Summary of Acid, Base, Concentration, and Titration Concepts
Units of Concentration
Solution: Homogeneous mixture of solute and solvent.
Concentration: Ratio of solute amount to solvent amount.
% (w/w), % (w/v), % (v/v) formulas:
% (w/w) = (mass solute/mass solution) x 100
% (w/v) = (mass solute/volume solution) x 100
% (v/v) = (volume solute/volume solution) x 100
ppm and ppb
ppm: parts per million = (mass solute/volume solution) x 10^6
ppb: parts per billion = (mass solute/volume solution) x 10^9
Molarity and Molar Mass
Molarity (M): moles of solute per liter of solution.
Mole: SI unit for amount of substance.
Molar mass: Calculated from individual elements.
Making Solutions
Stock solution: g = M x L x molar mass.
Dilution formula: C1V1 = C2V2.
Acids and Bases
Arrhenius: Acid increases [H3O+], base increases [OH-].
Bronsted-Lowry: Acid donates protons, base accepts protons.
Lewis: Acid accepts electron pairs, base donates electron pairs.
Strong vs Weak Acids/Bases
Strong acids/bases ionize completely; weak ones only partially.
pH: -log[H+].
pOH: -log[OH-].
Kw: [H3O+][OH-] = 1.0 x 10^-14 at 25°C.
Titration
Method to determine concentration of an unknown acid/base using neutralization reaction.
Equivalence point: Stoichiometric amount of acid and base.
Acid-Base Properties of Salts
Salts can produce neutral, acidic, or basic solutions depending on the strengths of the acids and bases from which they originate.