Urine Crystal Notes
Microscopic Examination of Urine Crystals
Crystal Formation
Crystals are formed by the precipitation of urine salts, organic compounds, and medications.
Factors influencing crystal formation:
Temperature
pH (very important in determining crystal type)
Urine concentration
Crystals can be found in healthy individuals and many types are relatively harmless.
- Urine sediments that have specific shapes under microscopy
- Crystals result from the precipitation of urine solutes out of solution
o Formed by the precipitation of urine salts, organic compounds, and medication
o Form as urine cools to room or refrigerator temperature (depending on storage) – not clinically significant
- If crystals are formed in fresh urine, they were formed in vivo (in the body) and are clinically significant
- If crystals form within the nephrons, they can cause significant tubular damage
- Crystals are identified based on their microscopic appearance and the pH at which they are present
o pH – very important in determining type of crystal formation
§ Some form an acidic pH and some at a basic pH

Formation Process
Ultrafiltrate passes through renal tubules.
Solutes become concentrated.
Increased solute concentration leads to saturation of the ultrafiltrate.
Crystals then precipitate.
Normal Crystals in Urine
Triple Phosphate
Calcium oxalate
Uric Acid
Hippuric Acid
Ammonium biurate
Calcium phosphate
Calcium carbonate
Amorphous
Abnormal Crystals in Urine
Bilirubin
Cholesterol
Leucine
Cysteine
Uric Acid Crystals
pH: Acidic
Solubility: Soluble in alkali and heat.
Color: Yellow to orange/brown or colorless.
Shape: Pleomorphic shapes include four-sided plates, rhombic plates, wedges, and rosettes.
Polarization: Appear multicolored under polarized light.
Clinical significance: Associated with gout, treatment with chemotherapy, and Lesch-Nyhan syndrome.
Calcium Oxalate Crystals
pH: Acidic, neutral, or alkaline
Dihydrate form:
Shape: Colorless octahedrons described as “envelopes.”
Polarization: Do not polarize light.
Association: Predominate in urine from patients with diets rich in oxalic acid and are the most common cause of kidney stones.
Monohydrate form:
Shape: Described as dumbbells or rings.
Association: Predominate in urine from patients who have ingested ethylene glycol (antifreeze).
Hippuric Acid
Color: Yellow-brown or colorless
Shape: Elongated prisms or plates, may be thin and resemble needles; often cluster together.
pH: Acidic or neutral
Solubility: Soluble in ether
Clinical significance: Little to no clinical significance, but may be associated with ethylene glycol intoxication.
Calcium Phosphate
pH: Neutral to alkaline
Shape: Colorless, blunt-ended needles, prisms, or rosettes
Association: May be associated with renal calculi
Triple Phosphate
pH: Alkaline
Shape: Colorless prisms described as “coffin lids.”
Polarization: Demonstrate birefringence under polarized light.
Clinical significance: Presence in urine is considered clinically insignificant; commonly seen in dog urine samples.
Calcium Carbonate
pH: Alkaline
Color: Small, yellow to colorless
Shape: Granules, dumbbell or spherical shapes with radial striations
Clinical significance: Not clinically significant but can be confused with other elements.
Unique feature: Crystals effervesce with hydrochloric acid or acetic acid, helping to confirm their presence.
Ammonium Biurate (Urate)
pH: Alkaline
Color: Yellow-brown
Shape: Spicule-covered spheres described as “thorny-apples.”
Clinical significance: May be clinically significant if formed in-vivo (dehydration).
Amorphous Crystals
Amorphous urates:
pH: Acidic
Color: Yellow to brown granules
Appearance: Appear as pink sediment (uroerythrin) in refrigerated samples.
Solubility: Dissolve at alkaline pH or heating above 60^\circ C
Amorphous phosphates:
pH: Alkaline
Appearance: Identical appearance to urates but colorless; white sediment in refrigerated samples.
Solubility: Soluble in acetic acid; do not dissolve when heated above 60^\circ C
Bilirubin
pH: Acidic
Shape: Needle-like to granular
Color: Yellow to brown
Associated with hepatic disorders/severe liver disease
Cholesterol
pH: Acidic
Shape: Colorless, rectangular plates with notched corners
Solubility: Soluble in chloroform and ether; insoluble in dilute acids and alkalis
Associated with nephrotic Syndrome and other disorders that produce lipiduria
Distinction: Differentiate from radiographic contrast media based on specific gravity
Cystine
pH: Acidic
Shape: Colorless thin hexagonal plates
Solubility: Soluble in HCL, sodium hydroxide, ammonium hydroxide; insoluble in acetic acid
Associations: Associated with inborn errors of metabolism such as hereditary cystinosis or cystinuria; most common cause of kidney stones in children
Confirmation: Confirmed by cyanide-nitroprusside test (turns red-purple)
Leucine
pH: Acidic
Shape: Yellow-brown spheres with concentric circles
Birefringent under polarized microscopy
Presence is associated with inborn errors of metabolism
Tyrosine
pH: Acidic
Shape: Colorless to yellow-brown single needles, sheaves, or rosettes
Associated with inborn errors of metabolism such as tyrosinemia and certain liver disorders in which amino acid metabolism is impaired
Crystals from Medication
Ampicillin
pH: Acidic
Shape: Colorless needles that may form in bundles
Sulfonamide
Color: Colorless to yellow-brown
Shape: Needles, sheaves of wheat, fan formations or rosettes
pH: Acidic
Solubility: Soluble in acetone and alkali; insoluble in acetic acid
Indinavir
Radiopaque Dye Crystals
Appearance: Flat needles or sheaves accompanied by round globules; variable in form
Confirmation: Consult ordering location to confirm administration of contrast media if suspected
Association: Associated with very high specific gravity results by refractometer (>1.035); reagent test pad specific gravity not affected by these crystals