presentation

A Technical-Environmental Comparison of Hybrid and Blended Slag Cement-Based Recycled Aggregate Concrete

Introduction

  • This study analyzes the eco-design of concrete using a hybrid binder (HB) combined with recycled aggregates (RA) to mitigate CO2 emissions.

  • Focus on the impact of different RA percentages and binder types on technical performance metrics such as compressive strength (CS), carbonation (DC), and chloride migration (DCl).

  • Results show that the percentage of RA is more significant than the binder type in influencing concrete performance.

Eco-Designed Concrete

  • Incorporation of concrete design parameters in functional units shows carbon footprint reductions between 10-60% for HB when considering strength and transport properties.

  • Optimizing RA percentages is crucial for achieving environmental benefits.

Material Properties and the Role of Activators

  • Historical work indicates sodium sulfate activation can enhance CS in high GGBFS mixtures, influencing early-age properties without altering binder quantities.

  • Activators, particularly sodium sulfate, play a vital role in enhancing strength through their interaction with binders and facilitating the formation of beneficial phases at early ages, leading to a denser microstructure.

Importance of Recycled Aggregates

  • Use of RAs in Europe is becoming standard due to the aim of a circular economy.

  • However, RAs are often limited to low percentages in structural concrete due to concerns about quality.

  • Durability studies on RA concrete yield variable results based on RA quality and mix design.

Hybrid Binder Evaluation

  • Emphasizing the need for studies at the concrete level, the paper aims to evaluate microstructure and transport properties across mixes with varying RA contents compared to commercial CEM III/B.

  • The use of sophisticated packing techniques can optimize the performance of concrete while minimizing carbon footprint.

Material and Methods: Mix Design

  • Binders used include CEM III/B, CEM I N, and GGBFS, with sodium sulfate serving as the activator.

  • Natural aggregates alongside RA made from C&DW have been employed, influencing water absorption rates and mix density.

  • Adjustments in mix designs took into account the morphology and absorption characteristics of RAs.

Testing Procedures

  1. Ultrasonic Pulse Velocity (UPV): Measuring setting and hardening phases to assess early strength development and microstructural changes.

  2. Compressive Strength (CS): Evaluated against standard cubic samples at various hydration durations.

  3. Water Absorption and Density Tests: Used to determine permeability and overall mix density over time.

  4. Rapid Chloride Migration and Resistivity Tests: Assessing durability and electrical resistance indicative of corrosion risks.

  5. Water Penetration Tests: Conducted to evaluate the effectiveness of barrier properties.

  6. Natural Carbonation Measurements: Analyzed to measure penetration depth of CO2.

  7. Life-Cycle Assessment (LCA): Used to evaluate the environmental impacts of concrete mixes throughout their life cycle, particularly focusing on CO2 emissions.

Results

Fresh State Properties
  • Enhanced workability and better slump ratings were noted in the hybrid binder mixes compared to CEM III/B due to the activator's effect.

  • Densities decreased with RA; however, concrete produced with the hybrid binder maintained superior densities relative to mixed CEM III/B outcomes.

Strength Development
  • Hybrid systems yielded significantly greater CS, especially at early hydration stages.

  • RA inclusion adversely affected strength metrics noted from 7 days onwards, highlighting binders' maxima in mitigating this reduction.

Transport Properties
  • Analyses of pore structures revealed that while porosity increased with RA content, hybrid binds performed slightly better than CEM III/B in water absorption and permeability indicators, revealing resilient bond capacities.

Durability Tests
  • Tested concretes meet high standards for chloride diffusion and exhibit low corrosion risk.

  • Carbons showed increased rates with RA; however, the hybrid mix corruption remained lower than CEM III/B mixes, suggesting structural integrity remains firmer.

Environmental Impact Assessment

  • Approximately 75% of total CO2 emissions stems from binder production, revealing the importance of selecting eco-efficient binding materials.

  • The study concluded that while replacing natural aggregates with RA has limited direct benefits, it plays a role in resource efficiency and landfill reduction.

  • Effective strategies combining RA usage with hybrid binders can lead to significant sustainability advancements, making them viable alternatives in low-carbon concrete production.

Conclusion

  • The incorporation of higher RA percentages lowers the concrete density but enhances life-cycle sustainability when paired with the hybrid binder.

  • The HB yields higher early-age performance while maintaining quality comparable to CEM III/B under durability assessments.

  • Combined strategies towards lower carbon output alongside circular economy principles show promising results in creating refined concrete qualities.