Chapter 10 – Transfer of thermal energy and its effects

Temperature and Heat

  • Temperature: Measures how cold or hot an object is.
  • Heat: Amount of thermal energy transferred from a hot region to a colder region.
  • Thermal energy always flows from a hotter region to a colder region.
  • Net flow of thermal energy occurs only when there is a difference in temperature.
  • SI unit of temperature: Kelvin (K).
  • Other common units: degree Celsius (°C) and Fahrenheit (°F).
  • 1°C274.15K1 °C ≈ 274.15 K

Expansion

  • Particles gain energy and vibrate more vigorously, hence move further apart.
  • Distance between particles increases, thus taking up more space.
  • Volume of matter increases, and density of matter decreases.

Contraction

  • Particles lose energy and vibrate less vigorously, hence moving closer to each other.
  • Distance between particles decreases, thus taking up less space.
  • Volume of matter decreases, and density of matter increases.
  • Mass of matter does not change during expansion or contraction.

Expansion and Contraction in Different States of Matter

  • In general, solids expand and contract less than liquids, while liquids expand and contract less than gases.
  • Gases have the weakest forces of attraction between particles.
  • The particles in gases can move much further apart than in liquids and solids, occupying a bigger volume.
  • Thus, gases expand the most.

Application of Expansion and Contraction: Bimetallic Strip

  • Used in thermostats & bimetallic thermometers.
  • Bimetallic strip consists of two different metals (e.g., brass and steel) bonded together.
  • Brass expands and contracts more than steel.
    • Expansion: Bimetallic strip bends downwards with brass on the outward side and steel on the inward side.
    • Contraction: Bimetallic strip bends upwards with brass on the inward side and steel on the outward side.
  • The metal that expands the most will also contract the most.

Conduction

  • Transfer of heat energy without the physical movement of the medium (solids, liquids, or gases).
  • The particles near the heat source gain thermal energy and start to vibrate more quickly.
  • They collide with their neighboring particles to transfer energy to them, causing them to start vibrating more quickly.
  • The process repeats itself until the particles at the colder end are vibrating at the same rate.
  • Gases are less effective conductors because the particles are far apart, and thus the transfer of energy from more energetic to less energetic particles by colliding cannot take place effectively.
  • Metals are better conductors because they have delocalized electrons that gain thermal energy from interacting with the particles.
  • The small size and high speed electrons allow them to move easily and quickly to the cooler end.

Convection

  • Transfer of thermal energy from one place to another by the physical movement of the medium [fluids (liquids and gases)], due to a difference in density.
  • When the particles near the heat source are heated, the fluid increases in volume (expands), becomes less dense, and rises.
  • The cooler part of the fluid will be denser than the hotter fluid and will sink to take the place of the hotter fluid that had rose.
  • In turn, the cooler part of the fluid gets heated by the heat source.
  • The cycle repeats to set up convection currents.
  • The convection currents help to transfer the thermal energy evenly until each part of the fluid reaches the same temperature.

Radiation

  • Transfer of thermal energy from a hotter body to a cooler body without the need for a medium (can take place in solids, liquids, gases, and vacuum).
  • All bodies and objects emit infrared radiation.
  • Thermal energy that is transferred by radiation may be absorbed or reflected.
  • The hotter the object, the more thermal energy it emits/radiates.
  • When the object emits/radiates thermal energy via radiation, its temperature decreases.
  • When the object takes in/absorbs thermal energy via radiation, its temperature increases.

Factors Affecting Rate of Transfer of Thermal Energy by Conduction

  • Type of materials
    • Different types of materials have different thermal conductivities.
  • State of matter
    • Solids are better conductors than liquids, and liquids are better conductors than gases.

Factors Affecting Rate of Transfer of Thermal Energy by Radiation

  • Temperature of object
    • The higher the surface temperature of an object compared to the surrounding temperature, the higher the rate of emission of heat.
  • Surface area of object
    • The larger the surface area of an object, the higher the rate of emission or absorption of thermal energy.
  • Type of surface
    • Color and texture of the surface.
      • Dull, rough, and black surfaces are better emitters and absorbers of thermal energy.
      • White, shiny, polished, or silver surfaces are poor emitters and absorbers of thermal energy.

Vacuum Flask

  • The layer of vacuum between the silvered surfaces in the vacuum flask prevents heat loss by conduction and convection.
  • Conduction and convection cannot take place in a vacuum.