Light and Matter I Exam #1 Notes
- The first midterm exam is Wednesday, March 8th during class time, administered through CANVAS with live Zoom proctoring. Please be on time.
- The exam will cover the material in Chapters 1, 2, 3, 4, and 5 of the optional textbook.
- Most questions will resemble in-class “Conceptual Questions” or the Lecture Tutorial and Ranking Task questions, so the LT book is the key study resource.
- Cell phones must be off and put away during the exam. Seeing or hearing a cell phone during the exam is grounds for failure.
- Special Relativity will be studied that day as well, so students should do the reading as usual.
Interaction of Light with Matter (Macro)
- Light and matter interact on a macroscopic level in four ways:
- Emission
- Absorption
- Transmission
- Reflection/scattering
- Interaction of light with matter involves the creation (emission) or annihilation (absorption) of photons by atoms and molecules.
Atoms and Light
- Atoms have a dense nucleus composed of protons and neutrons.
- Electrons surround the nucleus in a “cloud.”
Properties of Matter
- Matter comes in different types, but most detectable matter is made of atoms.
- There are 92 naturally occurring elements, each with atoms in its pure form.
- Combinations of atoms form molecules.
- All atoms consist of three kinds of particles: electrons, protons, and neutrons.
Isotopes
- The number of protons (Z) determines the element type.
- For a given element, the number of neutrons can vary, creating different versions called isotopes.
- Examples of Hydrogen Isotopes:
- Normal hydrogen (1H): 1 proton.
- Deuterium (2H): 1 proton and 1 neutron.
- Tritium (3H): 1 proton and 2 neutrons.
- Carbon also has isotopes (e.g., 12C, 13C, 14C).
- 14C is radioactive and used in “carbon dating”.
Energy Levels
- Electrons in an atom exist in well-defined energy levels, characterized by precise, quantized values of energy.
- When matter is at rest (0 K), all electrons are in their lowest energy level (ground state).
Electron Orbits
- Electron orbits in the electron cloud are restricted to specific radii and energies (r<em>1,E</em>1, r<em>2,E</em>2, r<em>3,E</em>3).
- Characteristic electron energies are different for each element.
Absorption
- A photon can only be absorbed if it has the correct energy to move an electron to one of the possible energy levels.
- If a high-energy photon (UV or X-ray) is absorbed, the electron would hold a great deal of energy within an allowed state.
- The photon is absorbed (ceases to exist), and the electron moves to a higher energy level.
- Electrons tend to get rid of extra energy and drop back down to a lower energy level, emitting light.
Emission
- When an electron drops to a lower energy level, it emits a photon with energy exactly equal to the energy difference between the levels.
- For example, if an electron absorbs a sky-blue photon and then drops back down, a new sky-blue photon would be emitted.
Continuous Spectrum and Atomic Cloud Interaction
- If a continuous spectrum of light hits a cloud of atoms, certain wavelengths get absorbed.
- The resulting spectrum on the other side is an absorption spectrum.
Emission Spectrum
- If one could only see the light emitted by a cloud of these atoms, an emission spectrum would be observed.
Kirchoff’s Laws - Absorption & Emission Lines
- The spectrum of a cloud of hot glowing gas contains emission lines.
- When viewed through a cloud of cool gas, a continuous spectrum will have absorption lines.
The Chemical Elements
- The number of protons (atomic number) in a nucleus determines the element.
- Each element has a number of electrons equal to the number of protons.
- The electron orbitals and energy differences between the orbitals are unique for each element.
Finger Prints of Elements
- Spectral lines can be used to identify elements.
Interaction of Light with Matter (Micro)
- Key points:
- Atoms absorb light when electrons move from lower to higher energy levels.
- Atoms emit light when electrons move from higher to lower energy levels.
- For a photon to be absorbed, its energy must match the energy difference between electron energy levels.
- The spacing between energy levels decreases as the energy levels increase.
- The absorption and emission spectra of an element are identical, providing a unique fingerprint.
Lecture Tutorial: Light and Atoms
- Work with partners on Lecture Tutorial: Light and Atoms I, pp. 65-67 (#1-#6) and Lecture Tutorial: Light and Atoms II, pp. 65-67 (#7-#11).
- Read instructions and questions carefully.
- Discuss concepts and answers with one another to reach a consensus.
- Write clear explanations for your answers.
- Seek help from other groups or the instructor if you get stuck.