Naming and Formulas of Covalent Compounds

Characteristics of Covalent Compounds

  • Composed of nonmetals located in the top right corner of the periodic table.
  • Held together by covalent bonds involving the sharing of electrons.
  • Unlike ionic compounds, covalent compounds lack charges to dictate formulas, necessitating prefixes in their names.

Naming Conventions and Prefixes

  • Prefixes indicate the specific number of each atom in a molecule.
  • First Element: Uses the full element name. A prefix is included only if there is more than one atom (e.g., N2O3N_2O_3 is dinitrogen trioxide).
  • Second Element: Ending is changed to ide-ide. A prefix is always used, including mono-\text{mono-} (e.g., carbon monoxide).
  • Vowel Adjustment: Final vowels in prefixes are often dropped before oxygen to sound better, such as dropping the "o" in mono-\text{mono-} or the "a" in deca-\text{deca-} (e.g., P4O10P_4O_{10} is tetra phosphorus deck oxide).
  • Common Prefixes: Includes di-\text{di-} (22), tetra-\text{tetra-} (44), hexa-\text{hexa-} (66), and deca-\text{deca-} (1010).

Specific Rules for Hydrogen and Organic Molecules

  • Molecules containing hydrogen do not utilize prefixes (e.g., HIHI is hydrogen iodide).
  • Hydrogen-containing molecules in water follow acid naming conventions, such as hydroiodic acid.
  • Compounds consisting of hydrogen bonded to carbon are classified as organic molecules and use separate naming systems.

Structural Information and Electronegativity

  • The sequence of elements in the name and formula reflects the molecular structure.
  • The first element named is typically the central atom and is the element furthest from fluorine on the periodic table due to its lower electronegativity.
  • The second element generally surrounds the central atom and is closer to fluorine (e.g., in OF2OF_2, oxygen is the central atom and is named first as oxygen difluoride).

Examples of Formulas and Names

  • SCl6SCl_6: sulfur hexa chloride (no prefix on sulfur because it is the first element and has only one atom).
  • P4O10P_4O_{10}: tetra phosphorus deck oxide (tetra-\text{tetra-} indicates four phosphorus atoms; deck-\text{deck-} indicates ten oxygen atoms).