Study Notes on the Origin of Elements, Nucleosynthesis and Abundance
Copyright Notice
The material has been reproduced and communicated by or on behalf of the University of the Philippines pursuant to PART IV: The Law on Copyright of Republic Act (RA) 8293 or the “Intellectual Property Code of the Philippines”.
The university does not authorize reproduction or communication of this material.
Reproduction/communication of this material may lead to copyright infringement with potential legal consequences for the infringer.
Do not remove this notice.
Chapter 1: Origin of the Elements
This chapter explores the formation of elements with a focus on three key processes:
Big Bang nucleosynthesis
Stellar nucleosynthesis
Supernova nucleosynthesis
Transuranium elements and their synthesis are also covered.
Discussion of the abundance of elements in the universe and on Earth.
Introduction
Definition of an element:
An element is identified by its atomic number, Z, which is the number of protons in its nucleus.
The origin of elements traces back to the formation of their subatomic particles, extending broadly to everything's origin.
Expanding Universe:
Observations indicate that the universe is expanding, suggesting it likely originated from a concentrated region, supporting the Big Bang Theory.
Coined by Fred Hoyle in a 1949 BBC broadcast but has roots in earlier observations (1912) by Vesto Slipher concerning receding galaxies.
Key Settings for Element Formation in Cosmic History:
Big Bang nucleosynthesis (BBN): the formation of elements during the universe's initial moments.
Stellar nucleosynthesis: the process of element formation within stars.
Supernova nucleosynthesis: element formation during the explosive death of massive stars.
Important mechanisms at play in nucleosynthesis include:
Nuclear fusion (combining nuclei for heavier nuclei in BBN and stellar nucleosynthesis)
Rapid neutron capture (nuclei bombarded by neutrons during supernova events)
Beta decay processes leading to more stable nuclei.
Learning Objectives
Ability to:
Discuss the processes by which elements were formed.
Explore the quantifiable abundance of elements within the universe and on Earth.
1.1. Nucleosynthesis and the Big Bang Theory
Nucleosynthesis: Formation of new atomic nuclei, originally occurred in the first three minutes post-Big Bang.
Big Bang refers to rapid universe expansion from a hot, dense singularity, establishing itself as the origin point of everything.
Timeline representation of the universe's evolution supports BBT.
Initial Conditions:
At the beginning, temperatures were so high that matter and energy could not be differentiated.
Matter consists of electrons and quarks; quarks combine to form hadrons, fundamental constituents like protons and neutrons.
Temperature Threshold for Nucleosynthesis:
Nucleosynthesis commences when temperature drops sufficiently (T=10^{11} K).
Key Processes in BBN targeting Light Element Synthesis (D, He-3, He-4, Li-7):
Table 1.1.1 illustrates the stages and temperature conditions along with relevant reactions.
Table 1.1.1: Stages of Big Bang Nucleosynthesis
Stage Breakdown:
First Frame: T=10x10^{11}
Reactions:
1e^0 + 0n^1 ⇄ 1^{1}H + 𝜈̅0: Too hot to form nuclei.
1^{1}H ⇄ 0n^1 + 0𝜈0: Neutron-to-proton ratio of 1:1 billion (approx).
Second Frame: T=3x10^{10}
Reactions: Neutron decay continues, still no nucleus.
n^1 → 1^{1}H + −1e^0 + 𝜈̅0; Neutron-to-proton ratio ~38:62.
[…] (Further frames include deuterium formation, subsequent reactions, and stability of tritium and helium).
1.1.2 The Transition from Nucleosynthesis to Star Formation
As the universe cools, elements (mainly H and He) initially spread uniformly, culminating in gravity fostering protogalactic clouds followed by dense protostars.
Stellar Nucleosynthesis: Initiated upon exceeding core temperatures of 15 million K, leading to hydrogen fusion and various elemental formations.
Notable fusion methods here:
Proton-Proton Chain Reaction: Fusion in small to medium stars.
CNO Cycle: Catalytic fusion sequence in medium stars.
Triple-alpha Process: Helium fusion into carbon in giant stars.
1.2. Mechanisms of Stellar Nucleosynthesis
Detailed fusion reactions yield various elements based on stellar mass and composition.
Proton-Proton Chain Reaction (Illustrated):
Initial reactions lead to He-4 with mass loss converting to energy (via ).
CNO Cycle Dynamics specialized more for heavier stars, recycling carbon as a catalyst.
Triple-alpha Process transforms helium nuclei to carbon, critical for heavier stars.
Heavier elements formed near supernova conditions where core collapses lead to neutron capture (r-process).
1.3. Synthesis of New Elements
Transuranium Elements (Z > 92): First synthesized Technetium (Tc) in 1936; Curium (1944) as the first purely synthetic element.
Evidence of decay evaluation is crucial for acknowledging artificial elements.
1.4. Abundance of the Elements
Figure 1.3.1 shows elemental distribution in the universe, with H and He dominating.
The Oddo-Harkins Rule explains even-to-odd ratios and their stability during stellar synthesis:
Elements with even Z are generally more stable due to even combinations of nucleons.
Planetary abundance is distinct from cosmic, as presented in Figure 1.3.2 concerning Earth's crust, highlighting rock-forming elements vs. lighter gases.