Metals - Properties and Reactions
- Metals are elements with specific properties and reactions.
- Examples of metals include gold (Au), titanium (Ti), lead (Pb), zinc (Zn), iron (Fe), and copper (Cu).
- Non-metals must be accompanied by a metal in chemical reactions.
- Metals have various uses.
- Recycling of metals is important.
- Metals are conductors of heat and electricity.
- Metals are malleable (can be shaped) and ductile (can be drawn into wires).
- Metals have high density.
- Metals are sonorous (make a ringing sound when struck).
- Some metals are magnetic, such as iron, cobalt, and nickel; however, not all metals are magnetic.
- Metallic bonding explains many physical properties of metals.
- Electrons in the outer shells of metal atoms are free to move, forming a "sea of electrons."
- Metal atoms are held together by their attraction to these free electrons.
- Free electrons provide conductivity.
- Close-packed structure leads to high density.
Malleability and Ductility
- Metals are malleable and ductile because the bonds between atoms are not broken when the metal is deformed.
- When a metal is hit, layers of atoms can move over each other due to the free-moving electrons.
| Property | Metals | Non-metals |
|---|
| Appearance | Shiny | Dull |
| Electrical and Thermal Conductivity | Conductors | Insulators |
| Density | High | Low |
| Melting and Boiling Points | High | Low |
| Ductility | Yes | No |
| Malleability | Yes | No |
- Metals can react with oxygen, water, steam, and acids.
1. Reaction with Oxygen
- General equation: Metal + Oxygen → Metal Oxide
- Example: Sodium + Oxygen → Sodium Oxide
- Some metals, like magnesium and calcium, burn in oxygen.
- Some metals, like iron and copper, react slowly with oxygen (e.g., rusting of iron, formation of copper oxide).
- Some metals, like silver, gold, and platinum, are inert or react very slowly with oxygen.
2. Reaction with Water
- General equation: Metal + Water → Metal Hydroxide + Hydrogen
- Example: Potassium + Water → Potassium Hydroxide + Hydrogen
- Only a few metals (potassium, sodium, calcium) react with cold water.
3. Reaction with Steam
- Some metals (magnesium, aluminum, zinc, iron) react with steam instead of water.
- Metal Oxide is formed instead of Hydroxide.
- Safety Alert: Remove the delivery tube before removing the Bunsen flame to prevent suck-back.
4. Reaction with Acid
- General equation: Metal + Acid → Metal Salt + Hydrogen
- The salt formed depends on the type of acid used.
- Example: Magnesium + Hydrochloric Acid → Magnesium Chloride + Hydrogen
- Reactive metals like sodium, potassium and lithium should NEVER be added to acid due to the risk of explosion.
- Some metals (copper, mercury, silver, gold) are inert to dilute acids, but copper and mercury can react with concentrated acids.
- Metal + Oxygen → Metal Oxide
- Metal + Water → Metal Hydroxide + Hydrogen
- Metal + Steam → Metal Oxide + Hydrogen
- Metal + Acid → Metal Salt + Hydrogen
| Acid | Name of Salt |
|---|
| Hydrochloric Acid | Chloride |
| Sulphuric Acid | Sulphate |
| Nitric Acid | Nitrate |
| Ethanoic Acid | Ethanoate |
| Phosphoric Acid | Phosphate |
| Carbonic Acid | Carbonate |
- A series based on the difference in reactivity of metals.
- Carbon and Hydrogen are NOT metals but act as indicators for metals’ reactivity.
- Mnemonic: "Please Stop Calling Me A Cute Zebra, I Tend-To Like Hot Chicken Meat. So God Please!"
- Order (Most to Least Reactive): Potassium (K) -> Sodium (Na) -> Calcium (Ca) -> Magnesium (Mg) -> Aluminum (Al) -> Carbon (C) -> Zinc (Zn) -> Iron (Fe) -> Tin (Sn) -> Lead (Pb) -> Hydrogen (H2) -> Copper (Cu) -> Mercury (Hg) -> Silver (Ag) -> Gold (Au) -> Platinum (Pt)
Displacement Reactions
- Definition: A more reactive metal will displace a less reactive metal from its compound.
Types of Displacement
- Solid Displacement
- A more reactive solid metal displaces a less reactive solid metal compound.
- Example: Thermite Reaction
- Equation: Aluminium+iron oxide→Aluminium oxide+iron
- Application: Source of molten iron for railway work (thermite welding for joining rails).
- Solution Displacement
- A more reactive solid metal displaces a less reactive aqueous metal compound.
- Example: Silver Tree Reaction
- Equation: Copper+silver nitrate→copper nitrate+silver
- Observation: Solution turns blue.
- Application: Comparing the reactivities of different metals.
Physical Properties
- Metals are shiny and sonorous.
- Metals are electrical and thermal conductors.
- Metals are malleable and ductile.
- Metallic bonding involves delocalized electrons surrounding positive metal ions.
Chemical Properties
- Metals react with oxygen to form metal oxides.
- Metals react with water to form metal hydroxides and hydrogen.
- Metals react with steam to form metal oxides and hydrogen.
- Metals react with acid to form salts and hydrogen.
- More reactive metals can displace less reactive metal compounds.