Gases in the Atmosphere

Composition of the Earth's Atmosphere

  • The Earth's atmosphere consists mainly of:
    • Nitrogen (N₂): 78%
    • Oxygen (O₂): 21%
    • Other gases: 1% (mainly Argon (Ar), traces of other noble gases, and Carbon Dioxide (CO₂) at 400 ppm or 0.04%)

Discovery of Oxygen

  • Space Shuttle Oxygen Supply:
    • Question about how space shuttles carry their oxygen supply.
  • Liquid Oxygen Transport:
    • Question about why oxygen is transported as a liquid.
  • Mercury Heated in Air:
    • Question about what happens to mercury when heated in air.
  • Priestley's Observation:
    • Question about what Priestley thought was given off when substances burned in oxygen.
  • Lavoisier's Experiment:
    • Question about which non-metallic element Lavoisier first burned in air to test his oxygen theory.
  • Magnesium Heating:
    • Question about what happens to the mass of a piece of magnesium after strong heating in air.
  • Scheele's Method:
    • Question about what type of compound Scheele heated to collect oxygen gas.
  • Modern Uses of Oxygen:
    • Question about two modern uses for oxygen.
  • Key Scientists:
    • Question about naming the three key scientists and their nationalities in the discovery of oxygen.

Experiment OXID/1: Determining the Percentage of Oxygen in Air

  • Apparatus:
    • Two gas syringes connected to a glass tube containing excess copper granules.
    • Total initial volume of air in both syringes: 100 cm^3.
  • Procedure:
    • Air is passed over heated copper in a Bunsen flame.
    • The volume of gas is measured after no further change is observed and the apparatus has cooled.
  • Measurements:
    • Initial volume of air: 100 cm^3
    • Final volume of air: to be recorded
    • Volume decrease: to be calculated
  • Calculations:
    • Percentage of oxygen in air: Calculated using the volume decrease.
  • Questions:
    • Ensuring unreacted copper: Why it's important to have some unreacted copper left over at the end of the reaction (Correct option: C - So that we know that all the Oxygen has been used up).
    • Cooling the apparatus: Why it's important to let the apparatus cool before measuring the final volume (Correct option: C - Because the hot gas expands and will make the readings on the syringe appear larger than they should).
    • Replacing copper with magnesium: Why this experiment wouldn't work if copper were replaced with magnesium (Correct option: B - Magnesium will also react with nitrogen and not just oxygen).

Experiment OXID/2: Percentage of Air Used Up When Iron Rusts

  • Process:
    • Iron rusts, removing oxygen from the air.
    • Steel wool is placed in a measuring cylinder, soaked in water, and inverted over a beaker of water.
    • The setup is left for a week to allow the iron to rust.
  • Measurements:
    • Initial volume of air: to be recorded in cm^3
    • Final volume of air: to be recorded in cm^3
    • Volume of air used up: to be calculated in cm^3
    • Percentage of oxygen in air: to be calculated
  • Phosphorus Experiment:
    • Phosphorus reacts with oxygen in the air, forming solid phosphorus oxide (P4O{10}).
    • This reduces the pressure, causing the water level in a bell jar to rise by about 20%.
    • Reaction: phosphorus + oxygen → phosphorus oxide

Experiment OXID/4: Reactions of Elements with Oxygen

  • Test for oxygen gas: Described.
  • Process:
    • Elements react with oxygen to form oxides.
    • A sample of the element is heated in a strong flame and transferred to a gas jar containing oxygen.
    • Distilled water is added to the gas jar to dissolve any oxide produced.
    • Universal indicator is added to the solution to determine the pH.
  • Results Table:
    • Elements tested: Carbon, Sodium, Sulfur, Magnesium.
    • Observations: To be recorded for each element.
    • Color and pH of solution: To be recorded for each element.
  • Observations:
    • Note differences between oxides formed by metals and non-metals.
  • Balanced Equations:
    • Write balanced equations for the reactions between sodium, sulphur, magnesium, and carbon, including state symbols.

Experiment HYD/2: Combustion of Hydrogen

  • Apparatus:
    • Draw a neat labeled diagram of the apparatus used in this experiment.
  • Observations:
    • Describe the appearance of the liquid that collects in the test-tube.
    • Describe how the liquid is tested and the result of the test.
    • Explain whether this test proves that the liquid is pure.
    • How to use a physical test to show that the liquid is pure water.

Greenhouse Gases

  • Greenhouse Gases:
    • Name at least two gases that can be described as greenhouse gases.
    • Explain how these gases are produced.
  • Effect on Climate:
    • What effect does the build-up of greenhouse gases have on the world's climate?
  • Polar Ice Caps:
    • Given that polar ice caps contain a significant amount of dissolved carbon dioxide and methane, what are the potential problems of polar ice caps melting?

Experiment OXID/6: Thermal Decomposition of Copper(II) Carbonate

  • Procedure:
    • A test-tube with approximately 0.4g of copper(II) carbonate is pre-weighed.
    • The tube is connected to a gas syringe.
    • The test-tube is heated until the copper carbonate has completely decomposed.
    • The apparatus is allowed to cool, and the volume of gas given off is measured.
    • The mass of the test-tube + solid after heating is reweighed.
  • Measurements and Calculations:
    • Mass of test-tube + copper carbonate before heating: to be recorded in grams (g).
    • Volume of gas given off: to be recorded in cubic centimeters (cm^3).
    • Mass of test-tube + solid after heating: to be recorded in grams (g).
    • Mass loss in the reaction: to be calculated in grams (g).
    • Mass of the gas given off in the reaction: to be calculated in grams (g).
    • Density of the gas (mass/volume): to be calculated in g/cm^3.
  • Gas Identification:
    • Density of gases provided: Oxygen (0.0013 g/cm^3), Carbon dioxide (0.0018 g/cm^3), Carbon monoxide (0.0012 g/cm^3).
    • Identify the gas from the densities.
  • Solid Residue:
    • What is the solid remaining in the test-tube?
  • Equations:
    • Write a word equation for the reaction that has occurred.
    • Write a balanced symbol equation for the reaction that has occurred.
  • Confirmation:
    • Heat a fresh sample of copper(II) carbonate and test the gas produced with limewater.
    • Observe if the limewater turns cloudy.
  • Observations Table:
    • Substance: Copper(II) carbonate, Lime water.
    • Observations: Before reaction, After reaction.
  • Questions:
    • Evidence of a chemical reaction: Give two pieces of evidence.
    • Gas produced: Which gas is produced in the reaction?
    • Test for the gas: What is the test for this gas?