Gas Laws and Ideal Gas Equation Notes

## Gas Laws - **Boyle’s Law** (constant TT and nn): p1V1=p2V2p*1V*1 = p*2V*2 - **Charles’s Law** (constant pp and nn): V1T1=V2T2\frac{V*1}{T*1} = \frac{V*2}{T*2}- Implication: Absolute minimum temperature exists. - **Avogadro’s Law** (constant TT and pp): VnV \propto n ## Absolute Temperature - Kelvin scale: Temp in °C+273.15=Temp in KTemp \space in \space °C + 273.15 = Temp \space in \space K ## Ideal Gas Equation - Combination of gas laws: pV=nRTpV = nRT- RR (Ideal Gas Constant) = 8.314 LkPaK1mol18.314 \space L \cdot kPa \cdot K^{-1} \cdot mol^{-1} ## General Gas Equation - When the number of moles is constant:
p1V1T1=p2V2T2\frac{p*1V*1}{T*1} = \frac{p*2V*2}{T*2} ## Density of Gases - Density (d) = mV\frac{m}{V} - Density of a gas is proportional to its molecular mass (M). - Using the Ideal Gas Equation:
d=mV=pMRTd = \frac{m}{V} = \frac{pM}{RT} - Dry air: - Average M = 29 gmol129 \space g \cdot mol^{-1} - Density ≈ 1.2 gL11.2 \space g \cdot L^{-1} - Gases with higher M than 29 (e.g., CO2CO*2, SO2SO*2) sink. - Gases with lower M than 29 (e.g., H2H*2, HeHe, COCO, NH3NH*3) rise.