Chemistry: The Central Science – Chapter 1 Study Notes


1. What is Chemistry?
  • Chemistry: The study of matter, its properties, and the changes it undergoes.

  • It is fundamental to understanding many scientific fields.


2. Matter
  • Matter: Anything that has mass and takes up space.

  • Classified by:

    • State: solid, liquid, gas

    • Composition: element, compound, mixture


3. States of Matter
  1. Solid: Definite shape and volume

  2. Liquid: Definite volume, no definite shape

  3. Gas: No definite shape or volume

Example: Ice (solid), liquid water, water vapor (gas)


4. Classification by Composition

Substances

  • Pure, distinct properties, constant composition.

    • Element: Cannot be broken down into simpler substances (e.g., O₂, Fe).

    • Compound: Made of two or more elements (e.g., H₂O, CO₂).

Mixtures

  • Blend of two or more substances.

    • Homogeneous: Uniform composition (e.g., saltwater, air).

    • Heterogeneous: Non-uniform composition (e.g., salad, granite).


5. Atoms and Molecules
  • Atoms: Building blocks of matter.

  • Molecules: Groups of atoms bonded together.

  • Elements: Made of one type of atom.

  • Compounds: Made of two or more different elements.


6. Properties of Matter

Physical Properties

  • Can be observed without changing the substance.

  • Examples: color, density, melting point, hardness.

Chemical Properties

  • Observed only when the substance changes.

  • Example: flammability, reactivity.

Intensive vs. Extensive Properties

  • Intensive: Independent of amount (e.g., density, color).

  • Extensive: Depends on amount (e.g., mass, volume).


7. Changes in Matter

Physical Changes

  • Do not change composition.

  • Examples: melting, boiling, cutting.

Chemical Changes

  • Produce new substances.

  • Examples: burning, rusting, decomposing.


8. Separating Mixtures

Based on physical properties:

  • Filtration: Separates solids from liquids.

  • Distillation: Separates based on boiling points.

  • Chromatography: Separates based on adhesion.


9. Energy
  • Energy: Capacity to do work or transfer heat.

  • Work: Force causing displacement.

  • Heat: Energy that increases temperature.

Forms of Energy

  • Kinetic: Energy of motion → KE=12mv2KE=21​mv2

  • Potential: Stored energy due to position.


10. Units of Measurement

SI Base Units

  • Mass: kilogram (kg)

  • Length: meter (m)

  • Time: second (s)

  • Temperature: Kelvin (K)

  • Amount: mole (mol)

Metric Prefixes

  • kilo (k) = 10³

  • centi (c) = 10⁻²

  • milli (m) = 10⁻³

  • micro (μ) = 10⁻⁶

Volume

  • Derived from length.

  • Common units: Liter (L), milliliter (mL)

  • 1 L = 1000 mL = 1 dm³

Temperature Scales

  • Celsius (°C): Based on water (0°C freezing, 100°C boiling)

  • Kelvin (K): SI unit, no negatives → K=°C+273.15KC+273.15

  • Fahrenheit (°F): Not scientific


11. Density
  • Density=MassVolumeDensity=VolumeMass​

  • Units: g/cm³ or g/mL

  • Intensive property


12. Numbers in Science

Exact vs. Inexact Numbers

  • Exact: Counted or defined (e.g., 12 eggs in a dozen)

  • Inexact: Measured (always some uncertainty)

Accuracy vs. Precision

  • Accuracy: Closeness to true value.

  • Precision: Closeness of repeated measurements.


13. Significant Figures
  • All certain digits + one uncertain digit.

  • Rules:

    • Non-zero digits are significant.

    • Zeros between non-zero digits are significant.

    • Leading zeros are NOT significant.

    • Trailing zeros ARE significant if there’s a decimal point.

Calculations with Sig Figs

  • +/–: Round to least precise decimal.

  • ×/÷: Round to least number of sig figs.


14. Dimensional Analysis
  • Method to convert units using conversion factors.

  • Example:
    2.54cm=1in2.54cm=1in
    → 2.54cm1in1in2.54cm​ or 1in2.54cm2.54cm1in​


Key Equations & Relationships

  • K=°C+273.15KC+273.15

  • °C=59(°F−32)°C=95​(°F−32)

  • Density=mVDensity=Vm

  • KE=12mv2KE=21​mv2

  • 1 cal = 4.184 J
    1 Cal (nutritional) = 1000 cal

KE= ½ mv²= unit of energy Joule

k= degree celsius + 273.15

most common units

g/mL or g/cm³