemical Bonds
  • Chemical bonds are forces that hold atoms together to form molecules or compounds.

  • They involve the rearrangement of valence electrons between atoms.

  • There are primary types of chemical bonds:

    1. Ionic Bonds: Formed when there is a complete transfer of electrons from one atom (typically a metal) to another (typically a non-metal), resulting in the formation of ions (charged atoms) that are attracted to each other.

      • Example: Sodium Chloride (\text{NaCl}). Na loses an electron to become Na^+, and Cl gains an electron to become Cl^-. The electrostatic attraction holds them together.

    2. Covalent Bonds: Formed when atoms share electrons to achieve a stable electron configuration.

      • Example: Water (\text{H}_2 ext{O}). Oxygen shares electrons with two hydrogen atoms.

Polarity of Covalent Bonds
  • The polarity of a covalent bond depends on the difference in electronegativity between the two atoms involved.

  • Electronegativity: A measure of an atom's ability to attract electrons in a chemical bond.

Polar Covalent Bonds
  • Occur when electrons are shared unequally between atoms due to a significant (but not complete) difference in electronegativity.

  • This unequal sharing creates partial positive (\delta^+) and partial negative (\delta^-) charges on the atoms, forming a dipole.

  • Example: Hydrogen Chloride (\text{HCl}).

    • Chlorine is more electronegative than hydrogen, so it pulls the shared electrons closer to itself.

    • This gives chlorine a partial negative charge (\delta^-) and hydrogen a partial positive charge (\delta^+).

Nonpolar Covalent Bonds
  • Occur when electrons are shared equally between atoms, typically when the atoms have similar or identical electronegativities.

  • No significant partial charges are formed.

  • Example 1: Diatomic molecules like Oxygen (\text{O}2) or Hydrogen (\text{H}2).

    • The two identical atoms have the same electronegativity, so electrons are shared perfectly equally.

  • Example 2: Methane (\text{CH}_4).

    • Although carbon is slightly more electronegative than hydrogen, the symmetrical tetrahedral structure of methane causes the individual bond dipoles to cancel each other out, resulting in a nonpolar molecule overall. (While individual C-H bonds are slightly polar, the molecule as a whole is nonpolar due to symmetry.)