Untitled

Chapter 15: Carbohydrates

1. Monosaccharides

  • Definition: Monosaccharides are the simplest form of carbohydrates, consisting of single sugar units.
  • Blood Sugar: The monosaccharide referred to as blood sugar is glucose (Answer: c).
    • Options Provided:
    • a) ribulose
    • b) galactose
    • c) glucose
    • d) ribose

2. Aldoses vs. Ketoses

  • Aldoses: Monosaccharides with an aldehyde group.
  • Ketoses: Monosaccharides with a ketone group.
  • Question: All of the following monosaccharides are aldoses except _.
    • Correct Answer: fructose (Answer: a).
    • Options Provided:
    • a) fructose
    • b) ribose
    • c) xylose
    • d) galactose

3. Ribose Structure

  • Ribose: Identify Ribose's classification.
  • Answer: Ribose is a(n) aldopentose (Answer: b).
    • Options Provided:
    • a) aldotetrose
    • b) aldopentose
    • c) ketotriose
    • d) ketohexose

4. Chiral Carbons in Molecules

  • Chiral Carbon: A carbon atom attached to four different groups, leading to non-superimposable mirror images.
  • Question: Identify the chiral carbon in the provided molecule.
    • Correct Answer: The green carbon (Answer: a).
    • Options Provided:
    • a) The red carbon
    • b) The blue carbon
    • c) The green carbon
    • d) The yellow carbon

5. Fischer Projections and Isomer Determination

  • D and L Isomers: Determined by the position of the hydroxyl group (-OH) on the chiral carbon furthest from the carbonyl group.
  • Question: In the Fischer projection, which chiral carbon determines whether the sugar is D or L?
    • Correct Answer: The green carbon (Answer: a).
    • Options Provided:
    • a) The green carbon
    • b) The yellow carbon
    • c) The blue carbon
    • d) The red carbon

6. Identifying Isomers from Fischer Projections

  • Question: In the Fischer projection shown, is this the D or L isomer?
    • Correct Answer: L, because the OH is on the left (Answer: c).
    • Options Provided:
    • a) D, because the OH is on the left
    • b) D, because the OH is on the right
    • c) L, because the OH is on the left
    • d) L, because the OH is on the right

7. Anomers and Haworth Structures

  • Anomers: Isomers that differ only in configuration at the anomeric carbon in a cyclic form of sugar.
  • Question: Is this Haworth structure the a or b anomer?
    • Correct Answer: b, because the OH is above the plane of the ring (Answer: d).
    • Options Provided:
    • a) a, because the OH is below the plane of the ring
    • b) a, because the OH is above the plane of the ring
    • c) b, because the OH is below the plane of the ring
    • d) b, because the OH is above the plane of the ring

8. Reducing and Non-reducing Sugars

  • Reducing Sugars: Any sugar that can act as a reducing agent due to a free aldehyde or ketone group.
  • Question: Which of the following is not a reducing sugar?
    • Correct Answer: sucrose (Answer: d).
    • Options Provided:
    • a) fructose
    • b) glucose
    • c) maltose
    • d) sucrose

9. Disaccharides

  • Lactose: The disaccharide found in milk and milk products.
    • Correct Answer: lactose (Answer: b).
    • Options Provided:
    • a) cellobiose
    • b) lactose
    • c) maltose
    • d) sucrose

10. Linking Monosaccharides to Form Disaccharides

  • Disaccharide Formation: Linking glucose and fructose together produces sucrose (Answer: d).
    • Options Provided:
    • a) galactose
    • b) maltose
    • c) lactose
    • d) sucrose

11. Saccharin Classification

  • Saccharin: A type of artificial sweetener.
  • Question: Saccharin is a(n) _.
    • Correct Answer: None of these are correct (Answer: d).
    • Options Provided:
    • a) pentose
    • b) hexose
    • c) aldose
    • d) None of these are correct.

12. Glycosidic Bonds

  • Glycosidic Bond: A type of covalent bond that links carbohydrates (sugars) together.
  • Question: What type of glycosidic bond is linking these monosaccharides together?
    • Correct Answer: a (1g4) (Answer: a).
    • Options Provided:
    • a) a (1g4)
    • b) a (1g6)
    • c) b (1g4)
    • d) a,b (1g2)

13. Sugar Composition upon Hydrolysis

  • Complete Hydrolysis: The breakdown of a compound by water into its constituent components.
  • Question: Which of the following yields a sugar other than glucose upon complete hydrolysis?
    • Correct Answer: lactose (Answer: a).
    • Options Provided:
    • a) lactose
    • b) maltose
    • c) starch
    • d) cellulose

14. Partial Hydrolysis of Carbohydrates

  • Partial Hydrolysis: The incomplete breakdown of a compound into simpler substances.
  • Question: Which of the following carbohydrates would not yield maltose if partially hydrolyzed?
    • Correct Answer: cellulose (Answer: b).
    • Options Provided:
    • a) amylose
    • b) cellulose
    • c) glycogen
    • d) starch

15. Highly Branched Polysaccharides

  • Highly Branched Polysaccharide: Glycogen is known to be the most highly branched polysaccharide.
    • Correct Answer: glycogen (Answer: d).
    • Options Provided:
    • a) amylopectin
    • b) amylose
    • c) cellulose
    • d) glycogen

16. Indigestible Polysaccharides for Humans

  • Indigestible Polysaccharides: Cellulose is not digestible by humans due to its structural properties.
    • Correct Answer: cellulose (Answer: b).
    • Options Provided:
    • a) glycogen
    • b) cellulose
    • c) amylose
    • d) amylopectin

17. Structural Features Preventing Digestion

  • Structural Feature: The type of linkages between the units of a polysaccharide can prevent human digestion.
  • Question: Which structural feature prevents the human digestion of cellulose?
    • Correct Answer: The b form of the linkages (Answer: c).
    • Options Provided:
    • a) The length of the polysaccharide
    • b) The branches formed in the polysaccharide
    • c) The b form of the linkages
    • d) The galactose units in the polysaccharide

18. Alpha Linkages in Carbohydrates

  • Alpha Linkages: Present in polysaccharides that can be digested by humans.
  • Question: In which of the following are monosaccharide units not joined by alpha linkages?
    • Correct Answer: cellulose (Answer: d).
    • Options Provided:
    • a) maltose
    • b) amylose
    • c) glycogen
    • d) cellulose

19. β (1→4) Linkages in Compounds

  • β (1→4) Linkage: A type of glycosidic linkage present in certain polysaccharides.
  • Question: Which compound contains a β (1→4) linkage?
    • Correct Answer: lactose (Answer: c).
    • Options Provided:
    • a) amylose
    • b) glycogen
    • c) lactose
    • d) maltose

20. Glycogen Structure

  • Glycogen Structure: Presence of both α (1→4) and α (1→6) linkages contributes to its highly branched structure.
  • Question: Which compound contains both α (1→4) and α (1→6) linkages?
    • Correct Answer: glycogen (Answer: c).
    • Options Provided:
    • a) amylose
    • b) cellulose
    • c) glycogen
    • d) sucrose