Chapter 8 : Irradiation & Dielectric Heating

Irradiation & Dielectric Heating

Irradiation and Radiation Definition

  • Radiation: A type of energy traveling in the form of waves or rays (electromagnetic waves).

  • Irradiation: The process of exposing a substance to radiation energy.

  • Ionizing radiation: Capable of knocking electrons out of molecular structures, producing free radicals.

  • Classification of electromagnetic waves is based on frequency; shorter wavelengths correspond to greater energy.

Food Irradiation

  • Utilizes controlled ionizing energy (electron volts, eV) to induce molecular changes on harmful organisms and preserve food quality.

  • Effects on Molecular Structure: Destroys or distorts nucleic acids, breaks hydrogen bonds, oxidizes double bonds, destroys ring structures, and polymerizes molecules.

  • Absorbed Radiation: Measured in Gray (Gy), where 1 Gy = 1 joule/kg, representing the amount of radiation per unit mass of food.

Types of Ionizing Radiation

Electron Beam

  • High energy electrons accelerated to nearly the speed of light.

  • Energy level: up to 10 MeV; low penetration depth (~2cm); fast penetration time; high dose rate; no radioactive waste.

Gamma Ray

  • Produced from spontaneous degradation of radioisotopes (e.g., Co-60, Cs-137).

  • Energy level: 1.17-1.5 MeV; highest penetration depth (~3 feet); widely applicable and easily controlled.

X-ray

  • Created through collisions of accelerated electrons with dense materials (e.g., Tantalum).

  • Energy level: 5-7 MeV; high penetration depth (~15 inches); largely directional with slow treatment and high shielding.

Usage and Regulation of Food Irradiation

  • Applied in over 60 countries globally, recognized as safe for food sterilization.

  • Governed by international standards and agreements, such as the WTO's SPS Agreement.

  • Certified by organizations: International Atomic Energy Agency, Food and Agriculture Organization, World Health Organization.

  • Malaysian legislation supports food irradiation for improving safety and quality, implemented in 2013.

Products Subject to Irradiation

  • Medical Supplies: Necessary for sterilization to ensure safety.

  • Pharmaceuticals: Essential for maintaining product integrity.

  • Consumer Goods: Various non-food items that may require sterilization.

  • Food Products: Such as spices, packaged food, fruits, and vegetables; promising for export-oriented produce in Malaysia.

Applications of Food Irradiation

  • Benefits: Reduces post-harvest losses, ensures hygienic quality, extends shelf life, facilitates trade.

  • Dosage Categories:

    • Low dose (<1 kGy): Inhibit sprouting, insect disinfection.

    • Medium dose (1-10 kGy): Kill foodborne pathogens.

    • High dose (10-50 kGy): Sterilization of dried foods (e.g., spices).

Effects of Radiation

  • Weaken cellulose at doses >10 kGy, increase susceptibility to oxidative rancidity at doses >3-5 kGy.

  • Weaken structural proteins causing denaturation at doses >10 kGy.

  • 20% loss of Thiamine at 3 kGy, though generally less impactful compared to cooking techniques.

Process Principles of Food Irradiation

  • Generation and Absorption of Radiation: Displacement of electrons forming free radicals which disrupt cellular processes.

  • Effectiveness varies by target organism sensitivity; insects and parasites are more susceptible than bacteria and viruses.

Equipment and Design Considerations

  • Proper design ensures maximum radiation absorption, with consideration of food product attributes (composition, size, temperature).

  • Continuous and batch processing modes each have unique advantages. Mobile irradiation is utilized in research.

Specifics of Irradiator Design

  • It includes components that enhance operational efficiency, dose uniformity, and manage processing time.

  • Efficiency relates to the amount of product processed per source activity, impacting operating costs and processing time.

Gamma Irradiator Structure

  • Composed of radiation source, biological shielding, and product handling systems (conveyor belts) for effective radiation exposure.

Cobalt-60 Characteristics

  • Cobalt-60 serves as the primary gamma irradiator source, with a half-life of 5.3 years, emitting gamma rays during disintegration without producing radioactive waste.

Operational Process Using Gamma Ray

  • Packaged food moved through radiation chamber; effective in food safety and preservation; used innovative applications like fruit juice extraction.

Electron Beam and X-Ray Machinery

  • Electron injector and accelerator, scanning systems, and material handling systems are key elements in these technologies.

Benefits and Barriers of Food Irradiation

Benefits

  • Reduces harmful microorganisms, preserves nutritional value, minimizes spoilage, and enhances food safety.

  • Facilitates immediate distribution post-treatment.

Barriers

  • Consumer skepticism and regulatory challenges primarily hinder broader acceptance.

Dielectric Heating Overview

  • Lower frequency spectrum of electromagnetic waves (30 Hz - 300 GHz).

  • Mechanism involves using the electrical properties of food (especially water) to generate heat internally through molecular friction.

Heating Mechanism

  • Water and ionic compounds act as electric dipoles, causing internal heating rather than relying on conduction from the surface.

  • Plastic, glass, and ceramics are ideal for microwave heating due to minimal absorption of microwaves.

Characteristics of Microwave Heating

  • Internal heating occurs at the speed of light, allowing rapid and uniform heating of food.

  • Clean energy process minimizes heating of the surrounding environment.

Dielectric Properties of Food

  • Dielectric constant and loss factor determine how effectively food converts microwave energy into heat.

  • High loss factor materials generate heat efficiently; penetration depth varies with material composition.

Microwave Oven Components

  • Key components like magnetron, isolator, waveguide, and safety features ensure efficient operation while minimizing radiation exposure.

Future Directions in Food Irradiation and Microwave Applications

  • Considerations include market size, consumer acceptance, regulatory frameworks, and industry growth obstacles (e.g., anti-nuclear sentiment, reliability issues).