Metals - Properties and Reactions

Metals: Properties and Reactions

Introduction to Metals

  • Metals are elements with specific properties and reactions.
  • Examples of metals include gold (Au), titanium (Ti), lead (Pb), zinc (Zn), iron (Fe), and copper (Cu).
  • Non-metals must be accompanied by a metal in chemical reactions.

Uses of Metals

  • Metals have various uses.
  • Recycling of metals is important.

Physical Properties of Metals

  • Metals are conductors of heat and electricity.
  • Metals are malleable (can be shaped) and ductile (can be drawn into wires).
  • Metals have high density.
  • Metals are sonorous (make a ringing sound when struck).
  • Some metals are magnetic, such as iron, cobalt, and nickel; however, not all metals are magnetic.

Metallic Bonding

  • Metallic bonding explains many physical properties of metals.
  • Electrons in the outer shells of metal atoms are free to move, forming a "sea of electrons."
  • Metal atoms are held together by their attraction to these free electrons.
  • Free electrons provide conductivity.
  • Close-packed structure leads to high density.

Malleability and Ductility

  • Metals are malleable and ductile because the bonds between atoms are not broken when the metal is deformed.
  • When a metal is hit, layers of atoms can move over each other due to the free-moving electrons.

Comparison of Metals and Non-metals

PropertyMetalsNon-metals
AppearanceShinyDull
Electrical and Thermal ConductivityConductorsInsulators
DensityHighLow
Melting and Boiling PointsHighLow
DuctilityYesNo
MalleabilityYesNo

Chemical Reactions of Metals

  • Metals can react with oxygen, water, steam, and acids.
1. Reaction with Oxygen
  • General equation: Metal + Oxygen → Metal Oxide
  • Example: Sodium + Oxygen → Sodium Oxide
  • Some metals, like magnesium and calcium, burn in oxygen.
  • Some metals, like iron and copper, react slowly with oxygen (e.g., rusting of iron, formation of copper oxide).
  • Some metals, like silver, gold, and platinum, are inert or react very slowly with oxygen.
2. Reaction with Water
  • General equation: Metal + Water → Metal Hydroxide + Hydrogen
  • Example: Potassium + Water → Potassium Hydroxide + Hydrogen
  • Only a few metals (potassium, sodium, calcium) react with cold water.
3. Reaction with Steam
  • Some metals (magnesium, aluminum, zinc, iron) react with steam instead of water.
  • Metal Oxide is formed instead of Hydroxide.
  • Safety Alert: Remove the delivery tube before removing the Bunsen flame to prevent suck-back.
4. Reaction with Acid
  • General equation: Metal + Acid → Metal Salt + Hydrogen
  • The salt formed depends on the type of acid used.
  • Example: Magnesium + Hydrochloric Acid → Magnesium Chloride + Hydrogen
  • Reactive metals like sodium, potassium and lithium should NEVER be added to acid due to the risk of explosion.
  • Some metals (copper, mercury, silver, gold) are inert to dilute acids, but copper and mercury can react with concentrated acids.

Summary of Metal Reactions

  • Metal + Oxygen → Metal Oxide
  • Metal + Water → Metal Hydroxide + Hydrogen
  • Metal + Steam → Metal Oxide + Hydrogen
  • Metal + Acid → Metal Salt + Hydrogen

Types of Salts Formed with Different Acids

AcidName of Salt
Hydrochloric AcidChloride
Sulphuric AcidSulphate
Nitric AcidNitrate
Ethanoic AcidEthanoate
Phosphoric AcidPhosphate
Carbonic AcidCarbonate

Metal Reactivity Series

  • A series based on the difference in reactivity of metals.
  • Carbon and Hydrogen are NOT metals but act as indicators for metals’ reactivity.
  • Mnemonic: "Please Stop Calling Me A Cute Zebra, I Tend-To Like Hot Chicken Meat. So God Please!"
  • Order (Most to Least Reactive): Potassium (K) -> Sodium (Na) -> Calcium (Ca) -> Magnesium (Mg) -> Aluminum (Al) -> Carbon (C) -> Zinc (Zn) -> Iron (Fe) -> Tin (Sn) -> Lead (Pb) -> Hydrogen (H2) -> Copper (Cu) -> Mercury (Hg) -> Silver (Ag) -> Gold (Au) -> Platinum (Pt)

Displacement Reactions

  • Definition: A more reactive metal will displace a less reactive metal from its compound.
Types of Displacement
  • Solid Displacement
    • A more reactive solid metal displaces a less reactive solid metal compound.
    • Example: Thermite Reaction
      • Equation: Aluminium+iron oxide→Aluminium oxide+ironAluminium + iron\ oxide \rightarrow Aluminium \ oxide + iron
      • Application: Source of molten iron for railway work (thermite welding for joining rails).
  • Solution Displacement
    • A more reactive solid metal displaces a less reactive aqueous metal compound.
    • Example: Silver Tree Reaction
      • Equation: Copper+silver nitrate→copper nitrate+silverCopper + silver \ nitrate \rightarrow copper \ nitrate + silver
      • Observation: Solution turns blue.
      • Application: Comparing the reactivities of different metals.

Summary of Metal Properties

Physical Properties
  • Metals are shiny and sonorous.
  • Metals are electrical and thermal conductors.
  • Metals are malleable and ductile.
  • Metallic bonding involves delocalized electrons surrounding positive metal ions.
Chemical Properties
  • Metals react with oxygen to form metal oxides.
  • Metals react with water to form metal hydroxides and hydrogen.
  • Metals react with steam to form metal oxides and hydrogen.
  • Metals react with acid to form salts and hydrogen.
  • More reactive metals can displace less reactive metal compounds.