Physical & Chemical Properties, Changes, and Separation

Physical vs. Chemical Properties

  • All matter exhibits properties classified as either physical or chemical.
  • Physical property: observed/measured without altering substance’s identity.
  • Chemical property: describes ability to undergo a change producing new substances.

Key Physical Properties

  • Appearance: color, luster, clarity.
  • Mechanical: hardness, malleability, ductility.
  • Thermal: melting point, boiling point.
  • Electrical/thermal conductivity.
  • Density (mass-to-volume ratio).
  • Solubility and miscibility.

Key Chemical Properties

  • Reactivity with acids, bases, oxygen, water, etc.
  • Flammability and combustibility.
  • Corrosion/oxidation tendencies (e.g., iron rusts).
  • Decomposition or fermentation behavior.

Physical vs. Chemical Changes

  • Physical change: no bonds broken/formed; same particles before & after.
    • State change, dissolution, separation, deformation.
  • Chemical change: bonds broken/formed; produces matter with new identity.
    • Combustion, oxidation, fermentation, decomposition.

Evidence of Chemical Change

  • Temperature change (exothermic/endothermic) without external heating.
  • Light emission.
  • Unexpected color change.
  • Gas formation (bubbling not due to boiling).
  • Precipitate formation from clear solutions.
  • Odor change.

Reversibility

  • Many physical changes are reversible (freeze–melt, condense–evaporate).
  • Chemical changes typically hard to reverse without another chemical reaction.

Classifying Examples

  • Water boiling → physical.
  • Salt dissolving in water → physical (retrievable by evaporation).
  • Nail rusting → chemical (new substance, color change).
  • Two clear solutions forming yellow solid → chemical (precipitate & color).

Separating Mixtures (Physical Processes)

  • Distillation: separates components via volatility differences.
  • Fractional distillation: multiple boiling points (e.g., crude oil refining).
  • Filtration: separates solids from fluids using a porous barrier.
  • Other methods: decantation, centrifugation, chromatography (not detailed here).

Quick Comparison Chart

  • Physical property: luster of gold; Chemical property: iron corrodes.
  • Physical change: ice melting; Chemical change: paper burning.