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Chapter 19: Enzymes and Vitamins

Enzymes and Vitamins: Comprehensive Study Notes

19.1 Catalysis by Enzymes

  • Enzyme Definition: A protein that functions as a catalyst for a biological reaction.

  • Enzyme Function in Biochemical Reactions:

    • An enzyme does not alter the energy or equilibrium of a chemical reaction.

    • It may catalyze both energetically favorable and unfavorable reactions. However, an unfavorable reaction requires energy, typically in the form of ATP.

    • The primary role of an enzyme is to decrease the time for a reaction to reach equilibrium by lowering the activation energy.

    • These reactions integrate thermodynamics (energy), kinetics (rate of reaction progress), and potentially information about the reaction mechanism.

  • Characteristics of Enzymes:

    • Most enzymes are water-soluble proteins found in the cell cytoplasm or the lumen of the gastrointestinal tract.

    • Some enzymes are not water-soluble and are associated with various membranes of cellular organelles.

    • Active Site: A

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