The first time you learned numbers in Spanish, you learned the cardinal numbers (uno, dos, tres...). This second time you will learn the ordinal numbers (first, second, third...).
First: primero
Second: segundo
Third: tercero
Fourth: cuarto
Fifth: quinto
Sixth: sexto
Seventh: séptimo, sétimo
Eighth: octavo
Ninth: noveno
Tenth: décimo
Keep the following in mind as you learn ordinal numbers:
When they are used as an adjective they must agree in number and gender with the noun they modify. Primer lugar, primera ganadora.
When primero and tercero come before a singular masculine noun, drop the ´o´. primer ganador, tercer lugar
For numbers past ten, it is common to use cardinal numbers: 21st century: el siglo veintiuno. For 11th and above, ordinal numbers are used mostly in formal situations. They are listed below:
11th: undécimo
12th: duodécimo
13th: decimotercero
14th: decimocuarto
15th: decimoquinto
16th: decimosexto
17th: decimoséptimo
18th: decimoctavo
19th: decimonoveno
20th: vigésimo
21st: vigésimo primero
22nd: vigésimo segundo
23rd: vigésimo tercero
24th: vigésimo cuarto
30th: trigésimo
31st: trigésimo primero
32nd: trigésimo segundo
40th: cuadragésimo
50th: quincuagésimo
60th: sexagésimo
70th: septuagésimo
80th: octogésimo
90th: nonagésimo
100th: centésimo
200th: ducentésimo
300th: tricentésimo
400th: cuadringentésimo
500th: quingentésimo
600th: sexcentésimo
700th: septingentésimo
800th: octingésimo
900th: noningentésimo
1,000th: milésimo
2,000th: dosmilésimo
3,000th: tresmilésimo
4,000th: cuatromilésimo
1,000,000,000th: millonésimo