E

3.4.3 EXTRA - environmental effects of addition polymers (OCR/Edexcel)

non-biodegradable: not broken down by microorganisms in the environment

addition polymers are unreactive because:

  • they contain many C-C and C-H bonds.

  • these bonds are nonpolar and (relatively) strong, so are difficult to break.

pros of the lack of reactivity of addition polymers

cons of the lack of reactivity of addition polymers

it makes them useful molecules, e.g. they can be used for containers for food and drinks without the polymer reacting with the contents

it makes them non-biodegradable, meaning they can pollute the environment for decades or longer and can cause harm to wildlife, e.g.

  • seabirds can become tangled in polymer waste or consume it, which can be fatal.

disadvantages of producing addition polymers:

  • the alkene monomers come from crude oil, which is a non-renewable resource.

  • the crude oil needs to be transported and refined, which requires lots of energy.

disadvantages of the disposal of addition polymers:

  • addition polymers are used in very large amounts, so occupy lots of space landfills.

  • they are non-biodegradable, so can pollute the environment for decades or longer and can cause harm to wildlife, e.g.

    • seabirds can become tangled in polymer waste or consume it, which can be fatal.

3 ways to reduce the negative effects of addition polymers:

1. combust waste polymers to generate energy, instead of sending them to landfill:

2. polymer waste can be sorted then recycled into new products:

3. feedstock recyling

- waste polymers are converted back into simpler hydrocarbons that can then be cracked and converted into different polymers.

pros:

  • less waste in landfill

pros:

  • reduces the use of crude oil

  • less waste in landfill

pros:

  • the waste polymers do not need sorting.

  • one polymer can be converted into a different polymer.

cons:

  • can release harmful chemicals, e.g. combusting PVC releases HCl gas, which is corrosive.

cons:

  • could be time consuming

cons:

  • could be time consuming

biodegradable polymers:

  • not additon polymers.

  • based on biological material such as plants, which is a renewable resource.

  • naturally break down due to the action of microorganisms.

photodegradable polymers:

  • oil-based polymers which slowly break down in sunlight.