Atoms, Elements, and Compounds: Bonding and Structures

Ions and Ionic Bonds

  • Ion Formation: Cations are positive ions, and anions are negative ions.
  • Ionic Bond Definition: Strong electrostatic attraction between oppositely charged ions, formed between metallic and non-metallic elements.
  • Structure: Giant lattice structure consisting of a regular arrangement of alternating positive and negative ions.
  • Properties:
    • High melting points and boiling points.
    • Good electrical conductivity when aqueous or molten; poor electrical conductivity when solid.

Simple Molecules and Covalent Bonds

  • Covalent Bond Definition: Formed when a pair of electrons is shared between two atoms, resulting in noble gas electronic configurations.
  • Molecules: Dot-and-cross diagrams represent bonding in molecules including H2H_2, Cl2Cl_2, H2OH_2O, CH4CH_4, NH3NH_3, HClHCl, CH3OHCH_3OH, C2H4C_2H_4, O2O_2, CO2CO_2, and N2N_2.
  • Properties:
    • Low melting points and boiling points due to weak intermolecular forces.
    • Poor electrical conductivity.

Giant Covalent Structures

  • Key Substances: Graphite, diamond, and silicon (IV) oxide (SiO2SiO_2).
  • Structure-Property Uses:
    • Graphite: Used as a lubricant and as an electrode.
    • Diamond: Used in cutting tools.
  • Structural Similarities: Diamond and silicon (IV) oxide (SiO2SiO_2) display similar properties related to their giant covalent structures.

Metallic Bonding

  • Metallic Bond Definition: Electrostatic attraction between positive ions in a giant metallic lattice and a 'sea' of delocalised electrons.
  • Properties:
    • Good electrical conductivity.
    • Malleable and ductile.