Alcohols
What is an alcohol in chemistry?
→ An organic compound containing one or more hydroxyl groups (–OH) attached to a saturated carbon atom.What is the general formula for a simple alcohol?
→ R–OH, where R is an alkyl group.How are alcohols different from phenols?
→ Alcohols have –OH on an alkyl group, while phenols have –OH on an aromatic ring.Give two examples of alcohols.
→ Methanol (CH₃OH) and Ethanol (CH₃CH₂OH).Are alcohols polar or non-polar?
→ Polar, due to the O–H bond — they can hydrogen bond.
🧪 Intermediate Level
How are alcohols classified?
→ Based on how many carbon atoms are attached to the carbon bearing the –OH:Primary (1°): R–CH₂–OH
Secondary (2°): R₂CH–OH
Tertiary (3°): R₃C–OH
What is the IUPAC suffix for naming alcohols?
→ -ol
Example: Propane → PropanolWhat happens when a primary alcohol is oxidized?
→ It forms an aldehyde, then further oxidation gives a carboxylic acid.What happens when a secondary alcohol is oxidized?
→ It forms a ketone.Can tertiary alcohols be oxidized easily?
→ No, because the carbon with the –OH group has no hydrogen atoms to remove.
🧠 Advanced / Chemistry Concepts
What type of reaction forms an alcohol from an alkene?
→ Hydration: Alkene + H₂O → Alcohol (with acid catalyst)How does the boiling point of alcohols compare to alkanes?
→ Alcohols have higher boiling points due to hydrogen bonding.What is a dehydration reaction in alcohols?
→ Removal of water (H and OH) to form an alkene, often using heat and acid.What happens when an alcohol reacts with a carboxylic acid?
→ It forms an ester and water (esterification).What is Lucas' test, and what does it distinguish?
→ A test using HCl + ZnCl₂ to differentiate between primary, secondary, and tertiary alcohols based on their reactivity (tertiary reacts fastest).