Phytohormones Introduction to Plant Hormones (Phytohormones) Definition: Small, endogenous chemical messengers that coordinate cellular and whole-plant functions. Key distinctions from animal hormones:Animals: many hormones, each triggers a specific, narrow response (e.g., insulin → blood-glucose control). Plants: comparatively few hormones; each affects most cells and elicits diverse, context-dependent responses. Modulating factors of hormone actionEnvironmental cues (light, gravity, temperature, water, nutrients). Developmental stage (seed → vegetative → reproductive). Crosstalk with other phytohormones (synergistic or antagonistic effects) – e.g., auxin vs cytokinin on branching. Primary vs. secondary metabolitesPrimary: essential molecules (e.g., amino acids, sugars) directly tied to growth and survival. Secondary: non-essential but adaptive molecules (phenolics, terpenes, alkaloids) – defense, attraction, etc. Economic importanceCrop productivity, food security, pharmaceuticals, growth regulators in fruits/vegetables/cereals/legumes. Natural Phytohormones vs. Phytoregulators (PGRs) PhytohormonesOrigin: synthesized naturally inside plant tissues. Function: regulate intrinsic processes (growth, development, stress responses). Scope: operate within the natural plant system. Phytoregulators (Plant Growth Regulators, Bioregulators)Origin: synthetic, external, or produced via biotechnology. Function: applied by humans to achieve specific agricultural or lab goals (e.g., rooting powders, herbicides). Examples: \text{IBA} rooting gel, 2,4\text{-D} herbicide, paclobutrazol (GA inhibitor). If a hormone is made synthetically and used for a purpose different from its native role, call it a phytoregulator. General Steps of Hormone Action Synthesis & AccumulationTightly regulated in space/time; often linked to developmental or stress cues. Newly synthesized molecules may be chemically modified → inactive storage forms. Activation = reversible de-conjugation; degradation controls steady-state levels. TransportLong-distance: xylem & phloem. Short-distance: carrier proteins, diffusion, plasmodesmata. Auxin transport is best-characterized (polar transport via PIN proteins). PerceptionReceptors can be membrane-bound (e.g., His-kinase cytokinin receptors, BRI1 for BRs) or intracellular (GA–GID1, ABA–PYR/PYL). Hormone binding → conformational (allosteric) shift → signal initiation. Signal TransductionKinase/phosphatase cascades, second messengers (Ca²⁺, ROS, cGMP), ubiquitin–26S proteasome (e.g., auxin & GA pathways). End-points: changes in gene expression (activation/repression via transcription factors) and non-genomic responses (ion fluxes, enzyme activity). Major Natural Phytohormones Auxins Name from Greek auxein (“to grow”). Primary molecule: Indole-3-acetic acid (IAA), structurally similar to tryptophan. Key rolesCell elongation (acid-growth hypothesis). Apical dominance: inhibits axillary shoot buds → fewer branches. Phototropism & gravitropism: differential distribution → curvature toward light/against gravity. Embryonic patterning, vascular differentiation, lateral root initiation, maintenance of root stem cells. TransportPolar auxin transport: basipetal (shoot → root) via PIN, AUX1/LAX, ABCB carriers. Molecular mechanismAuxin binds TIR1/AFB (F-box proteins) → part of SCF^{TIR1} E3 ubiquitin ligase. Aux/IAA repressors ubiquitinated → degraded by 26S proteasome. Freed ARF (Auxin Response Factor) transcription factors activate AuxRE-containing genes. Synthetic & natural analoguesNatural: \text{IAA}, \text{PAA} (phenylacetic acid). Synthetic: \text{IBA}, \text{NAA}, 2,4\text{-D} (herbicide at high dose). Practical usesRooting powders/gels for cuttings. Fruit thinning (NAA + IBA in apples/pears). Selective broad-leaf weed control (2,4-D). Classic experimentsCharles & Francis Darwin (1880): coleoptile tips perceive light → mobile signal (auxin) causes bending. Boysen-Jensen & Went: agar block “diffusible growth substance” = auxin. Cytokinins (CKs) Adenine derivatives; most active form: trans-zeatin. FunctionsStimulate cell division (cytokinesis). Delay leaf senescence (stay-green trait → higher photosynthetic duration). Regulate nutrient allocation; enhance N and K uptake (N:P:K = 12:12:12 fertilizer synergy). Root nodule formation in legumes; modulation of root/shoot architecture. Stem-cell maintenance at shoot apical meristem; antagonistic/synergistic interplay with auxin. SignalingPerception by membrane His-kinase receptors (AHK2, AHK3, AHK4/CRE1, CKI1). Phosphorelay: His → Asp (receiver domain) → AHP phosphotransfer proteins → type-B ARR TFs (activate CK-responsive genes); type-A ARRs act as negative feedback regulators. Applications / Case studiesElevated CK rice → more grains per panicle (altered inflorescence architecture). Tobacco overexpressing CK biosynthesis gene → delayed senescence, enhanced drought tolerance. Strigolactones (SLs) Carotenoid-derived diterpenoids synthesized mainly in roots. Ecological rolesSignal to arbuscular mycorrhizal fungi (symbiosis establishment). Germination stimulant for parasitic Striga spp. Developmental rolesInhibit axillary bud outgrowth (antagonistic to CK, synergistic with auxin in apical dominance). Mutation (e.g., rice dwarf27 ) → excess tillering. Long-distance coordinationShoot-derived auxin → root SL biosynthesis → SL transported upward → suppress lateral buds. Gibberellins (GAs) Family of >130 diterpenoid acids; only some are bioactive (e.g., \text{GA}1, GA 3, GA4, GA 7). Historical note: “foolish seedling” disease in rice caused by Gibberella fujikuroi overproducing GA. FunctionsStem elongation (bolting), seed germination (α-amylase in cereals), flowering induction (many long-day plants), sex determination, fruit set and growth. \text{GA}_4 often breaks seed dormancy; paclobutrazol inhibits GA biosynthesis → dwarf plants. SignalingBioactive GA binds soluble receptor GID1 → conformational change enabling interaction with DELLA repressor proteins. GA-GID1-DELLA complex → DELLA ubiquitination by SCF^{SLY1} (E3 ligase) → 26S proteasomal degradation → growth gene activation. Agronomic implications“Green Revolution” semi-dwarf wheat & rice carry GA metabolism/signaling mutations (e.g., wheat Rht DELLA, rice sd1 GA20-oxidase) → shorter, lodging-resistant, high-yield cultivars. GA sprays: parthenocarpic pears, cherry & citrus fruit sizing; GA_4/7 for apple quality. Brassinosteroids (BRs) Steroidal hormones (e.g., brassinolide) synthesized from campesterol. RolesCell elongation/expansion (cell-wall loosening enzymes → increased turgor-driven expansion). Pollen tube growth, vascular differentiation, root hair formation, seed germination, stress tolerance. SignalingPerception by LRR receptor-like kinase BRI1 (plasma membrane). BRI1-BAK1 heterodimer → phosphorylation cascade → inhibition of BIN2 kinase → de-phosphorylation & activation of BES1/BZR1 TFs → expression of BR-responsive genes. Phenotype of BR mutants: severe dwarfism (Arabidopsis bri1 , pea lka , tomato dwarf ). Ethylene (C₂H₄) Small gaseous hydrocarbon produced from methionine via enzymes ACC synthase & ACC oxidase. Functions Knowt Play Call Kai