Matter, Elements, and Chemical Bonding

Matter and Elements

  • Life is made up of matter, which occupies space and has mass.
  • Matter is composed of elements, which cannot be broken down chemically.
  • Elements are made of atoms with a constant number of protons and unique properties.
  • Each element has a chemical symbol (e.g., H, N, O, C, Na) and unique properties.

Atoms

  • An atom is the smallest component of an element that retains its chemical properties.
  • Atoms combine to form molecules, which can interact to form cells, tissues, and organs in multicellular organisms.
  • Atoms contain protons, electrons, and neutrons (except the most common hydrogen isotope).
  • Proton: Positively charged, resides in the nucleus, mass of 1, charge of +1.
  • Electron: Negatively charged, travels around the nucleus, negligible mass, charge of -1.
  • Neutron: Resides in the nucleus, mass of 1, no charge.
  • In a neutral atom, the number of protons equals the number of electrons, resulting in a net zero charge.
  • The mass of an atom is equal to the number of protons plus the number of neutrons.

Atomic Number and Mass Number

  • The atomic number is the number of protons in an element.
  • The mass number (atomic mass) is the number of protons plus the number of neutrons.
  • Number of neutrons can be determined by subtracting the atomic number from the mass number.

Isotopes and Radioisotopes

  • Isotopes are different forms of the same element with the same number of protons but a different number of neutrons.
  • Radioactive isotopes (radioisotopes) are unstable and lose subatomic particles or energy to form more stable elements.
  • Half-life: The time it takes for half of the original concentration of an isotope to decay to its more stable form.
  • Carbon-14 dating is used to age formerly living objects up to about 50,000 years old using the half-life of 14C.

Chemical Bonds

  • Electrons exist at energy levels that form shells around the nucleus.
  • The closest shell holds up to two electrons, while the second and third shells can hold up to eight electrons.
  • Atoms are most stable when their outermost shell is filled (octet rule).
  • Chemical bonds are interactions between elements that result in the formation of molecules to achieve greater stability.
  • Atoms bond by sharing, accepting, or donating electrons.
  • An ion is an atom that does not contain equal numbers of protons and electrons, giving it a net charge.
  • Cations: Positive ions formed by losing electrons.
  • Anions: Negative ions formed by gaining electrons.
  • Electron transfer: The movement of electrons from one element to another.

Types of Chemical Bonds

  • Ionic bond: A bond between ions formed through electron transfer, resulting in positive and negative ions attracting each other.
  • Covalent bond: A strong bond formed when electrons are shared between two elements; the most common type of bond in living organisms.
  • Nonpolar covalent bond: Electrons are equally shared between atoms of the same element or different elements.
  • Polar covalent bond: Electrons are unequally shared, resulting in a slightly positive (δ+) or slightly negative (δ–) charge.
  • Hydrogen bond: A weak attraction between the δ+ charge of a hydrogen atom and a δ– charge of another molecule.
  • van der Waals interactions: Weak attractions between polar, covalently bound atoms in different molecules due to temporary partial charges.