CHO

Carbohydrates (CHO) Study Guide

General Information

  • CHO are the most abundant biomolecules after water.

  • Plants: Serve structural and energy storage functions.

  • Animals: Primarily used as an energy source; stored energy plays a minor role.

  • Glycogen: Storage form of CHO in animals.

  • Non-ruminants: Main CHO source is starch.

  • Ruminants & Herbivores: Utilize starch, cellulose, and other non-starch polysaccharides.

  • Monosaccharides: All ketone and aldehyde sugars are monosaccharides.

Classification of Carbohydrates

  • Monosaccharides (Single sugar units): Glucose, fructose, galactose, mannose.

  • Disaccharides (Two sugar units): Lactose, sucrose, maltose.

  • Oligosaccharides (3-10 sugar units): Raffinose, stachyose, maltotriose, FOS, MOS, GOS.

  • Polysaccharides (>10 sugar units): Starch, cellulose, pectin, hemicellulose.

  • Sugar: Mono- or disaccharides in the diet.

Specific Carbohydrates

  • Dextrose: Another name for glucose.

  • Dextrins: Polymers of glucose from starch hydrolysis, containing alpha 1-4 and alpha 1-6 linkages.

  • Maltodextrin: A type of dextrin.

  • Dextran: Polymers of glucose with alpha 1-6 glycosidic linkages and branches from alpha 1-3 linkages.

  • Levulose: Another name for fructose.

  • Invert Sugar: A mix of glucose and fructose from enzymatically treated sucrose.

Structural and Chemical Properties

  • Carbohydrates are "hydrated carbons," with the smallest unit having 3 carbons.

  • Triose (3C): Glyceraldehyde (C3H6O3).

  • Tetrose (4C): Erythrose (C4H8O4).

  • Pentose (5C): Ribose, xylose, arabinose (C5H10O5).

  • Hexose (6C): Glucose, fructose, galactose (C6H12O6).



Monosaccharides

  • Major Sugars: Classified based on ketone or aldehyde groups.

  • Double Bonds: The key difference between aldehydes and ketones.

Ketone sugar examples: dihydroxyactetone, d-xylulose, d-ribulose, d-fructose, d-sedoheptulose 

Aldehyde sugar: d-glycerose, d-erthrose, d-lyxose, d-xylose, d-arabinose, d-ribose, d-galactose, d-mannose, d-glucose

  • Aldehyde Sugars: Contain aldehyde groups at carbon 1.

  • Ketone Sugars: Contain a ketone group at carbon 2.

  • Aldehyde Sugars: Contain aldehyde groups at carbon 1.

  • Ketone Sugars: Contain a ketone group at carbon 2.

Disaccharides and Polysaccharides

  • Maltose: Glucose + glucose (alpha 1-4) → Digested by maltase.

  • Cellobiose: Glucose + glucose (beta 1-4) → Not digestible by animals.

  • Sucrose: Glucose + fructose (alpha 1-2) → Digested by sucrase.

  • Lactose: Galactose + glucose (beta 1-4) → Digested by lactase.

  • Starch: Composed of amylose and amylopectin.

    • Amylose: Alpha 1-4 linkages, water-soluble, easy to digest.

    • Amylopectin: Alpha 1-4 and alpha 1-6 linkages, insoluble, branched, harder to digest.

    • Glycogen: Found in animal liver/muscles, similar structure to amylopectin.

  • Cellulose: Provides plant rigidity, not digestible by animals but by bacteria.

Carbohydrates in Diet & Digestion

  • High Glycemic Index (GI): Rapid digestion → Insulin spikes → Fat deposition → Type II diabetes.

  • Low GI Foods (<55): Most fruits, vegetables, lentils.

  • Medium GI Foods (56-69): Brown rice, oatmeal, popcorn.

  • High GI Foods (>70): White bread, corn flakes, instant potatoes.

  • Resistant Starch (RS): Staw

This study guide summarizes key concepts related to carbohydrates, their structure, function, digestion, and impact on health.


Flashcards

  • Carbohydrates (CHO): Most abundant biomolecules after water.

  • CHO in Plants: Structural and energy storage functions.

  • CHO in Animals: Primary energy source; minor role in storage.

  • Glycogen: Storage form of carbohydrates in animals.

  • Non-Ruminant CHO Source: Mainly starch.

  • Ruminant & Herbivore CHO Source: Starch, cellulose, and other non-starch polysaccharides.

  • Monosaccharides: Single sugar units (glucose, fructose, galactose, mannose).

  • Disaccharides: Two sugar units (lactose, sucrose, maltose).

  • Oligosaccharides: 3-10 sugar units (raffinose, stachyose, maltotriose, FOS, MOS, GOS).

  • Polysaccharides: More than 10 sugar units (starch, cellulose, pectin, hemicellulose).

  • Sugar: Mono- or disaccharides in the diet.

  • Dextrose: Another name for glucose.

  • Dextrins: Polymers of glucose from starch hydrolysis.

  • Maltodextrin: A type of dextrin.

  • Dextran: Glucose polymers with alpha 1-6 and alpha 1-3 linkages.

  • Levulose: Another name for fructose.

  • Invert Sugar: Glucose and fructose mix from enzymatically treated sucrose.

  • Triose: 3-carbon sugar (glyceraldehyde).

  • Tetrose: 4-carbon sugar (erythrose).

  • Pentose: 5-carbon sugar (ribose, xylose, arabinose).

  • Hexose: 6-carbon sugar (glucose, fructose, galactose).

  • Aldehyde Sugars: Have an aldehyde group at carbon 1.

  • Ketone Sugars: Have a ketone group at carbon 2.

  • Maltose: Glucose + glucose (alpha 1-4 linkage).

  • Cellobiose: Glucose + glucose (beta 1-4 linkage).

  • Sucrose: Glucose + fructose (alpha 1-2 linkage).

  • Lactose: Galactose + glucose (beta 1-4 linkage).

  • Starch: Made of amylose and amylopectin.

  • Amylose: Alpha 1-4 linked glucose, water-soluble.

  • Amylopectin: Alpha 1-4 and alpha 1-6 linked glucose, branched.

  • Glycogen: Animal storage carbohydrate, similar to amylopectin.

  • Cellulose: Provides plant rigidity, not digestible by animals.

  • Glycemic Index (GI): Measures the speed of carbohydrate digestion.

  • High GI Foods: Rapid digestion, insulin spikes, potential obesity risk.

  • Low GI Foods: Slow digestion, includes most fruits and vegetables.

  • Resistant Starch (RS): Starch that escapes digestion in the small intestine.

  • SCFA Production: Short-chain fatty acids support gut health and energy.

  • Prebiotics: Non-digestible food ingredients promoting gut bacteria.

  • Probiotics: Live microorganisms beneficial for gut health.

  • Anti-Nutritional Oligosaccharides: Reduce digestibility (raffinose, stachyose).

  • Homopolysaccharides: Single sugar type (starch, cellulose).

  • Heteropolysaccharides: Multiple sugar types (hemicellulose, pectin).

  • Soluble Fiber: Dissolves in water, slows digestion.

  • Insoluble Fiber: Does not dissolve in water, speeds up digestion.