He6

Propane Combustion Reaction

  • Chemical Formula: Propane (C₃H₈)
  • Nature: Colorless, odorless gas used commonly as heating and cooking fuel.
  • Balanced Equation for Combustion Reaction:
    • The reaction of propane with oxygen yields carbon dioxide and water.
    • Balanced Equation:
      C₃H₈ + 5 O₂
      ightarrow 3 CO₂ + 4 H₂O

Potassium Chlorate and Sugar Reaction

  • Key Ingredients:
    • Ordinary safety matches contain potassium chlorate (KClO₃).
    • Potassium chlorate acts as a source of oxygen in combustion reactions.
    • Ordinary table sugar (sucrose, C₁₂H₂₂O₁₁) reacts violently with potassium chlorate.
  • Balanced Equation for Reaction with Sugar:
    • Reaction Products: Potassium chloride (KCl), carbon dioxide (CO₂), and water (H₂O).
    • Balanced Equation:
      2 KClO₃ + C{12}H{22}O_{11}
      ightarrow 2 KCl + 11 CO₂ + 6 H₂O

Generic Reaction Representation

  • Element Representation:
    • Element A (represented by red spheres or dark gray) reacts with Element B (represented by blue spheres or light gray).
  • Balanced Equation for Reaction: A + B ightarrow AB
    • Note: Actual symbols for elements A and B depend on the specific elements involved.

Molecular Weight and Molar Mass of Sucrose

  • Molecular Weight Calculation:
    • Sucrose (C₁₂H₂₂O₁₁)
    • Molecular Weight Calculation:
      (12 imes 12.01 ext{ g/mol}) + (22 imes 1.01 ext{ g/mol}) + (11 imes 16.00 ext{ g/mol}) = 342.30 ext{ g/mol}
  • Molar Mass:
    • Molar mass of sucrose = 342.30 g/mol.

Calculating Moles of Sucrose

  • Weight of Sucrose:
    • Given: 2.85 g of sucrose.
  • Moles Calculation:
    • ext{Moles of sucrose} = rac{ ext{mass (g)}}{ ext{molar mass (g/mol)}} = rac{2.85 ext{ g}}{342.30 ext{ g/mol}} ext{ mol}
    • Result = 0.00832 mol (rounded to 5 decimal places)

Grams in Moles of Sodium Bicarbonate

  • Given: 0.0626 moles of NaHCO₃ (Sodium Bicarbonate)
  • Grams Calculation:
    • Molar mass of NaHCO₃ = 84.01 g/mol
    • ext{Grams} = 0.0626 ext{ mol} imes 84.01 ext{ g/mol} = 5.25 ext{ g}

Aqueous Sodium Hypochlorite Reaction

  • Chemical Reaction Involvement:
    • Sodium hypochlorite (NaOCl): known as household bleach.
    • Reaction equation:
      2 NaOH(aq) + Cl₂(g)
      ightarrow NaOCl(aq) + NaCl(aq) + H₂O(l)
  • Grams Calculation of Required NaOH:
    • Given: 25.0 g of Cl₂.
    • Molar mass of Cl₂ = 70.91 g/mol
    • Moles of Cl₂: ext{Moles Cl₂} = rac{25.0 ext{ g}}{70.91 ext{ g/mol}} = 0.352 ext{ mol}
    • Stoichiometric ratio: 2 mol NaOH required for 1 mol Cl₂.
    • Required moles of NaOH = 2 × 0.352 = 0.704 mol.
    • ext{Mass of NaOH} = 0.704 ext{ mol} imes 40.00 ext{ g/mol} = 28.16 ext{ g}

Percent Yield Calculation

  • Reaction of Isobutylene:
    • Given: 32.8 g of methyl tert-butyl ether obtained from 26.3 g isobutylene reacted with excess methanol.
  • Balanced Reaction Equation:
    C₄H₈(g) + CH₃OH(l)
    ightarrow C₅H₁₂O(l)
  • Theoretical Yield Calculation Needed for Percent Yield:
    • Steps needed to obtain theoretical yield to complete percent yield calculation.
    • ext{Percent Yield} = rac{ ext{Actual Yield}}{ ext{Theoretical Yield}} imes 100

Diethyl Ether Yield Calculation

  • Given Weight: 40.0 g of ethyl alcohol with a reaction percent yield of 87%.
  • Balanced Reaction:
    2 C₂H₅OH(l)
    ightarrow C₄H₁₀O(l) + H₂O(l)
  • Theoretical Yield Calculation:
    • Molar mass of ethyl alcohol = 46.07 g/mol
    • ext{Moles of Ethyl Alcohol} = rac{40.0 ext{ g}}{46.07 ext{ g/mol}} ext{ mol}
    • Stoichiometry leads us to theoretical yield in grams for diethyl ether and then calculate the actual yield using 87%.

Cisplatin Preparation Reaction

  • Chemical Reaction for Cisplatin Synthesis:
    • Reactants: Potassium tetrachloroplatinate (K₂PtCl₄) and ammonia (NH₃).
  • Reaction Equation:
    K₂PtCl₄(aq) + 2 NH₃(aq)
    ightarrow Pt(NH₃)₂Cl₂(s) + 2 KCl(aq)
  • Given Weights: 10.0 g of K₂PtCl₄ and 10.0 g of NH₃.

Limiting and Excess Reactants

  • Identification of Limiting and Excess Reactants:
    • Consider molar masses and amount of moles available for each reactant.
  • Calculate Moles:
    • ext{Moles of K₂PtCl₄} = rac{10.0 ext{ g}}{K(39.10) + 2Pt(195.08) + 4Cl(35.45)}
    • Determine the limiting reactant based on stoichiometric needs compared to available moles.
  • Excess Reactant Calculation:
    • Calculate grams consumed and remaining for the limiting reactant.

Grams of Cisplatin Formed

  • Product Formation Calculation:
    • Moles of product from the limiting reactant leading to grams obtained.
  • Grams of Cisplatin Calculated:
    • Use molecular weights derived from products to calculate using moles formed.

Molarity Calculations

  • Sulfuric Acid Molarity:
    • Given: 2.355 g of H₂SO₄ in 50.0 mL of solution.
    • ext{Molarity} = rac{ ext{moles}}{ ext{volume (L)}}
    • First, calculate moles of H₂SO₄, then arrive at molarity.

Hydrochloric Acid Molarity Calculation

  • Commercial HCl Sale:
    • Concentration: 12.0 M in a volume of 300.0 mL.
  • Moles of HCl Calculation:
    • ext{Moles} = Molarity imes Volume.L
  • Steps to determine moles present.

Preparing NaOH Solution

  • NaOH preparation:
    • Desired volume: 500.0 mL, concentration: 0.2500 M from a 1.000 M stock.
    • Use dilution equation:
      C₁V₁ = C₂V₂
  • Solve for V₁, volume needed in mL to achieve desired molarity.

Neutralization of Stomach Acid

  • Reaction:
    • Hydrochloric Acid (HCl) neutralized by Sodium bicarbonate (NaHCO₃).
  • Equation:
    HCl(aq) + NaHCO₃(aq)
    ightarrow NaCl(aq) + H₂O(l) + CO₂(g)
  • Calculation of Volume Needed:
    • Given: 18.0 mL of 0.100 M HCl.
    • Use stoichiometry to determine volume of 0.125 M NaHCO₃ required to neutralize the acid.