Chapter 10 – Transfer of thermal energy and its effects
Temperature and Heat
- Temperature: Measures how cold or hot an object is.
- Heat: Amount of thermal energy transferred from a hot region to a colder region.
- Thermal energy always flows from a hotter region to a colder region.
- Net flow of thermal energy occurs only when there is a difference in temperature.
- SI unit of temperature: Kelvin (K).
- Other common units: degree Celsius (°C) and Fahrenheit (°F).
- 1°C≈274.15K
Expansion
- Particles gain energy and vibrate more vigorously, hence move further apart.
- Distance between particles increases, thus taking up more space.
- Volume of matter increases, and density of matter decreases.
Contraction
- Particles lose energy and vibrate less vigorously, hence moving closer to each other.
- Distance between particles decreases, thus taking up less space.
- Volume of matter decreases, and density of matter increases.
- Mass of matter does not change during expansion or contraction.
Expansion and Contraction in Different States of Matter
- In general, solids expand and contract less than liquids, while liquids expand and contract less than gases.
- Gases have the weakest forces of attraction between particles.
- The particles in gases can move much further apart than in liquids and solids, occupying a bigger volume.
- Thus, gases expand the most.
- Used in thermostats & bimetallic thermometers.
- Bimetallic strip consists of two different metals (e.g., brass and steel) bonded together.
- Brass expands and contracts more than steel.
- Expansion: Bimetallic strip bends downwards with brass on the outward side and steel on the inward side.
- Contraction: Bimetallic strip bends upwards with brass on the inward side and steel on the outward side.
- The metal that expands the most will also contract the most.
Conduction
- Transfer of heat energy without the physical movement of the medium (solids, liquids, or gases).
- The particles near the heat source gain thermal energy and start to vibrate more quickly.
- They collide with their neighboring particles to transfer energy to them, causing them to start vibrating more quickly.
- The process repeats itself until the particles at the colder end are vibrating at the same rate.
- Gases are less effective conductors because the particles are far apart, and thus the transfer of energy from more energetic to less energetic particles by colliding cannot take place effectively.
- Metals are better conductors because they have delocalized electrons that gain thermal energy from interacting with the particles.
- The small size and high speed electrons allow them to move easily and quickly to the cooler end.
Convection
- Transfer of thermal energy from one place to another by the physical movement of the medium [fluids (liquids and gases)], due to a difference in density.
- When the particles near the heat source are heated, the fluid increases in volume (expands), becomes less dense, and rises.
- The cooler part of the fluid will be denser than the hotter fluid and will sink to take the place of the hotter fluid that had rose.
- In turn, the cooler part of the fluid gets heated by the heat source.
- The cycle repeats to set up convection currents.
- The convection currents help to transfer the thermal energy evenly until each part of the fluid reaches the same temperature.
Radiation
- Transfer of thermal energy from a hotter body to a cooler body without the need for a medium (can take place in solids, liquids, gases, and vacuum).
- All bodies and objects emit infrared radiation.
- Thermal energy that is transferred by radiation may be absorbed or reflected.
- The hotter the object, the more thermal energy it emits/radiates.
- When the object emits/radiates thermal energy via radiation, its temperature decreases.
- When the object takes in/absorbs thermal energy via radiation, its temperature increases.
Factors Affecting Rate of Transfer of Thermal Energy by Conduction
- Type of materials
- Different types of materials have different thermal conductivities.
- State of matter
- Solids are better conductors than liquids, and liquids are better conductors than gases.
Factors Affecting Rate of Transfer of Thermal Energy by Radiation
- Temperature of object
- The higher the surface temperature of an object compared to the surrounding temperature, the higher the rate of emission of heat.
- Surface area of object
- The larger the surface area of an object, the higher the rate of emission or absorption of thermal energy.
- Type of surface
- Color and texture of the surface.
- Dull, rough, and black surfaces are better emitters and absorbers of thermal energy.
- White, shiny, polished, or silver surfaces are poor emitters and absorbers of thermal energy.
Vacuum Flask
- The layer of vacuum between the silvered surfaces in the vacuum flask prevents heat loss by conduction and convection.
- Conduction and convection cannot take place in a vacuum.