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(SHORT) Explaining Redox Reactions in Acids and Metals

Key Terms/Concepts

  • Redox Reaction: A chemical reaction involving the transfer of electrons between two species, resulting in oxidation and reduction processes.

  • Oxidation Number (ON): A value assigned to an element in a compound that represents the number of electrons lost or gained by that element.

  • Oxidant: A substance that gains electrons in a redox reaction, causing another substance to be oxidized.

  • Reductant: A substance that loses electrons in a redox reaction, causing another substance to be reduced.

Key Reactions

Reactant

Species (with ON)

Observation

Balanced Half Equation

Explanation

Hydrochloric Acid + Hydrogen

2 H+ (acid) -> H₂ (0)

Colourless gas (bubbles)

2 H+ + 2 e- -> H₂

H+ is reduced to H₂, forming bubbles of gas.

Sodium + Sodium Ion

Na (0) -> Na+ (1) + e-

Silver solid -> Colourless solution

Na -> Na+ + e-

Na is oxidized to Na+, changing from solid to solution.

Key Observations

  • Colourless Solution: Indicates the presence of dissolved ions in the solution.

  • Bubbles of Colourless Gas (H₂): Observed during the reaction, indicating the formation of hydrogen gas.

Key Equations

  • Overall Reaction: 2 Na + 2 H+ -> 2 Na+ + H₂

  • Balanced Half Equations:

    • For Hydrogen: 2 H+ + 2 e- -> H₂

    • For Sodium: 2 Na -> 2 Na+ + 2 e-

Key Principles

  • Conservation of Charge: The number of electrons lost in oxidation must equal the number of electrons gained in reduction.

  • Balancing Redox Reactions: Ensure that the number of electrons is the same on both sides of the equation.

Facts to Memorize

  • Oxidation number of H₂ is 0.

  • Oxidation number of Na is 0 in elemental form.

  • Balanced half equation for hydrogen: 2 H⁺ + 2 e⁻ -> H₂.

  • Balanced half equation for sodium: Na -> Na⁺ + e⁻.

Concept Comparisons

Concept

Oxidation

Reduction

Definition

Loss of electrons

Gain of electrons

Change in ON

Increases (more positive)

Decreases (more negative)

Example

Na -> Na⁺ + e⁻

2 H⁺ + 2 e⁻ -> H₂

Cause and Effect

Cause

Effect

Sodium reacts with hydrochloric acid

Formation of hydrogen gas (H₂) and sodium ions (Na⁺)

Hydrogen ions (H⁺) are reduced

Production of bubbles of colorless gas (H₂)

Sodium (Na) is oxidized

Formation of a colorless solution of sodium ions (Na⁺)