UNIT 7: APES + 4.4

Atmosphere Overview

Objectives, Essential Knowledge, and Skills

  • Suggested Skill: Visual representations
    • Learning Objective: ERT-4.D - Describe the structure and composition of the Earth's atmosphere.
    • Essential Knowledge:
    • ERT-4.D.1: The atmosphere consists of major gases, each with its own relative abundance.
    • ERT-4.D.2: Layers of the atmosphere are based on temperature gradients, including the troposphere, stratosphere, mesosphere, thermosphere, and exosphere.

Atmospheric Composition

  • Major Gases Abundance:
    • Nitrogen (N₂): 78.08%
    • Oxygen (O₂): 20.95%
    • Argon (Ar): 0.93%
    • Neon (Ne): 0.0018%
    • Helium (He): 0.0005%
    • Hydrogen (H₂): trace
    • Xenon (Xe): trace
  • Variable Gases:
    • Water Vapor (H₂O): 0-4% (varies)
    • Carbon Dioxide (CO₂): 0.038%
    • Methane (CH₄): 0.00017%
    • Nitrous Oxide (N₂O): trace
    • Ozone (O₃): trace
    • Chlorofluorocarbons (CFCs): trace

Characteristics of Atmospheric Layers

  • Exosphere:
    • Outermost layer; where atmosphere merges with space.
  • Thermosphere:
    • Hottest temperature; absorbs harmful X-rays and UV radiation.
    • Charged gas molecules glow under intense solar radiation, producing auroras (e.g., aurora borealis).
  • Mesosphere:
    • Middle layer (60-80 km); even less dense than higher layers.
  • Stratosphere:
    • Extends from 16-60 km; less dense due to pressure from layers above.
    • Ozone (O₃) layer present; absorbs UV-B and UV-C rays which can cause DNA mutations in animals (cancer risk).
  • Troposphere:
    • 0-16 km; most dense due to pressure of layers above.
    • Contains most of atmosphere’s gas molecules and is where weather occurs.
    • High levels of ozone (O₃) in this layer can be harmful to humans (respiratory irritant) and plants (damages stomata, forms smog).

Temperature Gradients in Atmosphere

  • Graph Data of Altitude vs Temperature:
    • The graph indicates that temperature typically decreases with altitude in the troposphere and mesosphere; however, it increases in the stratosphere and thermosphere due to the absorption of solar radiation.

Air Pollution Introduction

  • Learning Objective: STB-2.A - Identify the sources and effects of air pollutants.
  • Essential Knowledge:
    • STB-2.A.1: Coal combustion releases pollutants such as CO₂, SO₂, toxic metals, and particulates.
    • STB-2.A.2: Fossil fuel combustion also emits nitrogen oxides which contribute to ozone formation and acid rain.
    • STB-2.A.3: Sulfur dioxide (SO₂) impacts air quality negatively when released during fossil fuel burning.
    • STB-2.A.4: The Clean Air Act regulates lead emissions, significantly reducing atmospheric lead levels.
    • STB-2.A.5: Air pollutants can be primary (directly emitted) or secondary (formed in the atmosphere).

Detailed Air Pollutants Discussion

  • Common Air Pollutants Overview:
    • Sulfur Dioxide (SO₂): Respiratory irritant; forms acid rain.
    • Nitrogen Oxides (NOx): Respiratory irritants; lead to photochemical smog and acid rain.
    • Carbon Monoxide (CO): Product of incomplete combustion; lethal in high concentrations.
    • Particulate Matter (PM): Short for air pollutants can be deadly to human health, causing issues like chronic bronchitis.

Pollution Controls and Effects

  • Air Quality Control: Identified through the Clean Air Act, emphasizing monitoring pollutants and enforcing limits on lead and other criteria pollutants.
  • Primary vs. Secondary Pollutants:
    • Primary pollutants include CO, NOx, SO₂, PM, VOCs. Secondary pollutants include tropospheric ozone and acid rain (nitric & sulfuric acid).
  • Regulation Measures for Air Pollution: Corporate Average Fuel Economy (CAFE) standards for vehicle emissions control, as well as pollution credits for companies that reduce emissions below regulated levels.

Photochemical Smog

  • Learning Objective: STB-2.B - Causes and effects of photochemical smog and methods to reduce it.
  • Formation Conditions: Occurs when nitrogen oxides and volatile organic compounds (VOCs) react with heat and sunlight; mostly seen in urban areas.
  • Health impacts from photochemical smog: Causes respiratory problems and eye irritation.
  • Examples of VOCs: Formaldehyde, gasoline vapors, and their sources.

Thermal Inversion

  • Learning Objective: STB-2.C - Describe thermal inversion and its pollution effects.
  • Effects: Coal combustion produces pollution trapped in lower atmosphere layers during inversions, resulting in health concerns like asthma flare-ups.
  • Urban Heat Island Effect: Urban areas maintain higher temperatures due to lower albedo, affecting local climates and furthering pollution effects.

Natural and Indoor Air Pollutants

  • Natural Sources Include:
    • CO₂ from respiration, decomposition, and volcanic eruptions.
    • Particulate matter from natural dust, sea salt, and biological processes.
  • Indoor Air Pollutants: Includes carbon monoxide, asbestos, VOCs from household products, and radon from soil.

Acid Rain

  • Learning Objective: STB-2.H - Describe acid deposition.
  • Causes: Resulting from nitrogen oxides and sulfur oxides; often from coal burning and vehicles.
  • Effects: Can lead to soil and water acidification, harming plants and aquatic systems. Limiting emissions from primary sources reduces acid rain incidence.

Reduction of Air Pollutants Strategies

  • Key Methods: Regulatory practices, conservation, alternative fuels, and technological advancements in emission reduction such as scrubbers and vapor recovery nozzles.
  • Public Engagement: Actions like using less personal transportation, energy conservation, and promoting renewable energy sources may contribute to reducing overall air pollution levels effectively.