Chemistry: The Central Science – Chapter 1 Study Notes
1. What is Chemistry?
Chemistry: The study of matter, its properties, and the changes it undergoes.
It is fundamental to understanding many scientific fields.
2. Matter
Matter: Anything that has mass and takes up space.
Classified by:
State: solid, liquid, gas
Composition: element, compound, mixture
3. States of Matter
Solid: Definite shape and volume
Liquid: Definite volume, no definite shape
Gas: No definite shape or volume
Example: Ice (solid), liquid water, water vapor (gas)
4. Classification by Composition
Substances
Pure, distinct properties, constant composition.
Element: Cannot be broken down into simpler substances (e.g., O₂, Fe).
Compound: Made of two or more elements (e.g., H₂O, CO₂).
Mixtures
Blend of two or more substances.
Homogeneous: Uniform composition (e.g., saltwater, air).
Heterogeneous: Non-uniform composition (e.g., salad, granite).
5. Atoms and Molecules
Atoms: Building blocks of matter.
Molecules: Groups of atoms bonded together.
Elements: Made of one type of atom.
Compounds: Made of two or more different elements.
6. Properties of Matter
Physical Properties
Can be observed without changing the substance.
Examples: color, density, melting point, hardness.
Chemical Properties
Observed only when the substance changes.
Example: flammability, reactivity.
Intensive vs. Extensive Properties
Intensive: Independent of amount (e.g., density, color).
Extensive: Depends on amount (e.g., mass, volume).
7. Changes in Matter
Physical Changes
Do not change composition.
Examples: melting, boiling, cutting.
Chemical Changes
Produce new substances.
Examples: burning, rusting, decomposing.
8. Separating Mixtures
Based on physical properties:
Filtration: Separates solids from liquids.
Distillation: Separates based on boiling points.
Chromatography: Separates based on adhesion.
9. Energy
Energy: Capacity to do work or transfer heat.
Work: Force causing displacement.
Heat: Energy that increases temperature.
Forms of Energy
Kinetic: Energy of motion → KE=12mv2KE=21mv2
Potential: Stored energy due to position.
10. Units of Measurement
SI Base Units
Mass: kilogram (kg)
Length: meter (m)
Time: second (s)
Temperature: Kelvin (K)
Amount: mole (mol)
Metric Prefixes
kilo (k) = 10³
centi (c) = 10⁻²
milli (m) = 10⁻³
micro (μ) = 10⁻⁶
Volume
Derived from length.
Common units: Liter (L), milliliter (mL)
1 L = 1000 mL = 1 dm³
Temperature Scales
Celsius (°C): Based on water (0°C freezing, 100°C boiling)
Kelvin (K): SI unit, no negatives → K=°C+273.15K=°C+273.15
Fahrenheit (°F): Not scientific
11. Density
Density=MassVolumeDensity=VolumeMass
Units: g/cm³ or g/mL
Intensive property
12. Numbers in Science
Exact vs. Inexact Numbers
Exact: Counted or defined (e.g., 12 eggs in a dozen)
Inexact: Measured (always some uncertainty)
Accuracy vs. Precision
Accuracy: Closeness to true value.
Precision: Closeness of repeated measurements.
13. Significant Figures
All certain digits + one uncertain digit.
Rules:
Non-zero digits are significant.
Zeros between non-zero digits are significant.
Leading zeros are NOT significant.
Trailing zeros ARE significant if there’s a decimal point.
Calculations with Sig Figs
+/–: Round to least precise decimal.
×/÷: Round to least number of sig figs.
14. Dimensional Analysis
Method to convert units using conversion factors.
Example:
2.54cm=1in2.54cm=1in
→ 2.54cm1in1in2.54cm or 1in2.54cm2.54cm1in
Key Equations & Relationships
K=°C+273.15K=°C+273.15
°C=59(°F−32)°C=95(°F−32)
Density=mVDensity=Vm
KE=12mv2KE=21mv2
1 cal = 4.184 J
1 Cal (nutritional) = 1000 cal
KE= ½ mv²= unit of energy Joule
k= degree celsius + 273.15
most common units
g/mL or g/cm³