Chapter 13- Oxidation and Reduction

Oxidation

  1. Gain of oxygen

  2. Loss of hydrogen

  3. Loss of electrons

  4. Increase in oxidation state (e.g. from -1 to 0)

  5. For half equation of reduction, electrons are shown on the left side, e.g.

                                Pb2+ + 2e- →Pb
    

Reduction

  1. Loss of oxygen
  2. Gain of hydrogen
  3. Gain of electrons
  4. Decrease in oxidation state (e.g. from 0 to -1)

For half equation of oxidation, electrons are shown on the right side, e.g.

                              2Br-   → Br2 + 2e-

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  • Oxidation state: the charge an atom of an element would have if it existed as an ion in a compound.

  • Redox reactions: chemical reactions which involve oxidation of one substance and reduction of another.

  • Oxidising agent: a substance that causes another substance to be oxidised, and is reduced itself in the process.

  • Reducing agent: a substance that causes another substance to be reduced, and is oxidised in that process.

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  • To check if oxidation or reduction have taken place in an reaction, write a balanced chemical equation with oxidation states, and compare them on both sides.

  • Test for oxidising agents:

TestObservation when positiveExplanation
Add aqueous Potassium iodide, KI, to unknown substance.Brown solution is formedIodide ions are oxidised to iodine by oxidising agent.2I-         I2 + 2e-
Dip a piece of starch-iodide paper in unknown solution.Starch-iodide paper turns blue from whiteIodide ions are oxidised to iodine which reacts with starch to give a blue colour.

 

  • Test for reducing agents:
TestsObservation when positiveExplanation
For gases: Place a piece of filter paper soaked with acidified potassium manganate (VII), KMnO4, at the mouth of the test tubeFilter paper turns from purple to colourlessThe manganate (VII) ion, MnO4-, is reduced to manganese (II) ion, Mn2+ (colourless)
For solutions: Add acidified potassium manganate (VII) to unknown solutionColour changes from purple to colourlessThe manganate (VII) ion, MnO4-, is reduced to manganese (II) ion, Mn2+ (colourless)

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