Environmental Science Flashcards

Intro to ENVISCI

  • Denis Dyvee Errabo, PhD

Outline of Presentation

  • Definition

  • Classical and modern views

  • Why study the environment

  • Tragedy of the commons

  • Indicators of environmental stress

Environmental Science

  • Is a dynamic, interdisciplinary field that studies the interaction between living and non-living components of the environment.

Dynamics

  • Focuses on human impacts on the environment

  • Examines the conditions, objects, and circumstances that surround organisms and communities

  • Explores the complex interactions within environmental systems

Components of Environmental Systems

  • Energy

  • CO2CO_2

  • Water

  • Minerals

The Interdisciplinary Nature

  1. Hierarchy

    • Organismal, Population, Community, Ecosystem, Global

  2. Concept

    • Descriptive, Functional, Evolutionary

  3. Taxonomy

    • Plant, Microbial, Fungal, Animal, Avian, Protozoan

  4. Time/Place

    • Marine, Terrestrial, Freshwater, Paleoecology, Tropical Ecology

  5. Processes

    • Behavioral, Physiological

Hierarchy - Example of Inquiry

  • Organism: How does an organism adapt to extremes?

  • Population: Is the population increasing or decreasing? Why? What controls population size?

  • Community: Who eats whom? What happens to the community when you remove a top predator?

  • Ecosystems: What controls the flow of energy and nutrients through an ecosystem?

  • Biosphere: How is the biosphere responding to increasing atmospheric carbon dioxide levels?

Modern View

  • Environmental Science is at the intersection of Humanities, Social Sciences, and Natural Sciences.

Environmental Components

  • Energy

  • CO2CO_2

  • Water

  • Minerals

Environmental Components (Repeated)

  • Energy

  • CO2CO_2

  • Water

  • Minerals

Why Study Environmental Science?

  • Human behavior directly affects the environment

  • Understanding scientific principles behind natural interactions is essential

  • Our future depends on our capacity to evaluate and act on environmental evidence

Facing Global Challenges

  • Climate change

  • Habitat loss

  • Population growth

  • Rapid development

Complex Environmental Systems

  • Interactions between natural and human components

  • Links from local to global, short- to long-term

  • From individual behavior to collective action

The Tragedy of the Commons (Garrett Hardin, 1968)

  • A situation where individuals, acting in their own self-interest, collectively overexploit shared, limited resources—leading to long-term ruin for all.

Why It’s a Tragedy

  • A Rational behavior at the individual level

  • Irrational outcome at the collective level

  • “Freedom in a commons brings ruin to all.”

  • Hardin's Conclusion: Without restraints or ethics guiding use, shared resources will inevitably be depleted or destroyed.

Real-World Applications of the Commons

  • Overgrazing of public lands

  • Deforestation in shared forests

  • Overfishing in oceans

  • Water pollution from sewage dumping

  • Air pollution from shared atmosphere

Questions Regarding Environmental Impacts

  • How does deforestation influence the global climate?

  • How does deforestation influence the water supply to neighboring towns?

  • How does acid rain influence forest productivity?

  • What are the biological controls over rock weathering?

The Climate Crisis as a Commons Tragedy

  • Commons Affected: The atmosphere

  • Issue: CO2CO_2 emissions from burning fossil fuels

  • Short-term economic gain per country

  • Long-term global environmental cost

  • Hardin’s Insight: Countries, like the herders, act in their own interest, leading to climate degradation that affects everyone.

Global Environmental Stress — Key Indicators

  1. Forests

    • Deforestation: 1 million hectares lost annually (1980–1990)

    • Main driver: Agricultural land clearing by farmers

    • Concern: Forest degradation from overuse and lack of regulation

  2. Soil

    • 10% of vegetated land is moderately degraded

    • 20% of irrigated land is losing productivity

    • Issue: Long-term food security and soil sustainability

  3. Fresh Water

    • 20% of global population lacks access to safe drinking water

    • 50% lacks safe sanitation

    • By 2025: 2/3 of world population may face water stress

  4. Marine Fisheries

    • 25% of fisheries at max capacity; 35% overfished

    • Pressure to increase harvest through aquaculture

    • Risk: Pollution, wetland and mangrove loss

  5. Biodiversity

    • Threats: Habitat destruction and pollution

    • Estimated species: ~14 million

    • 1–11% species risk extinction every decade

    • Coastal ecosystems especially at risk

  6. Atmosphere

    • Human activity affects climate (IPCC finding)

    • CO2CO_2 emissions rising in industrialized nations

    • Countries failed to meet 1990 emission targets by 2000

  7. Toxic Chemicals

    • 100,000+ commercial chemicals, mostly untested for impact

    • Persistent organic pollutants (POPs): Found worldwide

    • Risk: Toxicity, long-term ecological harm

  8. Hazardous Wastes

    • Heavy metal pollution from mining/industry

    • Radioactive contamination incidents increasing

    • Legacy nuclear waste poses long-term threats

  9. Waste Management

    • Domestic/industrial waste increasing globally

    • Developed countries: Per capita waste tripled in 20 years

    • Developing countries: Waste expected to double next decade

    • Poor sanitation still a major cause of illness and death

The Process of Science

  • Denis Dyvee Errabo, PhD

Learning Objectives

  • Use the scientific method to develop analytical frameworks for environmental issues.

  • Analyze ecological, physical, social, and political principles of environmental systems.

  • Apply systems thinking in understanding environmental interactions.

Understanding the Scientific Method

Scientific Method

  • A structured way of exploring questions through experiments and careful observation.

Hypothesis

  • A testable idea or explanation for an event or pattern.

Steps of the Scientific Method

  • Make an observation

  • Ask a question

  • Form a hypothesis that answers the question

  • Make a prediction based on the hypothesis

  • Do an experiment to test the prediction

  • Analyze the results

    • If hypothesis is supported: Try again…

    • If hypothesis is not supported: Report results

Scientific Theory

  • A well-tested, widely accepted explanation of natural phenomena, built from many hypotheses and observations.

  • Why It Matters: Scientific theories form the foundation of scientific knowledge—they help us understand and predict the world.

Scientific Method as a Process

  1. Observation

    • Scientific discovery begins with careful observation.

  2. Inquiry

    • Asking questions leads to deeper understanding.

  3. Hypothesis

    • A proposed explanation that predicts an outcome and gives a reason why it might be true.

  4. Prediction

    • A specific, testable statement that follows from the hypothesis.

  5. Testing

    • Both hypotheses and predictions must be testable and measurable to be scientifically valid.

  6. Conclusion

    • Iteration of earlier assumptions vis-à-vis with the findings.

  7. Communication

    • Relating relevant findings to the stakeholders in the community.

Observational Study

  • Scientists observe and compare groups with and without the presumed cause (no manipulation).

Replicates Matter!

  • Use of multiple samples helps make results more reliable.

  • Ensures the patterns are due to the variable studied, not random chance.

Repeatability is Key

  • A study should be repeatable: If done the same way again, it should give similar results.

Multiple Studies, One Hypothesis

  • Different researchers may test the same hypothesis in various ways to build stronger evidence.

Lens of Experimental Design

  • Response Variable

    • The outcome being measured in the study.

  • Explanatory Variable (Treatment)

    • The factor scientists intentionally change to observe its effect.

  • Controlled Variables

    • Other factors kept constant to avoid affecting the results (also called confounding variables).

Manipulative Experiment

  • The explanatory variable is altered by scientists to test its effect on the response variable.

Control vs. Test Group

  • Control Group: Does not receive the treatment.

  • Test Group: Receives the treatment.

  • Both groups should be as similar as possible to ensure valid results.

Designing a Scientific Experiment

  1. Response Variable

    • The outcome being measured (what changes as a result of the experiment).

  2. Controlled Variables (Confounding Factors)

    • Other factors that might influence the outcome but are kept constant to ensure fair testing.

  3. Manipulative Experiment

    • Scientists change the explanatory variable (the cause) and observe its effect on the response variable.

    • This change is called the treatment.

  4. Control Group vs. Experimental Group

    • Control Group: Does not receive the treatment.

    • Experimental Group (or Test Group): Receives the treatment.

    • Both groups should be as similar as possible to make results valid.

  5. Purpose

    • To test cause-and-effect relationships in a controlled, measurable way.

Lens of Social Research Design

  • Dependent Variable (Response)

    • The social behavior, attitude, or condition being measured.

  • Independent Variable (Cause)

    • The factor believed to influence or cause change in the dependent variable (e.g., policy, education level, income).

  • Control Variables

    • Other factors that could affect results (e.g., age, gender, culture) and must be accounted for to avoid bias.

Social Inquiry Approach

  • Researchers do not always manipulate variables—they often observe, interview, or analyze patterns in real-world settings.

Comparison Groups

  • Control Group: Not exposed to the intervention or social condition.

  • Experimental/Focus Group: Experiences the condition or receives the intervention.

Ethics & Reflexivity

  • Researchers reflect on their own role, avoid harm, and protect participants’ rights and confidentiality.

Basic Science Process Skills

Observing

  • Using your senses to gather information about the world (e.g., sight, smell, touch).

Classifying

  • Grouping objects or events based on common characteristics (e.g., size, shape, use).

Measuring

  • Using tools to collect data in standard units (e.g., length, mass, time, temperature).

Inferring

  • Making explanations or interpretations based on your observations.

Predicting

  • Stating what you think will happen based on past experiences or patterns.

Communicating

  • Sharing findings through writing, talking, drawing, graphs, or charts.

Observation

Classification

  • Tropical Rainforest

  • Temperate Forest

  • Boreal Forest

  • Desert

  • Savanna

  • Grassland

  • Marine

  • Freshwater

  • Tundra

Measurement

  • A measurement of earthquake magnitude, based on seismic wave size.

  • Richter scale

Inferencing

Prediction

Communication

  • Storm surge warning system levels and expected heights:

    • RED (TAKE ACTION): 3 meters above - Storm surge is CATASTROPHIC.

    • ORANGE (ALARM): 1.1-3 meters - Storm surge is EXPECTED.

    • YELLOW (ALERT): 0.5-1 meter - Storm surge is POSSIBLE.

    • GREEN (NO ALERT): No action required.

Environmental Systems

Cultural

  • To understand development and process of the physical world.

Civic

  • Utilizing scientific processes to create informed decisions, participate in civic movement and cultural affairs, and contribute to economic productivity.

Scientific

  • Become active members of society through problem-solving.

Aesthetic

  • Promote and sustain beauty of nature.

System Thinking

  • A way of understanding how parts of a system are connected and how they affect one another.

  • Helps explain complex, real-world problems by seeing the big picture.

  • Why It Matters

    • Predicts and adjusts outcomes in complex systems (e.g., ecosystems, societies, economies).

    • Essential in a globalized, tech-driven world where problems are interconnected.

Environmental

Chemistry: Soil, Water, and Atmosphere

  • Denis Dyvee Errabo, PhD

Environmental Chemistry

  • Study of chemical processes occurring in the environment (natural and human-induced)

  • Focus Areas: Lithosphere, Hydrosphere, Atmosphere

  • Relevance: Pollution, ecosystem health, resource sustainability

Atoms and Elements

  • Everything in the environment is made of atoms

  • Atoms consist of protons, neutrons, and electrons

  • Elements are pure substances made of one type of atom

  • Atomic number = number of protons

  • Mass number = protons + neutrons

  • Common Environmental Elements: C, O, N, H, P, S

  • Role in Ecosystems: Biogeochemical cycles

Molecules and Compounds

  • Molecules: Two or more atoms bonded (e.g., O<em>2O<em>2, H</em>2OH</em>2O)

  • Compounds: Atoms of different elements bonded (e.g., CO2CO_2, NaClNaCl)

  • Environmental Examples: Water (H<em>2OH<em>2O), Carbon Dioxide (CO</em>2CO</em>2), Nitrogen Dioxide (NO2NO_2)

Key Environmental Molecules

Molecule/Compound

Sphere

Role

H2OH_2O (water)

Hydrosphere

Solvent for life, climate regulator

CO2CO_2 (carbon dioxide)

Atmosphere

Greenhouse gas, plant photosynthesis

CaCO3CaCO_3 (calcium carbonate)

Lithosphere

Forms rocks, marine shells; pH buffer

NO3NO_3^- (nitrate)

Soil/Water

Plant nutrient, pollutant (eutrophication)

O3O_3 (ozone)

Atmosphere

UV radiation shield (stratosphere), pollutant (troposphere)

Chemical Bonds

  • Ionic Bonds: Electron transfer (e.g., NaClNaCl)

  • Covalent Bonds: Electron sharing (e.g., H<em>2OH<em>2O, CO</em>2CO</em>2)

  • Importance in Stability and Reactivity

Ionic Bonds

  • Ionic bonds form between metals and nonmetals, involving the transfer of electrons. This results in the formation of oppositely charged ions (cations and anions) that attract each other.

  • Properties:

    • High melting and boiling points

    • Often water-soluble

    • Good conductors when dissolved (electrolytes)

Environmental Relevance of Ionic Compounds

Compound

Source

Environmental Relevance

NaClNaCl (sodium chloride)

Seawater, road de-icing

Affects aquatic salinity and soil structure

CaCO3CaCO_3 (calcium carbonate)

Limestone, shells

Natural buffer in soil and water; involved in ocean acidification

NO<em>3,PO</em>43NO<em>3^-, PO</em>4^{3-} (nitrate, phosphate ions)

Fertilizers

Key contributors to eutrophication in water bodies

Pb2+,Hg2+,Cd2+Pb^{2+}, Hg^{2+}, Cd^{2+} (heavy metal ions)

Mining, industry

Toxic pollutants that bioaccumulate in food chains

Covalent Bonds

  • Covalent bonds form between nonmetal atoms through the sharing of electrons, leading to stable molecules.

  • Properties:

    • Lower melting/boiling points than ionic compounds

    • Often insoluble or partially soluble in water

    • Can be polar or nonpolar, affecting how they move through soil or water

Environmental Relevance of Covalent Compounds

Compound

Source

Environmental Relevance

CO2CO_2 (carbon dioxide)

Combustion, respiration

Major greenhouse gas affecting climate change

CH4CH_4 (methane)

Landfills, wetlands, agriculture

Potent greenhouse gas, 25× stronger than CO2CO_2

C<em>6H</em>6C<em>6H</em>6 (benzene)

Fuel combustion, industry

Volatile organic compound (VOC), air pollutant, carcinogenic

DDT (dichlorodiphenyltrichloroethane)

Pesticides

Persistent Organic Pollutant (POP), disrupts ecosystems

Ions

  • Charged atoms/molecules

  • Ions: Atoms with unequal protons and electrons

    • Cations: lose electrons (+ charge)

    • Anions: gain electrons (– charge)

  • Common Ions: NO<em>3NO<em>3^-, SO</em>42SO</em>4^{2-}, Ca2+Ca^{2+}, ClCl^-

Ions and Environmental Impact

  • Soil fertility depends on the availability of ions like K+K^+, Mg2+Mg^{2+}, and NH4+NH_4^+.

  • Water quality is affected by ions such as NO<em>3NO<em>3^-, PO</em>43PO</em>4^{3-}, Pb2+Pb^{2+}.

  • Air pollution control involves ionic species like SO<em>42SO<em>4^{2-} and NH</em>4+NH</em>4^+ in aerosols.

Isotopes

  • Atoms of the same element with different neutrons

  • Use Cases: Tracing pollutants, dating rocks/water, climate history

  • Examples: 14C^{14}C (carbon dating), 18O^{18}O (paleoclimate)

Isotope Applications

Isotope

Use

Context

18O/16O^{18}O / ^{16}O

Climate reconstructions

Ice cores, rainfall history

15N^{15}N

Nitrogen cycling

Traces fertilizer runoff

14C^{14}C

Carbon dating

Archaeology, ecosystem carbon flow

13C^{13}C

Source identification

Fossil fuel vs. natural CO2CO_2

Acids, Bases, and pH

  • pH is a measure of the hydrogen ion concentration [H+][H^+] in a solution.

  • Scale ranges from 0 to 14:

    • pH < 7 = Acidic

    • pH = 7 = Neutral

    • pH > 7 = Basic (alkaline)

  • Environmental Impact: Acid rain, soil pH, aquatic life

  • Examples: H<em>2SO</em>4H<em>2SO</em>4 (acid), NaOHNaOH (base), H<em>2CO</em>3H<em>2CO</em>3 (weak acid)

Acids, Bases, and pH Examples

Term

Description

Examples

Acid

Substance that donates H+H^+ ions in solution

H<em>2SO</em>4H<em>2SO</em>4 (sulfuric acid), HNO<em>3HNO<em>3 (nitric acid), CO</em>2CO</em>2 (forms H<em>2CO</em>3H<em>2CO</em>3)

Base

Substance that accepts H+H^+ ions or donates OHOH^- ions

NaOHNaOH (sodium hydroxide), NH<em>3NH<em>3 (ammonia), CaCO</em>3CaCO</em>3 (buffering agent)

Soil Chemistry

  • Ideal soil pH: 6.0–7.5 for nutrient availability

  • Acidic soil (pH < 5.5): Limits plant growth, dissolves toxic metals like Al3+Al^{3+}

  • Alkaline soil (pH > 8): Reduces micronutrient availability (Fe, Zn, Mn)

  • Acidification sources: acid rain, overuse of ammonium fertilizers

  • Remediation: adding lime (CaCO3CaCO_3) to raise pH

Lithosphere

  • Key Elements/Compounds: CaCO<em>3CaCO<em>3, Fe</em>2O<em>3Fe</em>2O<em>3, SiO</em>2SiO</em>2

  • Issues: Soil acidification, nutrient depletion

  • Inorganic: Heavy metals (Pb, Cd, Hg), nitrates from fertilizers

  • Organic: Pesticides, herbicides, hydrocarbons from spills

  • Management: Fertilizers, lime application

Important Processes in the Lithosphere

  • Cation exchange capacity (CEC): Determines nutrient availability, especially for inorganic ions.

  • Decomposition: Organic matter breakdown releases CO<em>2CO<em>2, CH</em>4CH</em>4, and nutrients.

  • Complexation: Organic molecules bind heavy metals, affecting mobility and toxicity.

Water Chemistry

  • Aquatic life thrives in water with pH 6.5–8.5

  • Acidic water increases metal solubility → toxic to fish (e.g., Al3+Al^{3+} toxicity)

  • Basic water can reduce solubility of nutrients and cause ammonia toxicity

  • Causes of pH changes: industrial discharges, mine drainage, acid rain

  • Buffer systems: carbonate (HCO<em>3/CO</em>32HCO<em>3^- / CO</em>3^{2-}) buffer helps stabilize aquatic pH

Hydrosphere

  • Key Compounds: H<em>2OH<em>2O, dissolved O</em>2O</em>2, CO2CO_2

  • Pollution: Nitrates, phosphates, heavy metals

  • Inorganic: Arsenic, lead, nitrates

  • Organic: Petroleum hydrocarbons, plasticizers (BPA), pharmaceuticals

  • Acidification & Buffers: Carbonate buffering

Hydrogen Bonds

  • Form between δ+ hydrogen and δ– atom (often O or N)

  • Weaker than ionic or covalent bonds

  • Important in water properties and DNA structure

Water and Life

  • Water is polar and forms hydrogen bonds

  • Stabilizes temperature, dissolves substances, cohesive

  • Supports life processes and environments

Important Processes in the Hydrosphere

  • Solubility and speciation: How inorganics dissolve and react in aquatic systems.

  • Degradation: Biodegradation of organic molecules (aerobic/anaerobic)

  • Eutrophication: Caused by inorganic (nitrate, phosphate) and organic waste inputs.

Atmospheric Chemistry

  • Acid Rain Formation:

    • SO<em>2+H</em>2OH<em>2SO</em>4SO<em>2 + H</em>2O \rightarrow H<em>2SO</em>4

    • NO<em>2+H</em>2OHNO3NO<em>2 + H</em>2O \rightarrow HNO_3

  • Resulting precipitation pH: 4.2–5.0

  • Consequences:

    • Soil acidification

    • Aquatic ecosystem collapse

    • Corrosion of buildings and cultural heritage

Atmosphere

  • Key Gases: N<em>2N<em>2, O</em>2O</em>2, CO<em>2CO<em>2, O</em>3O</em>3

  • Pollutants: SO<em>2SO<em>2, NO</em>xNO</em>x → acid rain

  • Inorganic: SO<em>2SO<em>2, NO</em>xNO</em>x, CO, ozone

  • Organic: Methane, VOCs (benzene, toluene)

  • Processes: Greenhouse effect, ozone layer

Important Processes in the Atmosphere

  • Photochemical reactions: VOCs + NO<em>xNO<em>x + sunlight → tropospheric ozone (O</em>3O</em>3)

  • Acid rain formation: SO<em>2SO<em>2 and NO</em>xNO</em>x (inorganic) react with water to form H<em>2SO</em>4H<em>2SO</em>4 and HNO3HNO_3

  • Smog formation: Interaction of inorganic oxides and organic vapors

Systems Thinking: Interconnectivity of Soil, Water, and Atmosphere

  • Example 1: Acid rain affects soil pH and aquatic life.

  • Example 2: Agricultural runoff (nitrates and phosphates) pollutes water bodies and contributes to air pollution via nitrogen compounds.

  • Example 3: Wildfires degrade air quality, impact soil nutrients, and alter water cycles.