Class12 Bioplastics

Page 1: Introduction to Environmental Biotechnology

  • Overview of the field focusing on the integration of biological processes for environmental engineering.

Page 2: Overview of Bioplastics

  • Introduction to bioplastics, mentioning the institution where the information is presented.

  • ZTF-FCT (Zientzia eta Teknologia Fakultatea, Universidad del País Vasco) as the source.

Page 3: Historical Context of Plastic Production

  • Global production and use of plastics from 1950 to 2015.

  • Measurement in million metric tons, including polymer resins, synthetic fibers, and additives.

Page 4: Reducing Plastic Pollution

  • Types of plastics: thermoplastics, thermosets, polyurethanes (PURs), elastomers, etc.

  • Prevalent materials: high-density polyethylene (PE), low-density PE, polypropylene (PP), polystyrene (PS), polyvinylchloride (PVC), polyethylene terephthalate (PET).

  • Pure polymers often mixed with additives to enhance material properties.

Page 5: The Microplastics Issue

  • Introduction to microplastics and their associated health risks:

    • Skin irritation from larger plastic products.

    • Respiratory problems linked to personal hygiene products (toothpaste, shower gel, etc.).

    • Digestive problems and cardiovascular disease.

    • Reproductive effects and cancer risk linked to microplastics and associated toxins (e.g., phthalates, PCBs, DDT).

Page 6: Definition of Bioplastics

  • Bioplastics defined as both biobased and/or biodegradable materials.

  • Biobased: Derived mainly from biomass (e.g., corn, sugarcane).

  • Biodegradable: Capable of being decomposed by microorganisms, thus avoiding pollution.

Page 7: Biodegradable Fossil-based Plastics

  • Types of biodegradable polymers include:

    • Polybutyrate adipate terephthalate (PBAT)

    • Polybutylene succinate (PBS)

    • Polycaprolactone (PCL)

    • Polyvinyl alcohol (PVOH)

  • Structure allows for breakdown by microorganisms; significant degradation (90%) of PBAT in 80 days.

Page 8: Standards for Compostable Plastics

  • Compostable plastic characteristics:

    • Biodegradability to CO2 by microorganisms under natural processes.

    • Disintegratability (fragmentation in compost).

    • No negative effects on compost quality with minimal heavy metals.

  • Compliance with European standards (EN 13432 or EN 14995).

Page 9: Biodegradable Plastics Video

  • A link provided to a video for further understanding of biodegradable plastics.

Page 10: Types of Bioplastics

  • Comparison between biobased and conventional plastics:

    • Biobased: PLA, PHA, biobased PE, PBS.

    • Conventional: PE, PP, PET; non-biodegradable vs. biodegradable plastics (e.g., PBAT, PCL).

Page 11: Non-degradable Biobased Plastics

  • Overview of biobased non-degradable plastics:

    • PET resin and processes (catalytic oxidation, polymerization).

  • Description of bio-PET vs. traditional petroleum-based PET.

Page 12: Changes in Bioplastics Production

  • Description of bioplastics redesign for sustainability; examples of biobased products.

  • Comparison of different categories of bioplastics with conventional options.

Page 13: Origins of Biobased Biodegradable Plastics

  • Sources include:

    • Animal: Collagen.

    • Marine: Chitin, chitosan.

    • Agricultural: Plant polysaccharides (e.g., cellulose, amylose).

    • Microbial: Bacterial fermentation of sugars/lipids for PLA and PHA production.

Page 14: Starch-based Plastics

  • Mention of starch-based plastics and their sources.

Page 15: Polylactate (PLA) Characteristics

  • PLA as a biodegradable polyester made from lactate.

  • Applications in biomedicine (implants, sutures).

  • Advantages of PLA include lower fossil energy consumption and non-toxic degradation products.

Page 16: PLA Production Process

  • Overview of PLA production from raw materials, leading to compostable products.

Page 17: Applications of Polylactates (PLA)

  • Uses in:

    • Biomedicine: implants, tissue engineering, absorbable surgical instruments.

    • Industry: food packaging, textiles, 3D printing.

Page 18: Polyhydroxyalkanoates (PHA)

  • Description of PHA as bacterial biopolymers formed naturally.

  • Details of the microbial biosynthesis process and how microorganisms respond to conditions.

Page 19: Production Process of PHA

  • Steps in PHA production from strain development to fermentation studies.

  • Mention of specific strains and their effectiveness in producing different types of PHA.

Page 20: Mineralization of PHA

  • Complete mineralization of PHA to water and carbon dioxide in aerobic conditions.

  • Breakdown products in anaerobic conditions: H2O, CO2, CH4.

Page 21: PHA Applications

  • Applications in the chemical industry and as an alternative biofuel source.

Page 22: Examples of Starch-based Plastics

  • Specific compostable starch-based plastics produced by various companies.

Page 23: Conclusion

  • Reiteration of importance of environmental biotechnology and bioplastics for sustainability.

Page 24: Overview of Biomining

  • Introduction to biomining and its relevance in environmental biotechnology.

Page 25: Research Projects in Environmental Biotechnology

  • Overview of project funding proposals related to environmental technology initiatives.