History of Atoms

  • Pre-Quantum Mechanics Atomic Theory

  • Democritus and John Dalton's Theories

  • Democritus (460 B.C.) speculated the existence of atoms, theorizing them as indivisible and invisible to the naked eye, calling them 'atomos'.

  • John Dalton's theory (approx. 1800) included the Law of Definite Proportions and the Law of Multiple Proportions, presenting atoms as indivisible solid spheres.

  • J.J. Thompson and Ernest Rutherford's Discoveries

  • J.J. Thompson (approx. 1900) discovered the electron through the cathode ray tube experiment, proposing the 'raisin bun' model of the atom.

  • Ernest Rutherford (1911) conducted the Gold Foil Experiment, leading to the discovery of the nucleus and the atom's composition of mostly empty space.

  • Classical Theories of Light

  • James Maxwell's Discoveries

  • James Maxwell (mid 1800s) described light as an electromagnetic wave with continuous wavelengths forming a spectrum.

  • Different colors of light have specific wavelengths (e.g., red light = 656 nm) and frequencies.

  • The Photoelectric Effect and Planck's Contribution

  • Heinrich Hertz (1887) discovered the photoelectric effect, where light with high frequency emitted electrons from a metal surface.

  • Max Planck's experiment on blackbodies led to the conclusion that matter emits energy in discrete quantities, represented by E = nhf.

  • Quantum Mechanics Beginnings

  • Niels Bohr's Quantum Model

  • Niels Bohr (1913) developed a quantum model of the atom based on the wave properties of electrons.

  • Bohr's postulates included the concept of stationary orbits with constant energy levels and transitions between energy levels emitting or absorbing light.

  • Limitations of Bohr's Model

  • Bohr's model explains only the first 20 elements of the periodic table and provides a 2D representation of electron locations, lacking a complete quantum mechanical description.