Title: Introductory Chemistry, Second Edition, Chapter 3 Lecture Slides
Author: Kevin Revell
©2021 Macmillan Learning
Atoms are the fundamental building blocks of matter.
Reference to Revell's Introductory Chemistry (2e, 2021).
Matter is neither created nor destroyed in chemical reactions.
Key example:
Hydrogen + Oxygen = Water
4.0 g + 32.0 g = 36.0 g
Antoine Lavoisier (1743-1794) is credited with establishing this principle.
When 16.0 grams of methane react with 64.0 grams of oxygen, they yield:
36.0 grams of water and carbon dioxide
Reaction equation: methane + oxygen = carbon dioxide + water
16.0 g + 64.0 g = 44.0 g + 36.0 g
John Dalton (1766-1844) proposed key ideas:
Elements consist of tiny indivisible particles called atoms.
Atoms of each element are unique.
Atoms combine in whole-number ratios to form compounds.
Atoms remain unchanged in chemical reactions.
Atoms consist of elements that can combine chemically.
All matter consists of atoms.
Each element's atoms have distinct properties.
Atoms remain unchanged but can form compounds.
Inquiry into the visibility of atoms.
Scientists use X-ray crystallography to visualize atomic arrangements.
Displays elements arranged by atomic number and properties.
Example elements: F (Fluorine), Cl (Chlorine), Br (Bromine)
Classification of elements into groups and periods.
Groups: Elements with similar properties.
Periods: Across rows; represent energy levels.
Explanation of the term 'periodic' with reference to calendars.
Further classification of elements by family groups (e.g., Metals, Nonmetals).
Symbols for common elements:
Carbon (C), Hydrogen (H), Magnesium (Mg), Calcium (Ca), Sodium (Na), Iron (Fe), Copper (Cu), Lead (Pb).
Main groups, transition metals, and inner transition elements are identified.
Metals are located to the left of the periodic table.
Transition metals are highlighted.
Characteristics of nonmetals: located on the upper right of the periodic table.
Metalloids are positioned between metals and nonmetals, exhibiting intermediate properties.
Alkali metals are soft and react violently with water.
Less reactive compared to group 1A and burn brightly.
Halogens exist as diatomic molecules and form various compounds.
Noble gases are stable, rarely form compounds, and are gases at room temperature.
Each element's atoms are unique, and they combine in whole-number ratios.
Particle characteristics:
Mass: atomic mass unit (u) 1 u = 1.66 × 10−27 kg.
Opposite charges attract; like charges repel.
Historical perspective on the creation of the periodic table.
Electron: negatively charged particle.
Proposed by Thomson; depicts negative electrons within positively charged material.
Reference to Ernest Rutherford's experiments with alpha particles.
The atom is primarily empty space with a dense nucleus.
Illustration of atomic structure with a nucleus and electrons.
Discussion regarding the spatial volume of atoms.
Summary of atomic particles:
Proton: mass 1.0073, charge +1
Neutron: mass 1.0087, no charge
Electron: mass 0.0005, charge -1
Similar information reiterated for clarity.
The identity of an atom is determined by the number of protons present.
Atomic number: number of protons.
Mass number: total number of protons and neutrons.
Isotopes have the same atomic number but varying mass numbers.
Methodology for writing atomic symbols based on protons, neutrons, and mass number.
Example using uranium's isotope.
Calculation based on the weighted average of isotopes.
Concept of calculating averages illustrated through poker chips analogy.
Average atomic mass example utilizing isotopic abundance of carbon.
Key points about atomic identity, atomic number, and isotopes.
Definition of ions: atoms with overall charge due to electron gain/loss.
Definition and characteristics of lithium and its ion.
Description and comparison of fluorine atom and fluoride ion.
Case study on sulfur atom and its sulfide ion formation.