Fat lecture

Overview of Lipids

  • Lipids include fats, oils, and waxes; focus on fats and oils in food.

Types of Fats

  • Animal Fats: Butter (milk), lard (pork), suet (beef).

  • Plant Oils: Olive oil, palm oil, coconut oil, corn oil, soybean oil, peanut oil.

Functions of Fats in Food

  • Flavor: Unique taste; enhances overall flavor by carrying soluble compounds.

  • Texture: Important for emulsions; contributes to creamy textures.

  • Cooking: Heat transfer medium in frying; allows higher cooking temperatures than water.

  • Tenderization: Softens baked goods (cakes, biscuits).

  • Aeration and Anti-foam: Incorporates air into batters; acts against foam formation.

Structure of Fats

  • Composed of glycerol and fatty acids.

    • Glycerol: 3 carbon atoms with hydroxyl groups.

    • Fatty Acids: Carboxyl group + carbon chain; can be saturated (no double bonds) or unsaturated (with double bonds).

    • Triglycerides: Main form in foods; composed of glycerol and three fatty acids.

Physical Properties of Fats

  • Solubility: Fats are fat-soluble; less affinity for water.

  • Melting Point: Influenced by chain length and degree of saturation.

    • Shorter chains = lower melting points.

    • More unsaturation = lower melting points.

Deterioration of Fats

  • Hydrolytic Rancidity: Fatty acids are released from glycerol due to heat or enzymes (lipases); leads to off-flavors like butyric acid.

  • Oxidative Rancidity: Occurs in unsaturated fats; produces off-flavors and losses of nutrients. Catalyzed by metals, light, and increased temperatures.

Fat Substitutes

  • Sucrose Polyester (Olestra): Fat-like but indigestible; calorie-free alternative.

  • Salatrim: Short-chain fatty acids, lower in calories; resembles fat in properties.

  • Simplesse: Derived from proteins; provides creamy texture without calories.

  • Oatrim: Derived from oat fiber; mimics fat texture, used in frozen products.