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Organic Chemistry Fundamentals: Carbon-Based Bonding and Isomerism

What is Organic Chemistry?

  • Definition: the study of carbon-based molecules and how they interact.
  • Emphasis in lecture: reactions involve movement and redistribution of electrons; bonds are broken and formed between carbon-based molecules.
  • The recording captures both PowerPoint content and material written on the board.
  • If pace is fast, don’t worry; the notes are provided to supplement understanding.

Why Carbon Chemistry Matters

  • Carbon-based life forms on Earth.
  • Many everyday materials are carbon-based: what we eat, the clothes we wear, drugs, plastics, and other materials.
  • Although not absolute, ionic species are often classified as inorganic; example: ammonium ion and cyanate ion.
  • Example ionic species:
    • Ammonium: ext{NH}_4^+
    • Cyanate: ext{OCN}^- (note: the formal negative charge is placed on the oxygen in this example; resonance can distribute charge)
  • The other contrasted case shows a molecule with all covalent bonds (no ionic bonds).

Carbon-based Molecules and Isomerism

  • In carbon chemistry, different arrangements of the same atoms can lead to different molecules.
  • Key concept: constitutional isomers (same molecular formula, different connectivity).
  • Example: for ext{C}2 ext{H}6 ext{O} there are two distinct constitutional isomers:
    • Ethanol: ext{CH}3 ext{CH}2 ext{OH}
    • Dimethyl ether: ext{CH}3 ext{OCH}3
  • Both have the same atoms, but bonds connect them differently, giving different properties and reactivities.

Structural Theory of Matter and Bonding

  • Atoms form covalent bonds; nonmetals commonly form covalent bonds.
  • Typical bonding patterns (for neutral molecules):
    • Carbon: usually forms 4 bonds
    • Nitrogen: usually forms 3 bonds
    • Oxygen: usually forms 2