geol unit1 pt3

Compositional Layers 

  • Earth resembles hard-boiled egg, with three principal layers: 

1. A not-so-dense crust (the eggshell) primarily (95%) composed of igneous and metamorphic rocks; remaining 5% is sedimentary rock 

2. A denser solid mantle in the middle (the “white”) 

3. A very dense core (the “yolk”) composed of metal

  • Silicates contain silicon (Si) and oxygen (O)

Compositional Layers: Crust 

  •  When you stand on the surface of Earth, you are standing on top of its outermost layer, the crust 

  • The crust is our home and the source of all our resources 

  • The crust consists of a variety of rocks that differ in composition (chemical makeup) from underlying mantle rock 

  • Base of crust (or crust-mantle boundary) = Moho (Mohorovicic seismic discontinuity) 

  •  Geologists distinguish between two fundamentally different types of crust: 

1. oceanic crust forming the floor of the deep oceans 

2. continental crust underlying virtually all the land surface and the shallow seas

Crust: Continental Crust 

  • Thick: 30 - 70 km thick 

  •  Old (up to 4,400,000,000 years) 

  • Heterogeneous composition

 – Felsic, intermediate, and mafic igneous rocks 

– Sedimentary rocks 

– Metamorphic rocks 

  •  Light (~2.7 g/cm3 ) 

  • Highly deformed by folding

Crust: Oceanic Crust 

  • Thin: about 7-10 km thick 

  • Young (<200,000,000 years) 

  • Homogenous composition 

-Mafic igneous rock (basalt and gabbro) with a thin layer of sediments/sedimentary rock on top 

  •  Dense (~ 3.0 g/cm3 ) 

  •  Relatively undeformed 

–Why?

Compositional Layers: Mantle 

  •  ~2900 km thick 

  •  Constitutes the great bulk of Earth 

– 82% of its volume 

– 68% of its mass 

  • More dense than crust 

– Why?

  • Mantle contains more iron, magnesium, and calcium than the crust 

– Ultramafic silicates

Compositional Layers: Mantle 

  •  The upper mantle is typically composed of peridotite, a rock dominated by the minerals olivine and pyroxene

 – This means that peridotite, though rare at Earth’s surface, is the most abundant rock in our planet!

Compositional Layers: Core 

  • 16% of Earth’s volume, but 32% of its mass 

  • We cannot see or measure Earth's core directly 

– Why not? Core lies unreachably far below Earth’s crust and mantle 

  • Geoscientists infer the presence of a metallic core

 – Iron alloy (iron mixed with tiny amounts of other elements, particularly nickel)

Layering by Differing Physical Properties Mechanical (or physical) properties of a material tell us:

 –How it responds to force

 –How weak or strong it is 

–Whether it is a solid or a liquid

Lithosphere 

  • crust and the uppermost part of the mantle constitute a single rigid unit known as the lithosphere (from lithos, the Greek word for ‘rock’) 

  • varies greatly in thickness – why??? Thin below ocean, thick below continental

Asthenosphere 

  • Below the lithosphere, the mantle is relatively weak, although its chemical composition is the same 

– This weak zone has been named the asthenosphere (using the Greek word for weak) 

  • Solid, but “plastic” region of the upper mantle 

– Asthenosphere is entirely in the upper mantle 

  • Highly viscous; mechanically weak

Outer Core (Liquid)

  • Circulation of liquid iron alloy in the outer core generates Earth’s magnetic field 

Inner Core (Solid)

– Pressure from the rest of the planet is so great that the iron cannot melt

Extremely high pressure Extremely hot

– 5,000-7,000°C (9,000- 13,000°F)

Has the properties we would expect of solid iron mixed with a small percentage of nickel 

From Continental Drift to Plate Tectonics 

  •  In the early 1900’s, most geologists believed that major features of Earth’s surface were fixed and permanent, having been formed during the formation of the planet 

  • First detailed theory of Continental Drift, a hypothesis that challenged this belief, put forth by Alfred Wegener in 1912 

• In the late 1960’s, technological advancements led to the development of the Theory of Plate Tectonics • The positions of the continents and ocean basins are not fixed

  • Took ~50 years for the idea of plate tectonics to be accepted…

    • WHY DID IT TAKE SO LONG?

  1. True revolution in thinking about Earth, and that was difficult for many established geologists to accept

  1. Political gulf between main proponent of Continental Drift (German Alfred Wegener) and the geological establishment of the day, which was mostly centered in UK and US

  2. Key evidence and understanding of Earth that would have supported plate tectonic theory simply didn’t exist until the middle of the 20th century (we had to wait for the technology to catch up)

“All truth passes through three stages. First, it is ridiculed. Second, it is violently opposed. Third, it is accepted as being self-evident.”

-Arthur Schopenhaur

Wegener’s Continental Drift Hypothesis (REJECTED) 

Alfred Wegener

  • 1880 – 1930

  • Ph.D., Astronomy, University of Berlin, 1904

  • Meteorologist by profession

  • First presented his theory of “continental displacement” at a meeting of the Geological Association in Frankfurt in 1912

  • Published The Origin of Continents and Oceans in 1915

What was Wegener’s idea?

  • Continents, Wegener said, wander about

  • They bump into each other

  • Collisions cause mountains

  • Continents were once joined together; have subsequently broken up and moved enormous distances apart

Continental Drift: An Idea Before Its Time

  • Continental Drift hypothesis

    • supercontinent, consisting of all of Earth’s landmasses, once existed

    • Wegener named his supercontinent Pangaea, meaning “all lands”

    • During the Mesozoic, ~200 million years ago, Pangaea began splitting (drifting) apart

Continental Drift: An Idea Before Its Time 

  • Continental Drift hypothesis 

  • supercontinent, consisting of all of Earth’s landmasses, once existed 

  • Wegener named his supercontinent Pangaea, meaning “all lands” 

  •  During the Mesozoic, ~200 million years ago, Pangaea began splitting (drifting) apart

Continental Drift: Supporting Evidence 

  1. Fit of the Continents 

  • fit of the continents is very good, especially of the coastlines of Africa and South America 

  • Wegener concluded that the fit of coastlines was too good to be coincidence 

  •  His conclusion = the continents once did fit together!

  •  Wegener published papers and books explaining his ideas of continental drift until shortly before his death in 1930. In this series of maps published in 1929, he illustrated the gradual breakup of Pangea (labels are the German names for portions of the geologic time scale

“Bullard's fit” of the continents, 1965 

  • Wegener’s fit of opposing coastlines 

1. good, but not great 

2. not terribly meaningful 

  •  Fit better/more meaningful if you use the continental slope instead 

  • real 'edge of the continent' is the continental slope 

  • although Wegener had realized this geological reality, he did not pursue this vital line of inquiry

“Bullard's fit” of the continents, 1965 

  • In 1965 paper, Bullard et al. pointed out that, in geological terms, the real edge of the continent is the continental slope 

  • Used early computers to fit continents together using continental slopes (not coastlines) 

  • A most excellent fit if you use the continental slope, not the coastline! Gap Overlap Sir Edward Bullard’s computer-aided solution to the Atlantic jigsaw Note- Bullard’s fit came after Continental Drift had been rejected!

Continental Drift: Supporting Evidence 

  • Matching Rock Units 

  • Continuity of Ancient Mountain Belts 

  • Appalachian Mountains same as mountains in Greenland, Scandinavia, UK, and NW Africa 

  • 2 billion year old rock region in western Sahara (Africa) continues into the São Luis region of northeastern Brazil

Continental Drift: Supporting Evidence 

  • Matching Rock Units 

  • Continuity of Major Faults 

  •  Wegener’s reassembly of the continents also brought together major crustal fractures or faults 

  • Great Glen Fault of Scotland continuation of the Cabot Fault of Newfoundland 

  •  major crustal fractures that reach the coast in the bight of Africa line up with similar fracture zones in eastern Brazil

Continental Drift: Supporting Evidence 

  • Matching Rock Units 

  • Not only do the outlines of the torn pieces fit together, but the printing on them (analogous to the ages and structural features of the continents) also matches across their edges

Continental Drift: Supporting Evidence Distribution of Climate Belts

  • Wegener’s father-in-law was Wladimir Peter Köppen 

  • developed Köppen climate classification system 

  • with some modifications, still commonly used!

Continental Drift: Supporting Evidence 

  •  Distribution of Climate Belts 

  • Observed deposits of coal, desert sandstone, rock salt, wind-blown sand, gypsum, and glacial deposits laid down ~300 million years ago near the end of the Paleozoic Era 

  •  Each deposit indicates a specific climatic condition at the time of its formation

Continental Drift: Supporting Evidence 

  • Past Glaciations 

  • As a glacier flows, it carries sediment of all sizes 

  • Grains protruding from the base of the moving ice carve scratches, called striations, into the substrate 

  • When the ice melts, it leaves behind sediment in deposits called till

Continental Drift: Supporting Evidence 

  •  Late Paleozoic glacial deposits found only in Southern Hemisphere and India 

  • areas now close to the tropics 

  • present-day cold latitudes in Northern Hemisphere show no evidence of glaciation at this time

Continental Drift: Supporting Evidence 

  • Arrows show direction of ice movement was from the sea toward the land-- this flow direction is impossible!! 

  • glaciers flow from centers of accumulation on the continents outward toward the sea

Continental Drift: Supporting Evidence 

  • both location of late Paleozoic glacial deposits and ice flow directions easily explained if: 

- continents restored to their former positions according to Wegener’s theory of continental drift 

- On Pangaea, areas with glacial deposits fit together with a southern polar cap

Continental Drift: Supporting Evidence 

  • Fossils Matching Across the Seas 

  • By 1900, most geologists and biologists accepted Charles Darwin’s theory of species evolution 

  • Darwin noted that the offspring of various creatures, isolated from each other and exposed to different environments, evolve into quite different beings with the passage of time

Continental Drift: Supporting Evidence 

  • Bison arose on the North American plains 

  • Wildebeest fills a similar ecological niche in Africa 

  • Both form huge herds, mostly survive by grazing (eating grass and seeds), but also by a little browsing (munching on the odd shrub) 

  • Both animals have manes, wild beards, and both look like trouble

Continental Drift: Supporting Evidence 

  • Fossils Matching Across the Seas 

  • you would instantly distinguish a bison from a wildebeest 

  • significant changes have taken place in the millions of years since the two animals shared a common ancestor 

  •  with very little practice, you would quickly discern the fossilized bones of each 

  • no African creatures evolved to exactly resemble the American bison and no wildebeest herd ever roamed the Kansas grasslands 

  •  similar, but distinct – though they have common ancestors

Continental Drift: Supporting Evidence 

  •  Not “similar, but distinct” – fossils on continents separated by oceans were identical 

  •  Mesosaurus 

  • Cynognathus 

  • Lystrosaurus 

  •  Glossopteris

Continental Drift: Supporting Evidence 

  •  Identical fossil organisms found on continents now separated by vast oceans 

  •  If you accept Darwin’s Theory of Evolution, how can you possibly explain this?

Problem! 

  • Geologists pointed out the most serious flaw in Wegener’s grand idea – continents couldn’t be moved by any force weaker than God 

  • HOW did the continents wander about?

Rejection of Continental Drift Hypothesis 

  • Objections to the continental drift hypothesis: 

  • Wegener’s inability to identify a credible mechanism for continental drift 

  •  Incorrectly proposed the gravitational forces of the Moon and Sun were capable of moving the continents 

  • Incorrectly suggested that continents broke through the ocean crust like icebreakers 

  • There was strong opposition to this hypothesis from all areas of the scientific community, and it was rejected! 

  • By analogy with a court of law, Wegener’s evidence was viewed by the jury as circumstantial and insufficient to secure a conviction

The death of Alfred Wegener (age 50) 

  • On November 2, 1930 Wegener and Rasmus Villumsen set off to deliver supplies to a small outlying camp which had been cut off by bad weather 

  • overtaken by a blizzard – never heard from again  

  • Wegener’s body not found until the following spring, on May 12, 1931 

  • lying upon a reindeer hide, placed there by Villumsen, who was never found 

Theory of Plate Tectonics (our current understanding of how Earth works)

Plate Tectonics 

  • During/following World War II, oceanographers with new equipment explored the seafloor (new technology!) 

  • Findings: 

1. Oceanic ridge system winds through all of the major oceans 

2. No oceanic crust older than ~180 million years old

 3. Thin sediment accumulation in the deep oceans 

  • These developments and others led to the Theory of Plate Tectonics

Plate Tectonics 

  •  In 1965, JT Wilson published “A New Class of Faults and their Bearing on Continental Drift” 

  • introduced plates for the first time

  •  “mobile belts, which may take the form of mountains, mid ocean ridges and ‐ major faults with large horizontal movements…are connected into a continuous network of mobile belts about the Earth which divide the surface into several large rigid plates.”

Plate Tectonics 

  • Rigid Lithosphere Overlies Weak Asthenosphere 

  •  Lithosphere 

  • Earth’s strong, rigid outer layer 

  • Asthenosphere 

  • hotter, weaker region of the upper mantle beneath lithosphere 

  • Because of differences in physical properties, lithosphere is effectively detached from asthenosphere, allowing layers to move separately

What Drives Plate Motions? Convection 

  • Geologists agree that mantle convection is the ultimate driver of plate tectonics

  • Convection is a type of heat transfer that involves the actual movement of a substance

Plate Tectonics: Plate Movement 

  • Plates move as somewhat rigid units relative to each other 

  •  Most interactions and deformations occur along plate boundaries 

  • Types of plate boundaries: 

  • Divergent plate boundaries (constructive margins) 

  • plates move apart 

  • Convergent plate boundaries (destructive margins) 

  •  plates move together 

  • Transform plate boundaries (conservative margins) 

  •  plates grind laterally past each other without the production or destruction of lithosphere

Changing Plate Boundaries 

  • Although Earth’s total surface area does not change, the size and shape of individual plates are constantly changing 

  • Plate boundaries migrate 

  • Plate boundaries are created and destroyed

Testing the Plate Tectonics Model 

  •  Evidence from the Ocean Floor 

  • bathymetric (water depth) measurements 

1. initially, soundings with hand lines 

2. Sonar (sound navigation and ranging) revolutionizes study of ocean floor 

  • Key finding = ocean floor much more rugged than previously thought! 

  • Mid-ocean ridge systems located in every major ocean basin

Sonar allows us to “see” underwater 

  • Key events in development/advancement of Sonar: 

1. Loss of HMS Titanic on April 15, 1912 

2. Allied shipping losses to U-boat attacks during WWI

  • Echo sounders calculate water depth by measuring the time it takes for the acoustic signal to reach the bottom and the echo to return to the ship

Discovery of Mid Ocean Ridges 

  • 1925-1927 

  • German scientific ship Meteor equipped with early Sonar produced first detailed survey of southern Atlantic Ocean floor 

  • found that a continuous mountainlike ridge runs through the Atlantic 

  • unfortunately it was not realized at the time that this finding supported Alfred Wegener's theory of continental drift 

Marie Tharp and Bruce Heezen (1953) 

  • Tharp and Heezen created map of the ocean floor 

  • Discovered huge (rift) valley in the center of (previously discovered) mid ocean ridge 

  • recognized (rift) valley as spreading center 

  • however both Tharp and Heezen tended to consider this a result of an expanding globe (they got the explanation wrong) 

  • Marie Tharp (actually did the work) and Bruce Heezen (published/took credit for Tharp’s work)

We finally figure out the “HOW?” 

  • Harry Hess proposes sea-floor spreading

Harry Hess and Seafloor Spreading (aka the “How?”) 

  • 1962 paper titled "History of Ocean Basins“ 

  •  one of the most important contributions in the development of plate tectonics 

  • introduced concept of seafloor spreading 

  •  outlined the basics of how seafloor spreading works 

  • molten rock (magma) oozes up from the Earth's interior along the mid-oceanic ridges, creating new seafloor that spreads away from the active ridge crest and, eventually, sinks into the deep oceanic trenches

Seafloor Spreading: The Key to Plate Tectonics 

  • continuous spreading produces fractures in the rift valley, into which magma from the mantle is injected to become new oceanic crust 

  • convection currents in the mantle carry the continents away from the oceanic ridge and toward deep-sea trenches 

  •  there, the oceanic crust descends into the mantle, with the descending convection current, and is reabsorbed 

  • in this way, the entire ocean floor is completely regenerated in ~200 million years

Testing the Plate Tectonics Model 

  • Evidence from Paleomagnetism 

  • Probably the most persuasive evidence 

  • Paleomagnetism = ancient magnetism preserved in rocks 

  • Paleomagnetic records show:

 1. Apparent polar wandering (evidence that continents have moved) 

2. Paleomagnetic Reversals 

  • Recorded in rocks as they form at ocean ridges

Testing the Plate Tectonics Model 

  • Evidence from Paleomagnetism 

  • Basaltic rocks contain magnetite (Fe3O4 ), an iron-rich mineral influenced by Earth’s magnetic field 

  • When the basalt cools below Curie point, iron-rich minerals become magnetized and align with existing magnetic field 

  • magnetite is then “frozen” in position and, like a compass needle indicates the position of the magnetic north pole and magnetic inclination angle at the time the lava solidified

Testing the Plate Tectonics Model 

  •  Evidence from Paleomagnetism 

  •  When the history of Earth’s magnetic field was first examined the results were startling 

  • Rather than pointing to the present-day magnetic poles as expected, the tiny magnetite compass needles in ancient basalt lavas were found to point in many different directions 

  • These data indicate that either the poles or the continents (or both) moved through geologic time Spoiler alert- it was the continents that were moving!

Testing the Plate Tectonics Model 

  •  Evidence from Paleomagnetism 

  • Paleomagnetic Reversals 

  • Reversals are not instantaneous 

  • they happen over a period of hundreds to thousands of years, though recent research indicates that at least one reversal could have taken place over a period of one year! 

  •  Rocks having same magnetism as present magnetic field exhibit normal polarity

  • Rocks having opposite magnetism exhibit reverse polarity 

  • Once this concept was confirmed, geologists established a timescale for these occurrences --magnetic time scale

noticed symmetrical pattern of magnetic stripes on either side of the mid ocean ridges

Testing the Plate Tectonics Model 

  • Evidence from Paleomagnetism 

  • Basaltic rocks contain magnetite (Fe3O4 ), an iron-rich mineral influenced by Earth’s magnetic field 

  • When the basalt cools below Curie point, iron-rich minerals become magnetized and align with existing magnetic field 

  • magnetite is then “frozen” in position and, like a compass needle indicates the position of the magnetic north pole and magnetic inclination angle at the time the lava solidified

Testing the Plate Tectonics Model 

  • Evidence from Paleomagnetism 

  • When the history of Earth’s magnetic field was first examined the results were startling 

  • Rather than pointing to the present-day magnetic poles as expected, the tiny magnetite compass needles in ancient basalt lavas were found to point in many different directions 

  • These data indicate that either the poles or the continents (or both) moved through geologic time 

  • Spoiler alert- it was the continents that were moving!

Testing the Plate Tectonics Model 

  • Evidence from Ocean Drilling 

  • 1000’s of wells drilled through layers of sediment that blanket the ocean floor and the basaltic ocean crust 

  •  Findings: 

1. sediments increase in age with increasing distance from the ridge crest 

2. sediments almost absent on ridge crest; sediments thickest furthest from the spreading center 

  • Pattern of distribution is expected with Hess’s seafloor spreading hypothesis being correct

Testing the Plate Tectonics Model 

  • Evidence from Seismic Surveys 

  • Seismic surveys use acoustic waves to create images of the subsurface 

  •  oil and gas industry routinely uses 2D and 3D seismic surveys to locate crude oil and natural gas in the subsurface

  • acquisition of seismic survey using ship, air guns and hydrophones

Testing the Plate Tectonics Model 

  • Evidence from Seismic Surveys 

  • Findings 

  • Sediment thicknesses were up to several thousands of meters thick near the continents, they were relatively thin—or even non-existent — in the ocean ridge areas 

  • Same thing ocean drilling had discovered… 

  • crust is relatively thin under the oceans (5 km to 6 km) compared to the continents (30 km to 60 km) and geologically very consistent, ocean crust composed almost entirely of basalt

Testing the Plate Tectonics Model 

  • Evidence from Hot Spots and Mantle Plumes 

  • mantle plume is a cylindrically shaped upwelling (i.e. blob) of molten rock (magma) 

  • surface expression of a mantle plume is an area of volcanism called a hot spot 

  •  as a plate moves over a hot spot, a chain of volcanoes, known as a hot-spot track, forms 

  • age of each volcano indicates how much time has elapsed since it was over the mantle plume 

  • Examples: Hawaiian Islands, Yellowstone

Hotspots

  1. A plume of hot material rises from deep within Earth’s interior

  2. The plume impinges on the lithosphere, leading to the outpouring of of flood basalts on the ocean floor. 

  3. Waning volcanic activity produces individual volcanoes that are carried away by plate motion to form a chain of extinct volcanoes.

Plate Boundaries 

  • Plates bounded by three distinct types of boundaries differentiated by the type of movement they exhibit 

1. Divergent plate boundaries 

  • where two plates move apart 

  •  results in upwelling of hot material from mantle to create new seafloor

2. Convergent plate boundaries 

  • where two plates move together

  •  results in either: 

  1. oceanic lithosphere descending beneath an overriding plate, eventually to be reabsorbed into the mantle 

  2.  collision of two continental blocks to create a mountain belt

3. Transform plate boundaries 

  • two plates grind past each other without the production or destruction of lithosphere

Plate boundaries 

  • Divergent and convergent plate boundaries each account for about 40% of all plate boundaries.

  • Transform faults account for the remaining 20% 

Oceanic-Oceanic Divergent Oceanic Ridge (mid-ocean ridge) 

  • broad, linear swell (mid ocean ridge) along a divergent plate boundary 

  • Longest topographic feature on Earth 

  • Occupy elevated positions 

  • Segments offset by transform faults (strike-slip motion)

  • Extensive faulting and earthquakes (shallow focus) 

  • Rift valley (deep, down-faulted structure) exists on axis of most ridges 

  •  Volcanoes (new ocean crust created here)

Remember Seafloor Spreading? 

  • Harry Hess, 1962 

  • Seafloor spreading occurs along mid ocean ridges 

  • Newly formed melt (from decompression melting of mantle) slowly rises toward surface 

  • Most melt (magma) solidifies in lower crust, but some escapes to sea floor and erupts as lava 

  • Volcanoes present here!

Why Are Ocean Ridges Elevated? 

  • Newly created lithosphere is hot and less dense than surrounding rocks 

  • As the newly formed crust moves away from the spreading center, it cools and increases in density

Divergent Plate Boundaries Continental Rifts (Continent-Continent)

Evolution of an Ocean Basin 

  • Divergent plate margins first develop in continents 

  • New ocean basin begins with formation of continental rift 

  • elongated depression (rift valley) where lithosphere is stretched and thinned 

  • When lithosphere is thick and cold, rifts are narrow: 

  • East African Rift, Rio Grande Rift, Baikal Rift, Rhine Valley 

  • When the lithosphere is thin and hot, rift can be very wide: 

  • Basin and Range, USA

East African Rift Valley 

  • Continental rift extending through eastern Africa 

  • Consists of several interconnected rift valleys 

  • Normal faulting led to grabens (down-faulted blocks) 

  • Area has expensive basaltic flows and volcanic cones (volcanoes present here!)

  • lithosphere is thick and cold, rifts are narrow

Mount Kilimanjaro, Tanzania (Volcano!)

Red Sea Rift 

  • Formed when Arabian Peninsula rifted from Africa beginning ~30 million years ago 

  • Fault scarps surrounding Red Sea similar to structures seen in East African Rift 

  •  If spreading continues, Red Sea will grow wider and develop an elongated mid-ocean ridge

Atlantic Ocean 

  • After tens of millions of years, the Red Sea may develop into a feature similar to the Atlantic Ocean

  • As new oceanic crust was added to the diverging plates, rifted margins moved further from region of upwelling 

  • These margins cooled and subsided below sea level

New Madrid Seismic Zone (NMSZ) 

  • prolific source of intraplate earthquakes (earthquakes within a tectonic plate) in the southern and midwestern US 

  • responsible for the 1811–12 New Madrid, MO earthquakes 

  • M 7-8 (?) 

  • has the potential to produce large (M 7-8?) earthquakes in the future!

  • Reelfoot Rift formed during breakup of supercontinent Rodinia ~ 750 million years ago) 

  • resulting rift system failed to split the continent, but has remained as zone of weakness deep underground

Charleston, South Carolina Earthquake 

  • September 01 02:51 UTC (local August 31), 1886

  • Magnitude 7.3

Convergent Plate Boundaries: 3 types of convergent plate boundaries

  1. ocean-continental 

  2. ocean-ocean 

  3. Continental-continental (mountains)

Ocean will subduct, older will always be the one subducting

Convergent Plate Boundaries Oceanic-Oceanic 

  •  two oceanic plates move toward one another 

  • one oceanic plate bends and sinks down into the asthenosphere beneath the other plate 

  • Geologists refer to the sinking process as subduction 

  • These types of convergent boundaries are also known as subduction zones 

  •  EARTHQUAKES and VOLCANOES have the potential to cause TSUNAMIS at subduction zones

Major Features of Subduction Zones 

  • Volcanic island arc 

  • Deep-ocean trench 

  • Forearc region 

  • Back-arc region

Volcanic Island Arc 

  • subducting slab partially melts the overlying mantle wedge 

  •  Melt migrates upward through the overlying oceanic lithosphere and forms a growth called a volcanic island arc or island arc

Volcanic Island Arc 

  • The Aleutian Islands in Alaska are a volcanic island arc formed via subduction

Deep Ocean Trenches 

  • Trenches created when oceanic lithosphere bends as it descends into the mantle 

  • Trench depth is related to the age of the subducting lithosphere 

  • Old lithosphere is cold and dense 

  • Plates subduct at steep angle, producing a deep trench 

  • Young lithosphere is warm and buoyant 

  • Plates subduct at shallower angle and produce shallower trenches (if at all)

Forearc and Back-Arc Regions 

forearc region 

  • area between the trench and the volcanic island arc 

back-arc region 

  • located on the side of the volcanic island arc opposite the trench 

  • both regions consist of pyroclastic material and eroded sediments 

  • tensional forces prevalent in these regions, causing stretching

Convergent Plate Boundaries Oceanic-Continent

Convergent Plate Boundaries Ocean-Continent 

  • Oceanic plate and continental plate move toward one another 

  • oceanic plate bends and sinks down into the asthenosphere beneath the continental plate 

  • Geologists refer to the sinking process as subduction 

  • These types of convergent boundaries are also known as subduction zones 

  • EARTHQUAKES and VOLCANOES have the potential to cause TSUNAMIS at subduction zones!

Major Features of Oceanic/Continent Subduction Zones 

  • Continental volcanic arc 

  • Deep-ocean trench

Convergent Plate Boundaries: Ocean-Continent 

  • oceanic plate always denser than continental plate 

  • oceanic plate subducts and melts, generating magma 

  • magma rises 

  • if magma reaches surface, volcanoes form

Convergent Plate Boundaries: Ocean-Continent 

  •  thick continental crust impedes the ascent of magma 

  •  most magma never reaches the surface and crystallizes underground as massive plutons called batholiths 

  • uplift and erosion eventually expose the batholiths 

  • typically range from granites to diorites

Convergent Plate Boundaries Continent-Continent 

  •  Two continental plates move toward one another 

  •  neither plate can be subducted due to their high buoyancy (continental crust=styrofoam)

  • The two continents become welded together as they are compressed together over time

  •  The underthrusting of one continent thickens the crust under the other 

  •  EARTHQUAKES

  •  Mountain Belts - no volcanoes!!

Continent-Continent Collisions: Collisional Mountain Belts 

  •  zone, where two continents collide, is called a suture 

  • Typically contains slivers of oceanic lithosphere 

  • deformation of a thick sequence of sedimentary rocks called a fold-andthrust belt

  • aka collisional mountain belts…

Collisional Mountain Belts: Himalayas 

  • Prior to the collision, India’s northern margin consisted of a thick platform of continental shelf sediments 

  • Asia’s southern margin was an active continental margin with a well-developed accretionary wedge and volcanic arc

Collisional Mountain Belts: Himalayas 

  •  ensuing continental collision folded and faulted the crustal rocks that lay across the margins of these continents to form the Himalayas

Mount Everest, Nepal and China (29,032′)

Collisional Mountain Belts: Appalachians

  • A volcanic arc (Taconic volcanic arc) develops to the east of North America 

Taconic Orogeny

  •  volcanic arc thrust over the continental block 450 million years ago 

  • volcanic rocks and marine sedimentary rocks were metamorphosed and are exposed in New York

Acadian Orogeny 

  • Continued closing of the ocean basin resulted in Avalonia microcontinent colliding with North America 350 ma ago 

  • Thrust faults, metamorphism, and granite intrusions are associated with this event 

  • Substantially added to the width of North America

Alleghanian Orogeny 

  • Africa collided with North America 250–300 million years ago 

  • Material was displaced 250 kilometers inland on North America

Pangaea began rifting apart ~200 million years ago (during the Early Jurassic Period) 

  •  Rift was eastward of the suture, leaving a remnant of Africa welded to North America

Transform boundaries 

  •  zones of shearing, where two plates slide horizontally past each other 

  • Rocks in the shear zone are strongly deformed, BUT crust is neither produced nor destroyed as the plates slide horizontally past each other 

  • EARTHQUAKES 

  • NO VOLCANOES 

  • Most transform faults are found on the ocean floor 

  • commonly offset the active spreading ridges, producing zig-zag plate margins, and are generally defined by shallow earthquakes

Transform Boundaries 

  • a few transform faults occur on land 

  • Example: San Andreas fault zone 

  • transform fault connects the East Pacific Rise, a divergent boundary to the south, with the South Gorda-Juan de Fuca-Explorer Ridge, another divergent boundary to the north

Transform Plate Boundary M 7.0 Haiti earthquake - January 12, 2010 

  • result of shallow strike-slip faulting in the boundary region separating Caribbean plate and North America plate 

  • Enriquillo-Plantain Garden fault zone (EPGFZ) 

  • 220,000-300,000 deaths 

  • estimates of death toll vary widely…

Hot Spots and Mantle Plumes 

  • Hotspots are the surface expressions of mantle plumes 

  • Mantle plumes are hot columns of partially molten rock anchored (at least relative to plate movements) in the deep mantle 

  • origin of mantle plumes unclear… 

  • geoscientists infer they arise from deep in the mantle, near the boundary between the core and the mantle (?)

Hot Spots and Mantle Plumes 

  • At a hotspot, plumes of abnormally hot but solid rock rising within Earth’s mantle begin to melt as the rock pressure on them drops (pressure reduction  melting) 

  •  Wherever peridotite of the asthenosphere partially melts, it releases basalt magma that fuels a volcano on the surface 

  • If the hotspot is under the ocean floor, the basalt magma erupts as basalt lava 

  • If the hot basalt magma rises under continental rocks, it partially melts continental rocks to form rhyolite magma 

  • rhyolite magma often produces violent eruptions

Hot Spots and Mantle Plumes 

  • Hotspots are the surface expressions of mantle plumes 

  • Mantle plumes are hot columns of partially molten rock anchored (at least relative to plate movements) in the deep mantle

  • origin of mantle plumes unclear… 

  • geoscientists infer they arise from deep in the mantle, near the boundary between the core and the mantle (?)

Hot Spots and Mantle Plumes 

  • At a hotspot, plumes of abnormally hot but solid rock rising within Earth’s mantle begin to melt as the rock pressure on them drops (pressure reduction  melting) 

  •  Wherever peridotite of the asthenosphere partially melts, it releases basalt magma that fuels a volcano on the surface 

  • If the hotspot is under the ocean floor, the basalt magma erupts as basalt lava 

  • If the hot basalt magma rises under continental rocks, it partially melts continental rocks to form rhyolite magma 

  • rhyolite magma often produces violent eruptions

Hot Spots and Mantle Plumes 

  • presence of hot spot inferred by anomalous volcanism (i.e. not at a plate boundary) • Hawaiian volcanoes located in middle of Pacific Plate 

  • hot spots also develop beneath continents 

  • Yellowstone hot spot

Hot Spots and Mantle Plumes 

  • As oceanic volcanoes move away from the hot spot, they cool and subside, producing older islands, atolls, and seamounts 

  • As continental volcanoes move away from the hot spot, they cool, subside, and become extinct

Earth is old… really, really, really old

  •  ~4,600,000,000 (~4.6 billion) Years old

  • 4,600 million years (Ma) = 4.6 billion years

  • Precambrian time (boring!) represents the first 87 yards 

  • Dinosaurs first appeared 5 yards from the goal line (exciting!) 

– 1 yard line dinosaurs go extinct in MASS EXTINCTION 

  • The glacial epoch (ICE AGE) occurred in the last inch 

  • Historic time is so short that it cannot be represented on this figure

Geologic Time: Rocks as Clocks

The Importance of a Time Scale 

  • Rocks record geologic and evolutionary changes throughout Earth’s existance

  •  Without a time perspective, these events have very little meaning

Principle of Cross-Cutting Relations (Lyell) 

  • Younger features cut across older features 

  • An event that cuts across existing rock is younger than the disturbed rocks (the rocks it cuts)

Principle of Cross-Cutting Relations (Lyell) 

  • Which is older? Granite (a)

– Igneous Dike

 – Granite Hint

  • what cuts what? dike(a)

Principle of Cross-Cutting Relations (Lyell) 

  • Which is older? Rock (a)

-Fault? 

– Rock? 

Correlation of Rock Layers: Fossil Assemblages 

  • fossil assemblage 

–group of fossils used to determine a rock’s age

Geologic Time: How old is the Earth? …and how do we know?

Archbishop James Ussher (1581-1656) 

  • Volume 4 of Annals of the World (1650)

 – “…beginning of the night which preceded the 23rd of October in the year 710 of the Julian period”  

  • Earth created in 4004 B.C.E. – 4004 + 2023 = 6027 (Earth currently 6027 years old)

“Salt Clock” or Chemical Denudation 

  • Hypothesis - Streams continually bring dissolved salts into the oceans, so over time, the oceans should get saltier 

  • How much time it would take for an initially fresh-water ocean to achieve its current level of salinity? 

– Earth cannot be very young (few thousand years) -- oceans would still be mostly freshwater

 – Earth could not be infinitely old -- oceans would be thoroughly saturated with salt, like the Dead Sea

“Salt Clock” or Chemical Denudation 

  • Edmond Halley (1656–1742) – Idea only; didn’t actually do the math… 

  • These guys actually do the math… 

– T. Mellard Reade (1876): 25 Ma 

– John Joly (1899): 99.4 Ma and (1909) 80-150 Ma 

– George F. Becker (1910): 50-70 Ma

  • Rivers dissolve rocks, which makes the water hold ions. Makes the sea saltier.

George-Louis Leclerc, Comte de Buffon (1707-1788) 

  • Epochs of Nature (1774) 

  • Estimated the time it would take for molten Earth to cool to its present state

 – Actually performed experiments designed to help him make the best possible estimates  

  • Experimented with heating iron spheres and scaling their cooling to an Earth-sized mass 

– His conclusion: Earth ~75,000 years old

William Thomson, 1st Baron Kelvin (1824-1907)

  • Refined Buffon's calculations 

  • Assumed that Earth had formed as a completely molten object, and determined the amount of time it would take for the near-surface temperature gradient to decrease to its present value 

– Kelvin conceded that his calculation would only be accurate if no other source of heat existed within the Earth 

  • His latest (and most confident) answer, reached in 1897 after more than 50 years of study, was in the range of around 24 million years Oops!! 

  • Turns out there is another source of heat – radioactive decay!

Atomic Number 

  • All atoms of a given element have the same number of protons in their nucleus—we call this number the atomic number 

–Atomic number = number of protons in the nucleus of an atom

  •  Determines the atom’s chemical nature

Mass Number 

  • Number of protons + number of neutrons 

  • Atoms of a given element always have the same atomic number, but they can have different mass numbers

Isotopes 

  • Carbon always has atomic number 6, but its mass number can be 12, 13, or 14 

  • 12C = 6 protons, 6 neutrons 

  • 13C = 6 protons, 7 neutrons 

  • 14C = 6protons, 8 neutrons

Potassium-40 to Argon-40 

  • One of the isotope pairs widely used in geology is the decay of K-40 to Ar-40 (potassium-40 to argon-40) 

  • K-40 is a radioactive isotope of potassium that is present in very small amounts in all minerals that have potassium in them 

  • It has a half-life of 1.3 billion years (Ga) 

– Over a period of 1.3 Ga one half of the 40K atoms in a mineral or rock will decay to 40Ar, and over the next 1.3 Ga one-half of the remaining atoms will decay, and so on

Potassium-40 to Argon-40 

  • In order to use the K-Ar dating technique, we need to have a rock that includes a potassiumbearing mineral 

  • One good example is the igneous rock granite, which normally contains the mineral potassium feldspar

Dating with Radioactivity 

  • A complex process! 

  • Determining the quantities of parent and daughter isotopes must be precise 

  • Some radioactive materials do not decay directly into stable daughter isotopes

Radiocarbon dating 

  • Radioactive isotope = carbon-14 

  • Half-life of carbon-14 is 5730 years 

  • Can be used to date events from the historic past to events as old as ~70,000 years 

  • Only useful in dating organic matter (doesn’t work for rocks)

Radiometric dating of Earth rocks 

  • Earth is geologically active; surface rocks typically get recycled 

  • Must find old rocks!

 – Jack Hills, Australia (4.4 Gyr) 

– Acasta Gniess, Canada (4.03 Gyr)

 – Isua Greenstone Belt, Greenland (3.8 Gyr) 

Radiometric dating of Lunar (Moon) rocks 

  • Radiometric dating indicates Lunar (Moon) rocks 4.360 Ga 

  • Apollo 17 mission, astronaut and geologist Harrison H. "Jack" Schmitt

Radiometric Dating of Meteorites 

  • Meteorites are rocks that has fallen to Earth from outer space 

  • 4.568 billion years old 

– Oldest age obtained for any Solar System object so far NWA 2364 meteorite (NW Africa)

Structure of the Geologic Time Scale: Eons 

  • Geological time divided into four eons: 

  1. Hadean (4567 to 4000 Ma)- oldest

  2. Archean (4000 to 2500 Ma) 

  3. Proterozoic (2500 to 538.8 Ma) 

  4. Phanerozoic (538.8 Ma to present)-youngest

Structure of the Geologic Time Scale: Eons 

Proterozoic Eon 

  • “Before Life” 

  • 2500 Ma – 538.8 Ma 

Archean Eon 

  • “Ancient” 

  • 4000 Ma – 2500 Ma 

Hadean Eon (oldest) 

  • 4567 Ma to ~4000 Ma

isotope - same number of protons, different number of neutrons, different atomic mass

Phanerozoic eon

  •  “visible life”

  • 538.8 Ma to present

  • We live in the Phanerozoic eon

Structure of the Geologic Time Scale: Eras 

  • Eons are divided into eras 

  • The Phanerozoic eon is divided into three eras: 

  1.  Paleozoic era (oldest) »538.8 Ma (“early or ancient life”)

  2. Mesozoic era »252 Ma (“middle life”) 

  3. Cenozoic era »66 Ma (“new or recent life”) 

  • We live in the Cenozoic era

Phanerozoic eon— the past 538.8 Ma of Earth’s history —is divided into three eras:

  1.  Paleozoic (“early or ancient life”) 

  2. Mesozoic (“middle life”) 

  3. Cenozoic (“new or recent life”)

Put time boundaries in areas of mass extinction 

EX: paleozoic era ended with the extinction of dinos

Structure of the Geologic Time Scale: Period 

  • Eras are divided into periods 

  • Cenozoic era, which represents the past 66 Ma, is divided into three periods 

1. Paleogene (oldest) 

2. Neogene 

3. Quaternary (present)

EON ->ERA-> PERIOD ->EPOCH 

-Four eons 

  • Hadean 

  • Archean 

  • Proterozoic 

  • Phanerozoic 

-Phanerozoic eon divided into three eras 

  • Paleozoic 

  • Mesozoic 

  • Cenozoic 

-Eras are further divided into periods 

The cenozoic era is divided into three periods 

  • Paleogene 

  • Neogene 

  • Quaternary

- Periods are divided into epochs

Element 

  • Most fundamental substance into which matter can be separated by chemical means 

  • An element is a pure substance that cannot be separated into other materials

  •  ~92 naturally occurring elements

  • Can also be synthesized (made) in a lab

  • Organized in a periodic table so that those with similar properties line up

Atom 

  • Smallest unit of an element that possesses the properties of the element 

Composed of: 

  • Protons: charge of +1 

  • Nucleus

  • Neutrons: charge of 0 

  • Electrons: charge of –1 

  • Electrons exist as a cloud of negative charges surrounding the nucleus

Atomic Number

  •  Atomic number = number of protons in the nucleus of an atom 

  • Determines the atom’s chemical nature

Fun Terminology  

Mass Number/Atomic Mass Number 

  • the number of protons plus neutrons in an atom of an element 

  • atoms of a given element always have the same atomic number, but they can have different mass numbers 

Isotopes 

  • Iron has four naturally-occurring stable isotopes, 54Fe, 56Fe, 57Fe and 58Fe

  •  Iron always has atomic number 26, but its mass number can be 54, 56, 57, or 58

  • 54Fe = 26 protons, 28 neutrons 

  • 56Fe = 26 protons, 30 neutrons 

  • 57Fe = 26 protons, 31 neutrons 

  • 58Fe = 26 protons, 32 neutrons

Ions 

  • Atoms that have as many electrons (-1 charge) as protons (+1 charge) are electrically neutral 

  • Atoms can gain or lose electrons in their outermost shells 

  • Atom that loses or gains electron(s) has a net electric charge and is called an ion

  • An ion is atom that is not neutral 

  • Ions form in solution 

  • Ex: saltwater

  • An ion with an excess negative charge (it has more electrons than protons) is an anion 

  • example: Cl– has a single excess electron so has -1 charge 

  • An ion with an excess positive charge (it has more protons than electrons) is a cation 

  • Example: Fe2+ is missing two electrons so has +2 charge 

  • Importance: attraction between cations and anions is the bonding force that often holds matter together 

  • cations are positive- Grumpy Cat always has a positive attitude!

Chemical Bonds 

  • A chemical bond is an attractive force that holds two or more atoms together

  •  There are several types of chemical bonds: 

  1.  ionic bonds form when a cation and an anion (ions with opposite charges) get close together and attract each other 

  2.  covalent bonds form when atoms share electrons 

  3.  In materials with metallic bonds, some of the electrons can move freely

Chemical Bonds: Ionic Bonding (transfer)

  • One atom (metal) transfers an electron to another atom (nonmetal)

  •  Attractive force is set up that creates an ionic bond

Halite (NaCl)—Example of Ionic Bonding

  • The transfer of an electron from a sodium(NA) to (CL) chlorine atom leads to the formation of a Na+ ion and a Cl- ion

Covalent Bonding (share)

  • Electrons from different nonmetal atoms “pair-up” 

  • No electrons are lost/gained 

  • No ions are formed 

  • Each atom shares the electrons in order to fill the outer shell

  • Two hydrogen atoms combine to form a hydrogen molecule, held together by the attraction of oppositely charged particles- positively charged protons in each nuclei and negatively charged electrons that surround these nuclei.

Metallic Bonding (free flow)

  • Positive metal ions attract conducting electrons 

  • Atoms are so tightly packed that electrons can be shared among several atoms 

  • Valence electrons are free to migrate among atoms

  • This mobility accounts for the high electrical conductivity and ductile behavior of metals

Van der Waals Bonding (stick together)

  • Weak attraction between electrically neutral molecules that have asymmetrical charge distribution

Minerals

  • Minerals are all around us!

  •  the graphite in your pencil

  • the salt on your fries

  • the drywall on your walls

  • the trace amounts of gold in your computer 

  • everything made of metal is derived from minerals

  • minerals can be found in a wide variety of consumer products including paper, medicine, processed foods, cosmetics, electronic devices, and many more

  • Minerals are there, even if you can’t see them with your eyes

Minerals: Building Blocks of Rocks

Definition of a Mineral:

  • Naturally occurring

  • (Generally) inorganic

  • Solid substance

  • Crystalline material - specific, orderly crystalline structure 

  • Definite chemical composition

Definition of a Rock: 

  • Naturally occurring aggregate of minerals

Never, ever confuse rocks and minerals! minerals are to rocks as letters are to words.

Naturally Occurring

  • true minerals grow in nature, not in factories 

  • only naturally occurring inorganic solids are minerals

  • chemists can manufacture materials that have characteristics virtually identical to those of real minerals

  • Such materials can be referred to as synthetic minerals

  • Synthetic products are not minerals!

(generally) Inorganic

  • distinction between inorganic and organic compounds not always clear

  • living (organic) vs nonliving (inorganic) 

  • biogenic CaCO3 becomes problematic…

  • carbon (organic) vs no carbon (inorganic

  • calcite, graphite, diamond, etc. become problematic…

  • define an organic compound as one containing both carbon and hydrogen

  • Coal (not a mineral)

Solid

  • A mineral, like any matter in the solid state, can maintain its shape indefinitely, so it will not conform to the shape of its container

  • Minerals cannot be liquids (such as oil or water) or gases (such as air) 

  • Liquid mercury is not a mineral (because it’s a liquid!)

Crystalline Material: Specific, Orderly Crystalline Structure

  • In a crystalline material, the atoms reside in an orderly, fixed pattern, locked in place by chemical bonds

  • The three-dimensional geometric arrangement of atoms or ions that defines that pattern is called a crystal (crystalline) structure

  • Minerals have a specific, orderly crystalline structure 

  • René-Just Haüy (1743-1822) 

  • Opal is a mineraloid (not a mineral!) because although it has all of the other properties of a mineral, it does not have a specific, orderly crystalline structure

  • crystalline structure of a mineral controls its physical properties 

  • diamond and graphite are minerals

  • diamond and graphite have the same chemical composition [(carbon (C)], but the carbon atoms form different crystalline structures

Definite Chemical Composition 

  • minerals have a specific (definite) chemical formula or composition

  • Can be expressed by a specific chemical formula

  • Quartz is SiO2 …always 

  • Calcite is CaCO3… always

  • Halite is NaCl… always

How do minerals form? 

  • New mineral crystals can form in several ways: 

  1.  Solidification (freezing) of a melt

  2. Precipitation from aqueous solution (water)

  3. Solid-state diffusion 

  4. Biomineralization 

  5. Chemical Weathering 

  6. Precipitation from gaseous emanations (i.e. precipitation directly from a gas) 

  7. Metamorphism

Solidification (freezing) of a melt 

  • Happens when a liquid (magma/lava) cools and turns into a solid 

  • Similar to water freezing

  • When the magma/lava is hot, atoms are mobile

  • When the magma/lava cools, atoms slow and begin to chemically combine

  • water crystallizes to form ice (a mineral) 

  • magma/lava crystallizes to form minerals

Precipitation from aqueous solution (water) 

  • ions dissolved in an aqueous solution reach saturation and start forming crystalline solids 

  • drop in temperature or water loss through evaporation can cause ions to reach saturation

Solid-state diffusion 

  • results from the movement of atoms or ions through a solid to arrange into a new crystal structure 

  • Garnets, for example, grow by diffusion in solid rock 

  • During this process, they replace pre-existing minerals

Biomineralization 

  • takes place when minerals grow at the interface between the physical and biological components of the Earth System

  • This process can happen because metabolic processes of some living organisms can cause minerals to precipitate either within their bodies, on their bodies, or immediately adjacent to their bodies 

  • Shells (composed of the mineral aragonite or calcite) produced by marine organisms grow when these organisms extract ions from the water they live in

Chemical weathering

  •  minerals unstable at Earth’s surface may be altered to other minerals

Precipitation directly from a gas can occur around volcanic vents or around geysers 

  •  volcanic gases or steam enter the atmosphere and cool, so some gas molecules of some elements are able to bind together 

  • some of the bright yellow sulfur deposits found in volcanic regions form in this way

Metamorphism 

  • formation of new minerals directly from the elements within existing minerals under conditions of elevated temperature and pressure 

  • No melting occurs!

  • EX: blue kyanite

  • Graphite and diamond are both made entirely out of carbon

  • If we put graphite under a huge amount of pressure, the carbon atoms will be squeezed together and will rearrange themselves into the more compact crystal structure of diamonds

Minerals

  •  ~3800 minerals (!) 

  • Rock-Forming Minerals

  • common minerals that make up most of the rocks of Earth’s crust 

  • less than 2 dozen 

  • A much more manageable number!!!

  • composed mainly of the 8 elements that make up most of Earth’s crust

  • Most minerals are made up of a cation (a positively charged ion) or several cations and an anion (a negatively charged ion (e.g., S2–)) or an anion complex (e.g., SO4 2–)

  • For example, in the mineral hematite (Fe2O3 ):

  • the cation is Fe3 + (iron) 

  • the anion is O2– (oxygen) 

8 most common elements in Earth’s crust 

  1. Oxygen

  2. Silicon

  3. Aluminum 

  4. Iron

  5. Calcium

  6. Sodium

  7. Potassium

  8. Magnesium

Mineral Classification

  • We classify minerals according to the anion part of the mineral formula

  • recall, an anion is a negatively charged ion such as Cl- or CO 3 -2

  • mineral formulas are always written with the anion on the right

  • pyrite (FeS2 )

  • Fe 2 + is the cation 

  • S – is the anion

Carbonates 

  • carbon and oxygen bonded with another element 

Oxides 

  • oxygen bonded with a metal

Halides 

  • chlorine or fluorine, typically bonded with a metal from left side of table

Sulfates (Sulphates)

  • sulfur combined with oxygen and bonded to a metal

Sulfides (Sulphides) 

  • sulfur bonded with a metal

Native minerals

  • contain a single element

Silicate Structures: Independent (or Isolated) Tetrahedra

  • In this group, the silica tetrahedra do not share any oxygen atoms

  • Silica tetrahedra bond to other elements, not other silica tetrahedra

  • The attraction between silica tetrahedra and positive ions (cations) holds these minerals together

  • Examples: Olivine, Garnet, Zircon, Kyanite

Olivine 

  • Olivine composed of individual (independent) silica tetrahedra 

  • in olivine, the –4 charge of the silica tetrahedron is balanced by two divalent (i.e., +2) iron or magnesium cations

  • Olivine can be either Mg2SiO4  or Fe2SiO4 , or some combination of the two (Mg,Fe)2SiO4

Silicate Structures: Single Chains 

  • In a single-chain silicate, the tetrahedra link to form a chain by sharing two oxygen atoms 

  • strongly bonded so cleavage cuts parallel to the chains 

  • two planes of cleavage at 90 degrees

Single Chain Silicate Minerals: Pyroxenes 

  • The most common of the many different types of single-chain silicates are pyroxenes

  • Pyroxenes important components of dark-colored igneous rocks

  • Augite most common mineral in the pyroxene group

  • Black in color 

  • Two distinctive cleavages at nearly 90 degrees 

  • Dominant mineral in basalt

Silicate Structures: Double Chains

  •  In a double-chain silicate, the tetrahedra link by sharing two or three oxygen atoms

  • minerals cleave parallel to the double chains

  • two planes of cleavage at 60 and 120 degrees

Double Chain Silicate Structures: Amphiboles

  • Amphiboles are the most common type of double chain silicates

  • Hornblende most common mineral in this group

  • Two perfect cleavages exhibiting angles of 120 and 60 degrees

Silicate Structures: 2D Sheet Silicates 

  • All the tetrahedra in this group share three oxygen atoms and therefore link to form two-dimensional sheets

  • Other ions, and in some cases water molecules, fit between the sheets in some sheet silicates

  • Because of their structure, sheet silicates have cleavage in one direction and occur in books of very thin sheets

  • bonds between sheets are weak 

  • This group includes micas and clays (which occur only in extremely tiny flakes)

2D Sheet Silicate Structures: Muscovite 

  • Common member of the mica family 

  • Excellent cleavage in one direction 

  • Clear, thin sheets 

  • Produces the “glimmering” brilliance often seen in beach sand

Silicate Structures: 3D Framework Silicates 

  • In a framework silicate, each tetrahedron shares all four oxygen atoms with its neighbors, so the tetrahedra are configured in a threedimensional structure 

  • Examples:Feldspars, Quartz 

  • All oxygen ions are “shared” between tetrahedra

Feldspars 

  • Most common mineral group

  • Forms under a wide range of temperatures and pressures 

  • Exhibit two directions of perfect cleavage at 90 degrees

Quartz 

  • Only common silicate mineral composed entirely of oxygen and silicon 

  • Hard (7) and resistant to weathering

  • Breaks with conchoidal fracture 

  • Often forms hexagonal crystals 

  • Colored by impurities (various ions)

Nonsilicate Minerals: Halides

  • minerals that make up the halide group include those in which the halogen elements of fluorine, chlorine, bromine, and iodine are combined with one or more metals

  • includes halite, sylvite, fluorite

  • halogen elements are the anion

Nonsilicate Minerals: Oxides

  • Oxide minerals have oxygen (O2–) as their anion 

  • but we exclude those minerals with oxygen complexes such as carbonate (CO3 2–), sulphate (SO4 2–), and silicate (SiO4 4–) from the oxide group 

  • several minerals of great economic importance including the chief ores of iron, chromium, manganese, tin, and aluminum 

  • Hematite (iron oxide Fe2O3 )

  •  Magnetite (Fe3O4 )

  •  Corundum (aluminum oxide Al2O3 )

Nonsilicate Minerals: Sulfates/Sulphates

  •  basic unit of the sulfate minerals is the sulfate anion, SO4 2- 

  • sulfate anion combines with metal cation to form the sulfate minerals

  •  the metal cation has a +2 charge, which balances the –2 charge on the sulfate ion

  • many sulfates form by precipitation out of water at or near the Earth’s surface 

  • Common sulfate minerals: 

  • Barite (BaSO4 )

  • Gypsum(CaSO4 .2H2O)

  • Anhydrite(CaSO4)

Nonsilicate Minerals: Native Elements 

  • Minerals that are composed of atoms from a single element are referred to as native elements 

  • Native metals consist of pure masses of a single metal

  • The metal atoms are bonded by metallic bonds

  • Ex: gold, copper, diamond, sulfur,graphite