Gas Laws & Kinetic Molecular Theory

Core idea: matter is made of particles that are always moving.

Key Principles:

More kinetic energy - higher temperature

Slower particle movement - less heat present

Energy and States of Matter:

Most to Least energy: Gas, Liquid, Solid

Changes in energy = changes in states of matter

Brownian Motion: random particle movement suspended in a fluid

cause: continuous collisions w/ smaller, faster moving particles

significance: evidence that particles are always in movement

Temperature: measurement of the average kinetic energy of particles in a substance

the higher the kinetic energy, the higher the temperature

measured in kelvin +273

States of Matter and Phase Changes

energy and states

solid - (particles) vibrates in place - least (energy) level

liquid - slide past each other - moderate level

gas - move freely and rapidly - highest level

Phase Diagram

purpose: to show how pressure and temperature determine the state of a substance

used to identify:

  • freezing/melting point

  • vaporization/condensation point

  • sublimation point

triple point: specific temperature + pressure where all states of matter coexist.

pressure: force presented by gas particles colliding w/ the walls of a container

formula: p = force/area (dependent on)

units: pascal (pa), atmosphere (atm), millimeters of mercury (mmHg) or Torr

volume: space that matter occupies

units: L, mL

more gas particles = more volume

volume = depends on pressure and temperature

Three Laws of Gases

  1. Boyle

inverse relationship between pressure and volume when temp. and gas amount are constant

P1V1=P2V2

if pressure increases, volume decreases and viceversa

  1. Charles

direct relationship between temperature and volume when pressure and gas amount are constant

V1/T1=V2/T2

if temp. increases, volume increases

  1. Gay

direct relationship between pressure and temp. when volume is constant

P1/T1=P2/T2

if temp. increases, pressure increases

Combined Gas Law

pressure, volume, temp all change while gas amt. is constant

P1V1/T1=P2V2/T2