Naming and Formulas of Covalent Compounds
Characteristics of Covalent Compounds
- Composed of nonmetals located in the top right corner of the periodic table.
- Held together by covalent bonds involving the sharing of electrons.
- Unlike ionic compounds, covalent compounds lack charges to dictate formulas, necessitating prefixes in their names.
Naming Conventions and Prefixes
- Prefixes indicate the specific number of each atom in a molecule.
- First Element: Uses the full element name. A prefix is included only if there is more than one atom (e.g., N2O3 is dinitrogen trioxide).
- Second Element: Ending is changed to −ide. A prefix is always used, including mono- (e.g., carbon monoxide).
- Vowel Adjustment: Final vowels in prefixes are often dropped before oxygen to sound better, such as dropping the "o" in mono- or the "a" in deca- (e.g., P4O10 is tetra phosphorus deck oxide).
- Common Prefixes: Includes di- (2), tetra- (4), hexa- (6), and deca- (10).
Specific Rules for Hydrogen and Organic Molecules
- Molecules containing hydrogen do not utilize prefixes (e.g., HI is hydrogen iodide).
- Hydrogen-containing molecules in water follow acid naming conventions, such as hydroiodic acid.
- Compounds consisting of hydrogen bonded to carbon are classified as organic molecules and use separate naming systems.
- The sequence of elements in the name and formula reflects the molecular structure.
- The first element named is typically the central atom and is the element furthest from fluorine on the periodic table due to its lower electronegativity.
- The second element generally surrounds the central atom and is closer to fluorine (e.g., in OF2, oxygen is the central atom and is named first as oxygen difluoride).
- SCl6: sulfur hexa chloride (no prefix on sulfur because it is the first element and has only one atom).
- P4O10: tetra phosphorus deck oxide (tetra- indicates four phosphorus atoms; deck- indicates ten oxygen atoms).